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A ternary mechanism for the facilitated transfer of metal ions onto metal–organic frameworks: implications

Frontiers of Chemical Science and Engineering   Pages 1632-1642 doi: 10.1007/s11705-022-2187-6

Abstract: Although metal–organic frameworks offer a new platform for developing versatile sorption materials, yetHerein, a ternary mechanism for U(VI) uptake in metal–organic frameworks was reported.energy-dispersive X-ray spectroscopy and zeta potential measurement reveal that U(VI) uptake in the three metal–organicThe present study suggests that changing metal center of metal–organic frameworks and sorption conditionsalters sorption mechanism, which helps to construct effective metal–organic frameworks-based sorbents

Keywords： U(VI)     metal–organic frameworks     adsorption mechanism     metal node    

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Selective capture and separation of xenon and krypton using metal organic frameworks: a review

Frontiers of Chemical Science and Engineering   Pages 1895-1912 doi: 10.1007/s11705-023-2355-3

Abstract: Metal organic frameworks as hotspot porous materials for gases uptake and separation are considered toIn this review, we comprehensively summarized recent researches on metal organic frameworks for selectiveaspects of different optimal design strategies, including optimal pore/cage size and geometry, open metal

Keywords： metal organic frameworks     xenon     krypton     selective separation     used nuclear fuel    

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Metal-organic frameworks for CO

Lei ZHANG, Junqing ZHANG

Frontiers in Energy 2019, Volume 13, Issue 2,   Pages 221-250 doi: 10.1007/s11708-019-0629-8

Abstract: Metal-organic frameworks (MOFs) have attracted much attention because of their large surface areas, tunableMOF-based photocatalysts (functionalized pristine MOFs, MOF-photosensitizer, MOF- semiconductor, MOF-metal

Keywords： metal-organic frameworks (MOFs)     photocatalysis     CO2 photoreduction     composite    

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Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 939-949 doi: 10.1007/s11705-022-2152-4

Abstract: organic frameworks for efficient degradation of organic contaminants.nanodroplets from diffusion-induced swollen micelles as the dual pore-forming templates, and Fe-based metal-organicmicroparticles possess interconnected hierarchical porous structures decorated with highly accessible Fe-based metal-organicprovides a simple and general strategy to flexibly combine hierarchical porous structures and catalytic metal-organicframeworks to engineer advanced microparticles for water decontamination.

Keywords： metal-organic framework     polymer microparticle     nanocatalyst     decontamination     organic contaminant    

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Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reduction

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 5,   Pages 570-580 doi: 10.1007/s11705-022-2247-y

Abstract: Recently, metal–organic frameworks are one of the potential catalytic materials for electrocatalyticreduction reaction and oxygen evolution reaction catalytic activities of heterometallic cluster-based organicframeworks are investigated using density functional theory.>2Mn, Fe2Co–PCN–Fe2Co, and isolated Fe2M clusters, the mixed-metalFurthermore, the analysis of the electron structure indicates that constructing a mixed-metal cluster

Keywords： bimetallic metal–organic frameworks     bifunctional electrocatalyst     density functional theory     oxygen    

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Crystalline porous materials: from zeolites to metal-organic frameworks (MOFs)

Zaiku Xie, Bao-Lian Su

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 123-126 doi: 10.1007/s11705-020-1921-1

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Review of plasma-assisted reactions and potential applications for modification of metal–organic frameworks

Tingting Zhao, Niamat Ullah, Yajun Hui, Zhenhua Li

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 3,   Pages 444-457 doi: 10.1007/s11705-019-1811-6

Abstract: involved in dry reforming of methane, CO methanation, the methane coupling reaction, and volatile organicApplications of plasma for modification of metal–organic frameworks are discussed.

Keywords： plasma catalysis     methane     carbon dioxide     VOCs     metal–organic frameworks    

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Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1487-1499 doi: 10.1007/s11705-021-2085-3

Abstract: Developing cost-effective electrocatalysts for oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is vital in energy conversion and storage applications. Herein, we report a simple method for the synthesis of graphene-reinforced CoS/C nanocomposites and the evaluation of their electrocatalytic performance for typical electrocatalytic reactions. Nanocomposites of CoS embedded in N, S co-doped porous carbon and graphene (CoS@C/Graphene) were generated via simultaneous sulfurization and carbonization of one-pot synthesized graphite oxide-ZIF-67 precursors. The obtained CoS@C/Graphene nanocomposites were characterized by X-ray diffraction, Raman spectroscopy, thermogravimetric analysis-mass spectroscopy, scanning electronic microscopy, transmission electronic microscopy, X-ray photoelectron spectroscopy and gas sorption. It is found that CoS nanoparticles homogenously dispersed in the in situ formed N, S co-doped porous carbon/graphene matrix. The CoS@C/10Graphene composite not only shows excellent electrocatalytic activity toward ORR with high onset potential of 0.89 V, four-electron pathway and superior durability of maintaining 98% of current after continuously running for around 5 h, but also exhibits good performance for OER and HER, due to the improved electrical conductivity, increased catalytic active sites and connectivity between the electrocatalytic active CoS and the carbon matrix. This work offers a new approach for the development of novel multifunctional nanocomposites for the next generation of energy conversion and storage applications.

Keywords： MOF derivative     graphene     electrocatalyst     oxygen reduction reaction     oxygen evolution reaction     hydrogen evolution reaction    

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Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 734-746 doi: 10.1007/s11708-022-0840-x

Abstract: a recompilation of the most important and recent strategies employed to increase the efficiency of metal–organicA thorough review and comparison of the results established that metal–nanoparticle@MOF composites haveThus, we conclude that adding SBUs to organic linkers is the most efficient strategy to perform the PHE

Keywords： metal–organic frameworks (MOFs)     photocatalytic hydrogen evolution     MOF heterojunctions     materials derived    

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A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 3, doi: 10.1007/s11783-023-1633-0

Abstract:

● pz-UiO-66 was synthesized facilely by a solvothermal method.

Keywords： Pyrazine     Metal-organic frameworks     Copper removal     Strong acidity     High selectivity    

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An Overview of Metal–Organic Frameworks for Green Chemical Engineering Review

Xiang-Jing Kong, Jian-Rong Li

Engineering 2021, Volume 7, Issue 8,   Pages 1115-1139 doi: 10.1016/j.eng.2021.07.001

Abstract: The boom in metal–organic frameworks (MOFs) and MOF-derived materials in recent years has stimulated

Keywords： Metal-organic frameworks (MOFs)     Application     Green chemical engineering    

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Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 7, doi: 10.1007/s11783-023-1689-x

Abstract:

● Application of the MOF-composite membranes in adsorption was discussed.

Keywords： Emerging organic contaminants     Metal organic frameworks     Synthesis     Adsorption     Catalysis    

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Mixed-Matrix Membranes Containing Porous Materials for Gas Separation: From Metal–Organic Frameworks Review

Ziqi Yang, Zhongjie Wu, Shing Bo Peh, Yunpan Ying, Hao Yang, Dan Zhao

Engineering 2023, Volume 23, Issue 4,   Pages 40-55 doi: 10.1016/j.eng.2022.07.022

Abstract: In this review, we highlight state-of-the-art advances in combining metal–organic frameworks (MOFs) and metal–organic cages (MOCs) with polymeric matrixes to fabricate MMMs using different strategies

Keywords： Gas separation     Metal–organic frameworks     Metal–organic cages     Mixed-matrix membranes     Interfacial compatibility    

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Research progress of defect-engineered UiO-66(Zr) MOFs for photocatalytic hydrogen production

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 656-666 doi: 10.1007/s11708-021-0765-9

Abstract: In recent years, defect-engineered Zr-based UiO-66 metal-organic frameworks (UiO-66(Zr) metal-organicframeworks (MOFs)) have shown huge advantages in catalytic, functional materials, adsorption, and other

Keywords： defect engineering     metal-organic frameworks     UiO-66     photocatalysis    

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Fabrication of MIL-100(Fe)@SiO

Yinlong Hu,Shuang Zheng,Fumin Zhang

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 4,   Pages 534-541 doi: 10.1007/s11705-016-1596-9

Abstract: SiO @Fe O microspheres with a novel core-shell structure were fabricated by the self-assembly of a metal-organic

Keywords： metal-organic frameworks     heterogeneous catalysis     magnetically recoverable catalysts     core-shell structure    

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Title Author Date Type Operation

A ternary mechanism for the facilitated transfer of metal ions onto metal–organic frameworks: implications

Journal Article

Selective capture and separation of xenon and krypton using metal organic frameworks: a review

Journal Article

Metal-organic frameworks for CO

Lei ZHANG, Junqing ZHANG

Journal Article

Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Journal Article

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reduction

Journal Article

Crystalline porous materials: from zeolites to metal-organic frameworks (MOFs)

Zaiku Xie, Bao-Lian Su

Journal Article

Review of plasma-assisted reactions and potential applications for modification of metal–organic frameworks

Tingting Zhao, Niamat Ullah, Yajun Hui, Zhenhua Li

Journal Article

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Journal Article

Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Journal Article

A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

Journal Article

An Overview of Metal–Organic Frameworks for Green Chemical Engineering

Xiang-Jing Kong, Jian-Rong Li

Journal Article

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Journal Article

Mixed-Matrix Membranes Containing Porous Materials for Gas Separation: From Metal–Organic Frameworks

Ziqi Yang, Zhongjie Wu, Shing Bo Peh, Yunpan Ying, Hao Yang, Dan Zhao

Journal Article

Research progress of defect-engineered UiO-66(Zr) MOFs for photocatalytic hydrogen production

Journal Article

Fabrication of MIL-100(Fe)@SiO

Yinlong Hu,Shuang Zheng,Fumin Zhang

Journal Article