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《工程(英文)》 >> 2017年 第3卷 第4期 doi: 10.1016/J.ENG.2017.03.029

洞察无有机模板合成沸石分子筛催化材料

Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310007, China

录用日期: 2017-07-21 发布日期: 2017-08-30

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摘要

作为当前最重要的工业催化材料之一,沸石分子筛的合成一般是在有机模板存在的条件下水热合成的,但是该合成过程会产生大量的有害气体和废水,不仅污染环境,还增加了生产成本。本文旨在概述有机模板在沸石分子筛合成过程中的角色,并据此分别设计沸石晶种和导向剂溶液导向的无有机模板条件下合成沸石分子筛的路线。在此基础上,总结并揭示了在无有机模板的Na+ 体系中合成的沸石分子筛的微孔体积与Si/Al 比值的关系,即微孔体积越大,Si/Al 比值越小,这对于无有机模板条件下合成Si/Al 比值可调控的沸石分子筛和设计它们的合成路线具有重要意义。

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