Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic media

2011, Volume 5, Issue 1

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Frontiers of Chemical Science and Engineering >> 2011, Volume 5, Issue 1 doi: 10.1007/s11705-010-0532-7

Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic media

1. Department of Chemistry, Payame Noor University (PNU), Isfahan 81395-671, Iran; 2. Department of Chemistry, Payame Noor University (PNU), Shahin Shahr Branch, Isfahan 83196, Iran; 3. Department of Chemistry, Yasouj University, Yasouj 75918-74831, Iran

Available online: 2011-03-05

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Abstract

Mono and bis-4-methylpiperidiniummethyl urea were synthesized, characterized and used as new corrosion inhibitors of mild steel in the acidic media. Inhibitory effect of two compounds on mild steel surface in the 1 mol·L sulphuric acid has been studied by a series of techniques, such as potentiodynamic polarization, weight loss and quantum chemical calculation methods. Potentiodynamic polarization measurements showed that two inhibitors are mixed type. All measurements showed that inhibition efficiencies enhanced with increase of inhibitor concentration. This reveals that inhibitive actions of inhibitors were mainly due to adsorption on mild steel surface. Density functional (DFT) calculations have been carried out for the title compounds by performing HF and DFT levels of theory using the standard 6-31G* basis set.

Keywords

corrosion inhibitors ; mild steel ; acidic medium ; theoretical studies ; DFT

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