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Thermodynamic analysis of reaction pathways and equilibrium yields for catalytic pyrolysis of naphtha

Frontiers of Chemical Science and Engineering   Pages 1700-1712 doi: 10.1007/s11705-022-2207-6

Abstract: length and hydrocarbon type significantly affect the production of light olefins during the catalytic pyrolysisand operation parameters optimization, the reaction pathways and equilibrium yields for the catalytic pyrolysisdevelopment of superior catalysts and the selection of proper operation parameters for the catalytic pyrolysis

Keywords： naphtha     catalytic pyrolysis     reaction pathway     equilibrium yield    

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Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 11, doi: 10.1007/s11783-022-1581-0

Abstract: >

● The co-existing metals in WPCBs has positive catalytic influence in pyrolysis

Keywords： Waste printed circuit board     Catalyst     Pyrolysis     Kinetics    

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Theoretical study on the mechanism of sulfur migration to gas in the pyrolysis of benzothiophene

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 3,   Pages 334-346 doi: 10.1007/s11705-022-2209-4

Abstract: The release and control of sulfur species in the pyrolysis of fossil fuels and solid wastes have attractedthe mechanism of sulfur migration during the release of sulfur-containing radicals in benzothiophene pyrolysisstrong competitiveness of S and SH radicals results in abundant H2S during benzothiophene pyrolysisstudy lays a foundation for elucidating sulfur migration mechanisms and furthering the development of pyrolysis

Keywords： benzothiophene     sulfur migration     pyrolysis     density functional theory    

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Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 7, doi: 10.1007/s11783-021-1488-1

Abstract:

• Adding kaolin/zeolite promotes the formation of stable heavy metals.

Keywords： Co-pyrolysis     Sewage sludge     Heavy metals     Rotary kiln     Immobilization mechanism    

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Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

Frontiers in Energy 2010, Volume 4, Issue 3,   Pages 424-429 doi: 10.1007/s11708-010-0015-z

Abstract: Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed to achieve fast pyrolysis of xylanand on-line analysis of pyrolysis vapors.temperature on pyrolytic products, and to reveal the effect of HZSM-5 and M/HZSM-5 (M= Fe, Zn) zeolites on pyrolysisCatalytic cracking of pyrolysis vapors with HZSM-5 and M/HZSM-5 (M= Fe, Zn) catalysts significantly altered

Keywords： xylan     fast pyrolysis     catalytic pyrolysis     Py-GC/MS     HZSM-5    

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Mechanism insight into the formation of HS from thiophene pyrolysis: A theoretical study

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1404-8

Abstract: ListItem>

• Possible formation pathways of H2S were revealed in thiophene pyrolysis

Keywords： Density functional theory     Waste rubber     Thiophene     H2S     Pyrolysis    

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Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 355-361 doi: 10.1007/s11705-010-0567-9

Abstract: flammable gas, charcoal, wood vinegar, wood tar oil and noncombustible materials with thermo-chemical pyrolysisBased on the data from a straw pyrolysis demonstration project, the mass and heat balance of the biomasspyrolysis process were analyzed.These results showed that the straw pyrolysis project has little risk, and will produce remarkable economic

Keywords： mass balance     heat balance     biomass pyrolysis     economic benefit    

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Upgrading of derived pyrolysis vapors for the production of biofuels from corncobs

Liaoyuan Mao, Yanxin Li, Z. Conrad Zhang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 50-58 doi: 10.1007/s11705-017-1685-4

Abstract: were fast pyrolyzed in the bubbling bed using fine sand particles as a heat carrier and the resulting pyrolysisEven a low usage of zeolite catalyst at WSHV of 180 h was effective in upgrading the pyrolysis oil and

Keywords： corncob     monolith     upgrading     pyrolysis    

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Hydro-pyrolysis of lignocellulosic biomass over alumina supported Platinum, Mo

Songbo He, Jeffrey Boom, Rolf van der Gaast, K. Seshan

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 155-161 doi: 10.1007/s11705-017-1655-x

Abstract: In-line hydro-treatment of bio-oil vapor from fast pyrolysis of lignocellulosic biomass (hydro-pyrolysiswere compared at 500 °C and atmospheric pressure which are same as the reaction conditions for fast pyrolysisResults indicated that under the pyrolysis conditions, the major components, such as acids and carbonyls, of the fast pyrolysis bio-oil can be completely and partially hydrogenated to form hydrocarbons, anhydrocarbon formation (ca. 60%), showing the feasibility of using the cheap non-noble catalysts for hydro-pyrolysis

Keywords： bio-oil     pyrolysis     hydro-deoxygenation (HDO)     non-noble metal catalysts     hydro-treatment    

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Prediction of high-density polyethylene pyrolysis using kinetic parameters based on thermogravimetric

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 1, doi: 10.1007/s11783-023-1606-3

Abstract:

● Reducting the sampling frequency can enhance the modelling process.

Keywords： HDPE     Pyrolysis     Kinetics     Thermogravimetric     ANOVA     Artificial neural network    

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Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1570-3

Abstract:

● Collaborative treatment of plastics and OS was established to improve oil quality.

Keywords： Oily sludge     Pyrolysis     Polyethylene     H/Ceff ratio     Oil quality    

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Particle formation of hydroxyapatite precursor containing two components in a spray pyrolysis process

W. Widiyastuti, Adhi Setiawan, Sugeng Winardi, Tantular Nurtono, Heru Setyawan

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 1,   Pages 104-113 doi: 10.1007/s11705-014-1406-1

Abstract: precursor containing two components, Ca(OOCCH ) and (NH ) HPO with a ratio of Ca/P= 1.67, in a spray pyrolysis

Keywords： droplet     hydroxyapatite particle     CFD     tubular furnace     spray pyrolysis    

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Fabrication of N-doped carbon nanobelts from a polypyrrole tube by confined pyrolysis for supercapacitors

Wei Wang, Haijun Lv, Juan Du, Aibing Chen

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1312-1321 doi: 10.1007/s11705-020-2033-7

Abstract: In this present work, N-doped carbon nanobelts (N-CNBs) were prepared by a confined-pyrolysis approachThe silica layer provided a confined space for the Ppy pyrolysis, thereby hindering the rapid overflowof pyrolysis gas, which is the activator for the formation of carbonaceous materials.This process of confined pyrolysis realizes self-activation during the pyrolysis of Ppy to obtain the

Keywords： carbon nanobelts     polypyrrole     N-doped     confined pyrolysis     supercapacitor    

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Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis

Ying Yan, Peng Huang, Huiping Zhang

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 4,   Pages 772-783 doi: 10.1007/s11705-019-1827-y

Abstract: The specific surface area of the CMSM/PSSF fabricated in different pyrolysis temperature varies fromWhen pyrolysis temperature exceeds 600°C, the specific surface, pore diameter and pore volume decreasedBesides, the degree of graphitization in carbon matrix increased with rising pyrolysis temperature.

Keywords： carbon molecular sieve membrane     stainless steel fibers     pyrolysis     structured fixed bed     toluene    

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Effect of temperature on Lu’an bituminous char structure evolution in pyrolysis and combustion

Yandi ZHANG, Yinhe LIU, Xiaoli DUAN, Yao ZHOU, Xiaoqian LIU, Shijin XU

Frontiers in Energy 2021, Volume 15, Issue 1,   Pages 14-25 doi: 10.1007/s11708-020-0805-x

Abstract: In the process of pyrolysis and combustion of coal particles, coal structure evolution will be affectedsurface of the char particles at 1300°C, and it could be speculated that -Si N was generated in the pyrolysisThe SSA of the chars decreased with the increasing pyrolysis temperature.Inside the char particles, the micropore area and its proportion in the SSA also declined as the pyrolysisFurthermore, the constantly increasing pyrolysis temperature also caused the reactivity of char decrease

Keywords： bituminous char     pyrolysis     ash     structure evolution     reactivity    

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Title Author Date Type Operation

Thermodynamic analysis of reaction pathways and equilibrium yields for catalytic pyrolysis of naphtha

Journal Article

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

Journal Article

Theoretical study on the mechanism of sulfur migration to gas in the pyrolysis of benzothiophene

Journal Article

Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

Journal Article

Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

Journal Article

Mechanism insight into the formation of HS from thiophene pyrolysis: A theoretical study

Journal Article

Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

Journal Article

Upgrading of derived pyrolysis vapors for the production of biofuels from corncobs

Liaoyuan Mao, Yanxin Li, Z. Conrad Zhang

Journal Article

Hydro-pyrolysis of lignocellulosic biomass over alumina supported Platinum, Mo

Songbo He, Jeffrey Boom, Rolf van der Gaast, K. Seshan

Journal Article

Prediction of high-density polyethylene pyrolysis using kinetic parameters based on thermogravimetric

Journal Article

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis

Journal Article

Particle formation of hydroxyapatite precursor containing two components in a spray pyrolysis process

W. Widiyastuti, Adhi Setiawan, Sugeng Winardi, Tantular Nurtono, Heru Setyawan

Journal Article

Fabrication of N-doped carbon nanobelts from a polypyrrole tube by confined pyrolysis for supercapacitors

Wei Wang, Haijun Lv, Juan Du, Aibing Chen

Journal Article

Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis

Ying Yan, Peng Huang, Huiping Zhang

Journal Article

Effect of temperature on Lu’an bituminous char structure evolution in pyrolysis and combustion

Yandi ZHANG, Yinhe LIU, Xiaoli DUAN, Yao ZHOU, Xiaoqian LIU, Shijin XU

Journal Article