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Journal Article 4

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2015 1

2014 1

2011 1

2008 1

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hydrotreating 2

NiMo catalyst 1

activated carbon 1

canola oil 1

catalyst surface 1

co-hydrotreating 1

co-processing 1

differential thermal 1

ex-situ presulfurization 1

fluid petroleum coke 1

general 1

hydrotreating catalyst 1

in situ presulfurization 1

industrial NiW/-AlO 1

light cycle oil (LCO) 1

light gas oil 1

sulfur utilization ratio 1

tungsten phosphide 1

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Co-hydrotreating light cycle oil-canola oil blends

Huali WANG, Hena FAROOQI, Jinwen CHEN

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 1, Pages 64-76 doi: 10.1007/s11705-015-1504-8

Abstract: Canola oil and light cycle oil (LCO) blends were co-hydrotreated over a commercial hydrotreating catalystCompared to the pure LCO, the cetane index of the diesel product formed from hydrotreating the two canola

Keywords： hydrotreating co-hydrotreating co-processing canola oil light cycle oil (LCO)

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Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts

SUN Guida, LI Cuiqing, ZHOU Zhijun, LI Fengyan

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 2, Pages 155-164 doi: 10.1007/s11705-008-0038-8

Abstract: Supported tungsten phosphide catalysts were prepared by temperature-programmed reduction of their precursors (supported phospho-tungstate catalysts) in H and characterized by X-ray diffraction (XRD), BET, temperature-programmed desorption of ammonia (NH-TPD) and X-ray photoelectron spectroscopy (XPS). The reduction-phosphiding processes of the precursors were investigated by thermogravimetry and differential thermal analysis (TG-DTA) and the suitable phosphiding temperatures were defined. The hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activities of the catalysts were tested by using thiophene, pyridine, dibenzothiophene, carbazole and diesel oil as the feedstock. The TiO, -AlO supports and the Ni, Co promoters could remarkably increase and stabilize active W species on the catalyst surface. A suitable amount of Ni (3%–5%), Co (5%–7%) and V (1%–3%) could increase dispersivity of the W species and the BET surface area of the WP/-AlO catalyst. The WP/-AlO catalyst possesses much higher thiophene HDS and carbazole HDN activities and the WP/TiO catalyst has much higher dibenzothiophene (DBT) HDS and pyridine HDN activities. The Ni, Co and V can obviously promote the HDS activity and inhibit the HDN activity of the WP/-AlO catalyst. The G-Ni5 catalyst possesses a much higher diesel oil HDS activity than the sulphided industrial NiW/-AlO catalyst. In general, a support or promoter in the WP/-AlO catalyst which can increase the amount and dispersivity of the active W species can promote its HDS and HDN activities.

Keywords： tungsten phosphide differential thermal catalyst surface industrial NiW/-AlO general

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Development and application of ex-situ presulfurization technology for hydrotreating catalysts in China

Yulan GAO, Xiangchen FANG, Zhenmin CHENG

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3, Pages 287-296 doi: 10.1007/s11705-010-0529-2

Abstract: The development and application of ex-situ presulfurization (EPRES) technology for hydrotreating catalystseffectively reduce the environmental impact as well as the danger of start-up procedure in industrial hydrotreating

Keywords： ex-situ presulfurization in situ presulfurization hydrotreating catalyst sulfur utilization ratio

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Hydrotreating of light gas oil using a NiMo catalyst supported on activated carbon produced from fluid

N. Rambabu,Sandeep Badoga,Kapil K. Soni,A.K. Dalai,J. Adjaye

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2, Pages 161-170 doi: 10.1007/s11705-014-1430-1

Abstract: All of which make it a suitable support material for the preparation of a NiMo hydrotreating catalystHydrotreating activity studies of the NiMo/NAFSAC catalyst were carried out under industrial operatingA parallel study was performed on the hydrotreating activity of NiMo/ -Al O as a reference catalyst.

Keywords： activated carbon fluid petroleum coke NiMo catalyst hydrotreating light gas oil