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《结构与土木工程前沿(英文)》 >> 2020年 第14卷 第1期 doi: 10.1007/s11709-019-0579-6

Using thermodynamic parameters to study self-healing and interface properties of crumb rubber modified asphalt based on molecular dynamics simulation

. School of Transportation, Southeast University, Nanjing 211189, China.. School of Highway, Chang’an University, Xi’an 710064, China.. School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin 150090, China

录用日期: 2019-12-27 发布日期: 2019-12-27

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摘要

The thermodynamic property of asphalt binder is changed by the addition of crumb rubber, which in turn influences the self-healing property as well as the cohesion and adhesion within the asphalt-aggregate system. This study investigated the self-healing and interface properties of crumb rubber modified asphalt (CRMA) using thermodynamic parameters based on the molecular simulation approach. The molecular models of CRMA were built with representative structures of the virgin asphalt and the crumb rubber. The aggregate was represented by SiO and Al O crystals. The self-healing capability was evaluated with the thermodynamic parameter wetting time, work of cohesion and diffusivity. The interface properties were evaluated by characterizing the adhesion capability, the debonding potential and the moisture susceptibility of the asphalt-aggregate interface. The self-healing capability of CRMA is found to decrease as the rubber content increases. The asphalt-Al O interface with higher rubber content has stronger adhesion and moisture stability. But the influence of crumb rubber on the interfacial properties of asphalt-SiO interface has no statistical significance. Comparing with the interfacial properties of the asphalt-SiO interface, the asphalt-Al O interface is found to have a stronger adhesion but a worse moisture susceptibility for its enormous thermodynamic potential for water to displace the asphalt binder.

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