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Enzyme-instructed self-assembly of peptides containing phosphoserine to form supramolecular hydrogels

Jie Zhou, Xuewen Du, Jiaqing Wang, Natsuko Yamagata, Bing Xu

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 509-515 doi: 10.1007/s11705-017-1613-7

Abstract: Enzyme-instructed self-assembly (EISA) offers a facile approach to explore the supramolecular assembliesConjugating a phosphoserine to the -terminal of a well-established self-assembling peptide backbone,tyrosine in the peptide backbone provides insights on how the specific molecular structures influence self-assembling

Keywords: enzyme-instructed self-assembly     phosphoserine     phosphatase     supramolecular hydrogel    

Supramolecular self-assembly of two-component systems comprising aromatic amides/Schiff base and tartaric

Xin Wang, Wei Cui, Bin Li, Xiaojie Zhang, Yongxin Zhang, Yaodong Huang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 1112-1121 doi: 10.1007/s11705-019-1865-5

Abstract: interactions in -TA systems, which are likely to be the dominant driving forces for the supramolecular self-assemblyAdditionally, it was established that all of the studied gel self-assemblies and mesophases possess a

Keywords: supramolecular self-assembly     organogel     liquid crystal     tartaric acid     hydrogen bond    

Shrink-induced graphene sensor for alpha-fetoprotein detection with low-cost self-assembly and label-free

Shota SANDO, Bo ZHANG, Tianhong CUI

Frontiers of Mechanical Engineering 2017, Volume 12, Issue 4,   Pages 574-580 doi: 10.1007/s11465-017-0485-3

Abstract:

Combination of shrink induced nano-composites technique and layer-by-layer (LbL) self-assembled grapheneIn this study, self-assembled graphene on a shrink polymer substrate exhibits nanowrinkles after heatingapplications for pH and alpha-fetoprotein (AFP) detection with advantages of label free and low cost, due to self-assembly, and therefore the sensor also has a significant potential for biosensing as it relies on low-cost self-assembly

Keywords: graphene     self-assembly     shrink polymer     AFP     label-free     biosensor    

Control on self-assembly structures of rod-coil-rod (PANI)-(PEG)-(PANI) triblock copolymer

YANG Zhifang, WU Jingao, YANG Yingkui, ZHOU Xingping, XIE Xiaolin

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 1,   Pages 85-88 doi: 10.1007/s11705-008-0003-6

Abstract: The self-assembly behaviors of the rod-coil-rod (PANI)-(PEG)-(PANI) triblock copolymer are investigatedThe effects of solvents, concentration and ultrasonic irradiation on self-assembly are discussed.Also, the ultrasonic irradiation has a great effect on the self-assembly of the triblock copolymer.

Keywords: different     multi-layer     mono-layer     dimethyl formamide     concentration    

Two-dimensional self-assembly of melem and melemium cations at pH-controlled aqueous solution–Au(111)

Shinobu Uemura,Kenki Sakata,Masashi Aono,Yusuke Nakamura,Masashi Kunitake

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 294-300 doi: 10.1007/s11705-016-1564-4

Abstract: Two-dimensional self-assembly of melem at pH-controlled aqueous solution-Au(111) interfaces has beenIn the solutions with pH>p of melem, two ordered self-assembled structures (honeycomb and close-packedIn contrast, in the acidic solution with pH

self-assembled honeycomb network was

Keywords: self-assembly     scanning tunneling microscopy     electrochemistry     structural phase transition     melem    

Effects of solvents and temperature on spherulites of self-assembled phloroglucinol tristearate

Yawen Yao, Sabine Rosenfeldt, Kai Zhang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 3,   Pages 389-396 doi: 10.1007/s11705-019-1911-3

Abstract: solvents did not affect the formation of lamellas, the solvents played a crucial role in the formation of self-assembled

Keywords: phloroglucinol     tristearate     aprotic and protic solvent     self-assembly     spherulites    

The construction of pseudo-Janus silica/surfactant assembly and their application to stabilize Pickering

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1101-1113 doi: 10.1007/s11705-021-2095-1

Abstract: Based on the emulsification experimental results, the interaction models and the self-assembly behaviorstudy could help to better understand the construction mechanism of pseudo-Janus silica/surfactant assembly

Keywords: Janus nanoparticles     surfactant     double phase inversion     self-assembly     enhanced oil recovery    

2,5-Dialkoxylphenyl-1,3,4-oxadiazoles as efficient organogelators and their self-assembling property

Zipei SUN,Xuelin DONG,Yan ZHAI,Ziyan Li,Yaodong HUANG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2,   Pages 219-224 doi: 10.1007/s11705-014-1418-x

Abstract: The results indicate that the gelator molecules self-assemble into gels with elongated fibrous networks

Keywords: 1     3     4-oxadiazoles     organogelator     self-assembly    

Ionic strength directed self-assembled polyelectrolyte single-bilayer membrane for low-pressure nanofiltration

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 5,   Pages 699-708 doi: 10.1007/s11705-021-2093-3

Abstract: Layer-by-layer assembly is a versatile technique for fabricating nanofiltration membranes, where multipleIn this work, an ionic strength directed self-assembly procedure is described for the preparation of

Keywords: layer-by-layer self-assembly     single bilayer     nanofiltration membrane     desalination    

Organogelators based on

Yan Zhai,Wei Chai,Wenwen Cao,Zipei Sun,Yaodong Huang

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 4,   Pages 488-493 doi: 10.1007/s11705-015-1503-9

Abstract: Their self-assembly properties and structure-property relationship were investigated by scanning electron

Keywords: p-alkoxylbenzamide     organogelator     self-assembly     gelation    

Self-assembly of metal-cholesterol oxidase hybrid nanostructures and application in bioconversion of

Yu Xin, Qiuyue Gao, Yu Gu, Mengyao Hao, Guangming Fan, Liang Zhang

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 3,   Pages 615-629 doi: 10.1007/s11705-020-1989-7

Abstract: A cholesterol oxidase (COD) was hybridized with Ca , Zn , Al , Fe and Mn . After precipitation with PO at 4 °C for 72 h, the resulting pellets were freeze-dried. In scanning electron microscopy assays, the metal-COD complexes revealed flower-like or granular structures after hybridization. Fourier transform infrared spectroscopy assay revealed the characteristic peaks of both the enzyme and metal materials. X-ray diffraction analysis indicated that COD was encapsulated in CaHPO ·2H O-, Zn (PO ) ·4H O-, AlPO -, FeP - and Mn (PO ) ·3H O-based nanostructures, respectively. Differential scanning calorimetry assay indicated significant increases in thermo-denaturation temperatures from 60.5 °C to 167.02 °C, 167.02 °C, 137.70 °C, 172.85 °C and 160.99 °C, respectively. Using steroid derivatives as substrates, this enzyme could convert cholesterol, pregnenolone, dehydroepiandrosterone, ergosterol, -sitosterol and stigmasterol to related single products. Hybridization in metal-based nanostructures could significantly enhance the initial conversion ratio and reaction stability of the enzyme. In addition, substrate selectivity could be affected by various metal materials. Briefly, using Ca , Zn , Al , Fe and Mn as hybrid raw materials could help to encapsulate COD in related metal-enzyme nanostructures, and could help to promote the stability and tolerant properties of the enzyme, while also enhancing its catalytic characteristics.

Keywords: cholesterol oxidase     metal-enzyme hybridization     nanostructures     sterol derivatives     bioconversion    

Construction of a CaHPO4-PGUS1 hybrid nanoflower through protein-inorganic self-assembly, and its application

Tian Jiang, Yuhui Hou, Tengjiang Zhang, Xudong Feng, Chun Li

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 3,   Pages 554-562 doi: 10.1007/s11705-019-1834-z

Abstract: prepare a CaHPO -PGUS1 hybrid nanoflower for enzyme immobilization, based on protein-inorganic hybrid self-assembly

Keywords: β-glucuronidase     enzyme-inorganic hybrid nanoflower     biotransformation     glycyrrhizin     glycyrrtinic acid 3-O-mono-β-D-glucuronide    

Realization of energy-saving glass using photonic crystals

Yen-Hsiang CHEN, Li-Hung LIAO, Yu-Bin CHEN

Frontiers in Energy 2018, Volume 12, Issue 1,   Pages 178-184 doi: 10.1007/s11708-018-0523-9

Abstract: Each crystal is composed of identical and transparent polystyrene spheres after their self-assembling

Keywords: energy-saving glass     photonic crystals     polystyrene spheres     self-assembly    

Host–Guest Molecular Recognition at Liquid–Liquid Interfaces Review

Beibei Wang, Hao Chen, Tan Liu, Shaowei Shi, Thomas P. Russell

Engineering 2021, Volume 7, Issue 5,   Pages 603-614 doi: 10.1016/j.eng.2021.02.004

Abstract: ;liquid interface endows the interface with unique properties, including stimuli-responsiveness and self-regulation

Keywords: Liquid–liquid interface     Self-assembly     Host–guest chemistry     Microcapsules    

Novel 1,2,3-triazole-based compounds: Iodo effect on their gelation behavior and cation response

Yaodong Huang, Shuxue Liu, Zhuofeng Xie, Zipei Sun, Wei Chai, Wei Jiang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 2,   Pages 252-261 doi: 10.1007/s11705-017-1683-6

Abstract: Two new series of 1,2,3-triazole derivatives, with and without iodo substitution, were synthesized and their gelation properties were measured. It was found that the iodo substitution at position 5 of triazole ring could greatly enhance the gelation ability. Scanning electron microscopy and X-ray diffraction reveal that the structures of the organogels from iodo and hydrogenous gelators are totally different. Iodo gels are selectively responsive to the stimuli of Hg , whereas hydrogenous gels can respond to Hg and Cu . Moreover, the reversible gel-sol transition of hydrogenous gels can be controlled by redox reaction or tuned with suitable chemicals. The single crystal analysis of reference compound ( ) suggests that there are intermolecular and intramolecular non-classical hydrogen bonding interactions but no π-π interaction in hydrogenous gelator. The great difference between the two series of compounds results from the iodo effect and implies the existence of halogen bonding interaction in the iodo compounds.

Keywords: organogelator     1     2     3-triazole derivatives     self-assembly     halogen bonding     cation response    

Title Author Date Type Operation

Enzyme-instructed self-assembly of peptides containing phosphoserine to form supramolecular hydrogels

Jie Zhou, Xuewen Du, Jiaqing Wang, Natsuko Yamagata, Bing Xu

Journal Article

Supramolecular self-assembly of two-component systems comprising aromatic amides/Schiff base and tartaric

Xin Wang, Wei Cui, Bin Li, Xiaojie Zhang, Yongxin Zhang, Yaodong Huang

Journal Article

Shrink-induced graphene sensor for alpha-fetoprotein detection with low-cost self-assembly and label-free

Shota SANDO, Bo ZHANG, Tianhong CUI

Journal Article

Control on self-assembly structures of rod-coil-rod (PANI)-(PEG)-(PANI) triblock copolymer

YANG Zhifang, WU Jingao, YANG Yingkui, ZHOU Xingping, XIE Xiaolin

Journal Article

Two-dimensional self-assembly of melem and melemium cations at pH-controlled aqueous solution–Au(111)

Shinobu Uemura,Kenki Sakata,Masashi Aono,Yusuke Nakamura,Masashi Kunitake

Journal Article

Effects of solvents and temperature on spherulites of self-assembled phloroglucinol tristearate

Yawen Yao, Sabine Rosenfeldt, Kai Zhang

Journal Article

The construction of pseudo-Janus silica/surfactant assembly and their application to stabilize Pickering

Journal Article

2,5-Dialkoxylphenyl-1,3,4-oxadiazoles as efficient organogelators and their self-assembling property

Zipei SUN,Xuelin DONG,Yan ZHAI,Ziyan Li,Yaodong HUANG

Journal Article

Ionic strength directed self-assembled polyelectrolyte single-bilayer membrane for low-pressure nanofiltration

Journal Article

Organogelators based on

Yan Zhai,Wei Chai,Wenwen Cao,Zipei Sun,Yaodong Huang

Journal Article

Self-assembly of metal-cholesterol oxidase hybrid nanostructures and application in bioconversion of

Yu Xin, Qiuyue Gao, Yu Gu, Mengyao Hao, Guangming Fan, Liang Zhang

Journal Article

Construction of a CaHPO4-PGUS1 hybrid nanoflower through protein-inorganic self-assembly, and its application

Tian Jiang, Yuhui Hou, Tengjiang Zhang, Xudong Feng, Chun Li

Journal Article

Realization of energy-saving glass using photonic crystals

Yen-Hsiang CHEN, Li-Hung LIAO, Yu-Bin CHEN

Journal Article

Host–Guest Molecular Recognition at Liquid–Liquid Interfaces

Beibei Wang, Hao Chen, Tan Liu, Shaowei Shi, Thomas P. Russell

Journal Article

Novel 1,2,3-triazole-based compounds: Iodo effect on their gelation behavior and cation response

Yaodong Huang, Shuxue Liu, Zhuofeng Xie, Zipei Sun, Wei Chai, Wei Jiang

Journal Article