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Catalysis of semihydrogenation of acetylene to ethylene: current trends, challenges, and outlook

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1031-1059 doi: 10.1007/s11705-021-2113-3

Abstract: Ethylene is an important feedstock for various industrial processes, particularly in the polymer industryUnfortunately, during naphtha cracking to produce ethylene, there are instances of acetylene presenceAn increase in the reaction temperature affords high acetylene conversion and ethylene selectivity toobtain reactant streams free of ethylene.Conflicting findings to this trend have reported the presence of ethylene in the feed stream.

Keywords: selectivity     hydrogenation     acetylene     ethylene     palladium    

Gas phase ethylene polymerization over SiO

Liuzhong LI, Aiyou HAO, Ruihua CHENG, Boping LIU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1,   Pages 89-95 doi: 10.1007/s11705-010-0558-x

Abstract: In this work, gas phase ethylene polymerization by S-2 catalysts (Cat-1, Cat-2, and Cat-3) was carried

Keywords: UCC S-2 catalyst     Al-alkyl co-catalyst     gas-phase ethylene polymerization     high density polyethylene    

Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction

Jie Gao, Zhikai Li, Mei Dong, Weibin Fan, Jianguo Wang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 5,   Pages 847-856 doi: 10.1007/s11705-019-1848-6

Abstract: Coal-based ethanol production by hydration of ethylene is limited by the low equilibrium ethylene conversionTo improve ethylene conversion, coupling hydration of ethylene with a potential ethanol consumption reactionThe results show that dehydrogenation of ethanol to acetaldehyde has little effect on ethylene conversion, whereas for dehydrogenation of ethanol to acetaldehyde and ethyl acetate, ethylene conversion can beThe esterification of acetic acid with ethanol can greatly enhance the ethylene conversion to 22.5%;

Keywords: ethylene     ethanol     thermodynamics     coupling    

Cerebration and Practice of Expanded feedstock sources for Ethylene units

Cao Xianghong

Strategic Study of Chinese Academy of Engineering 2001, Volume 3, Issue 5,   Pages 35-43

Abstract:

This article starts with the research results that the performance of the ethylene production fromis the by-product of the de-waxing of the vacuum second and third cuts, can be used as feedstock for ethyleneIt proves that the feedstock ensures high ethylene yield and longer service lfie of cracker, thus is

Keywords: ethylene     feedstock     sources    

Modification of polycarbonateurethane surface with poly(ethylene glycol) monoacrylate and phosphorylcholine

Jing YANG,Juan LV,Bin GAO,Li ZHANG,Dazhi YANG,Changcan SHI,Jintang GUO,Wenzhong LI,Yakai FENG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2,   Pages 188-196 doi: 10.1007/s11705-014-1414-1

Abstract: Poly(ethylene glycol) monoacrylate (PEGMA) is grafted onto polycarbonateurethane (PCU) surface via ultraviolet

Keywords: poly(ethylene glycol) monoacrylate     phosphorylcholine     polycarbonateurethane     surface modification     anti-platelet    

Intensification of Ethylene Production from Naphtha via a Redox Oxy-Cracking Scheme: Process Simulations Article

Vasudev Pralhad Haribal,Yun Chen,Luke Neal,Fanxing Li

Engineering 2018, Volume 4, Issue 5,   Pages 714-721 doi: 10.1016/j.eng.2018.08.001

Abstract: margin:0cm 0cm 0.0001pt">Ethyleneproduction by the thermal cracking of naphtha is an energy-intensive process (up to 40 GJ heat per tonne ethylenex), along with 1.8–2 kg of carbon dioxide (CO2) emission per kilogram of ethyleneMoreover, the formation of ethylene and propylene can be enhanced due to the selective combustion ofThe upstream section of the process consumes approximately 67% less energy while producing 28% more ethylene

Keywords: Ethylene     Naphtha cracking     Process intensification     Chemical looping     Process simulations    

Techno-economic evaluation of a biogas-based oxidative coupling of methane process for ethylene production

Alberto T. Penteado, Mijin Kim, Hamid R. Godini, Erik Esche, Jens-Uwe Repke

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 4,   Pages 598-618 doi: 10.1007/s11705-018-1752-5

Abstract: In this sense, the OCM process allows for the direct conversion of methane into ethylene, which is afrom bioethanol industry, is treated for contaminant removal and its methane content is converted into ethylene

Keywords: biogas conversion     ethylene production     oxidative coupling of methane     feasibility study    

Thermal decomposition of poly(ethylene terephthalate)/mesoporous molecular sieve composites

RUN Mingtao, ZHANG Dayu, WU Sizhu, WU Gang

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 50-54 doi: 10.1007/s11705-007-0010-z

Abstract: The nonisothermal and isothermal degradation processes of poly (ethylene terephthalate)/mesoporous molecular

Keywords: polymerization     isothermal degradation     conversion     nonisothermal degradation     activation    

Scheme Study and Strategy on Expansion of Ethylene Plant to 660 kt/a at Yanshan Petrochemical Company

Cao Xianghong

Strategic Study of Chinese Academy of Engineering 2003, Volume 5, Issue 11,   Pages 34-46

Abstract: problems as low feedstock flexibility, high energy consumption and smaller scale as compared to other ethylenebe adjusted with the addition of a propylene compressor and compressor for binary mixture of methane-ethyleneThis revamp has expanded the ethylene capacity to the target of 660 kt/a with the actual capacity reaching

Keywords: ethylene     plant     expansion     scheme     stady    

Determination of the diffusion of poly(ethylene glycol) in polypropylene using ATR-FTIR

Hanjia CHEN, Xuhua SHI, Yafei ZHU, Yi ZHANG, Jiarui XU,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 3,   Pages 336-341 doi: 10.1007/s11705-009-0230-5

Abstract: The diffusion of poly(ethy1ene glycol) (PEG) in polypropylene (PP) was investigated using attenuated total reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), Atomic Force Micrograph (AFM), and Scanning Electron Microscopy (SEM). It has been found that the diffusion of PEG in PP was greatly affected by the annealing temperature and the molecular weight of PEG. Higher temperature was in favor of PEG to diffuse in PP with fast velocity and reached diffusion equilibrium with shorter time. PEG with higher molecular weight was distributed in PP with bigger phase domains and had lower diffusivity, which resulted in its lesser enrichment on the surface of the PP blend film.

Keywords: diffusion     polypropylene     molecular     diffusion equilibrium     attenuated    

Impact of dimethyl ether on engine seal materials

WU Ning, ZHANG Wugao, HUANG Zhen

Frontiers in Energy 2008, Volume 2, Issue 3,   Pages 279-284 doi: 10.1007/s11708-008-0042-1

Abstract: The constitution of ethylene propylene terpolymer rubber (EPDM) has a major impact on its resistance

Keywords: impact     Common polyvinylchloride     different     constitution     ethylene propylene    

rheological, phase morphologic, thermal and mechanical properties of poly(trimethylene terephthalate)/ethylene

RUN Mingtao, SONG Hongzan, WANG Yingjin, YAO Chenguang, GAO Jungang

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 3,   Pages 238-245 doi: 10.1007/s11705-007-0043-3

Abstract: properties of poly(trimethylene terephthalate)/metallocene polyethylene (PTT/mPE) blends in the presence of ethylene

Keywords: /metallocene polyethylene     presence     rheological     phenomena     trimethylene terephthalate    

Influence of accelerated curing on the compressive strength of polymer-modified concrete

Frontiers of Structural and Civil Engineering   Pages 589-599 doi: 10.1007/s11709-022-0789-1

Abstract: study to develop mathematical models for predicting compressive strength of concrete incorporating ethylene

Keywords: compressive strength prediction     polymer-modified concrete     linear regression fit     early age strength     ethylene    

Effects of the SAPO-11 synthetic process on dehydration of ethanol to ethylene

Lina WU, Xiaoxing SHI, Qun CUI, Haiyan WANG, He HUANG

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1,   Pages 60-66 doi: 10.1007/s11705-010-0540-7

Abstract: The effects of the synthetic condition of SAPO-11 molecular sieves on ethanol dehydration to ethyleneProduct-compositions, ethanol conversion, and selectivity to ethylene of synthesized and commercial SAPOAlso, ethanol conversion and selectivity to ethylene reached 99% at 280°C on synthesized SAPO-11, lower

Keywords: SAPO-11 molecular sieves     synthesis     ethanol     ethylene     dehydration    

Recent advances in selective acetylene hydrogenation using palladium containing catalysts

Alan J. McCue, James A. Anderson

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 2,   Pages 142-153 doi: 10.1007/s11705-015-1516-4

Abstract: In both cases enhanced ethylene selectivity is generally associated with modifying ethylene adsorptionselectivity modifiers (i.e., species adsorbed onto Pd particle surface) have also been shown to enhance ethyleneInorganic modifiers such as TiO change Pd ensemble size and modify ethylene adsorption strength whereasare thought to create a surface template effect which favours acetylene adsorption with respect to ethylene

Keywords: acetylene     ethylene     selective hydrogenation     palladium     bimetallic    

Title Author Date Type Operation

Catalysis of semihydrogenation of acetylene to ethylene: current trends, challenges, and outlook

Journal Article

Gas phase ethylene polymerization over SiO

Liuzhong LI, Aiyou HAO, Ruihua CHENG, Boping LIU

Journal Article

Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction

Jie Gao, Zhikai Li, Mei Dong, Weibin Fan, Jianguo Wang

Journal Article

Cerebration and Practice of Expanded feedstock sources for Ethylene units

Cao Xianghong

Journal Article

Modification of polycarbonateurethane surface with poly(ethylene glycol) monoacrylate and phosphorylcholine

Jing YANG,Juan LV,Bin GAO,Li ZHANG,Dazhi YANG,Changcan SHI,Jintang GUO,Wenzhong LI,Yakai FENG

Journal Article

Intensification of Ethylene Production from Naphtha via a Redox Oxy-Cracking Scheme: Process Simulations

Vasudev Pralhad Haribal,Yun Chen,Luke Neal,Fanxing Li

Journal Article

Techno-economic evaluation of a biogas-based oxidative coupling of methane process for ethylene production

Alberto T. Penteado, Mijin Kim, Hamid R. Godini, Erik Esche, Jens-Uwe Repke

Journal Article

Thermal decomposition of poly(ethylene terephthalate)/mesoporous molecular sieve composites

RUN Mingtao, ZHANG Dayu, WU Sizhu, WU Gang

Journal Article

Scheme Study and Strategy on Expansion of Ethylene Plant to 660 kt/a at Yanshan Petrochemical Company

Cao Xianghong

Journal Article

Determination of the diffusion of poly(ethylene glycol) in polypropylene using ATR-FTIR

Hanjia CHEN, Xuhua SHI, Yafei ZHU, Yi ZHANG, Jiarui XU,

Journal Article

Impact of dimethyl ether on engine seal materials

WU Ning, ZHANG Wugao, HUANG Zhen

Journal Article

rheological, phase morphologic, thermal and mechanical properties of poly(trimethylene terephthalate)/ethylene

RUN Mingtao, SONG Hongzan, WANG Yingjin, YAO Chenguang, GAO Jungang

Journal Article

Influence of accelerated curing on the compressive strength of polymer-modified concrete

Journal Article

Effects of the SAPO-11 synthetic process on dehydration of ethanol to ethylene

Lina WU, Xiaoxing SHI, Qun CUI, Haiyan WANG, He HUANG

Journal Article

Recent advances in selective acetylene hydrogenation using palladium containing catalysts

Alan J. McCue, James A. Anderson

Journal Article