Factors influencing the photodegradation of

2009年第3卷第1期

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《环境科学与工程前沿（英文）》 >> 2009年第3卷第1期 doi: 10.1007/S11783-009-0013-8

Factors influencing the photodegradation of

1. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China; 2. State Environmental Protection Key Laboratory for Lake Pollution Control, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; 3. College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083, China

发布日期： 2009-03-05

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摘要

In order to provide basic data for practical application,photodegradation experiment of -nitrosodimethylamine (NDMA) in aqueous solution was carried out with a low-pressure Hg lamp. Effects of the initial concentration of NDMA, solution pH, dissolved oxygen, and the presence of humic acid on NDMA photodegradation were investigated. NDMA at various initial concentrations selected in this study was almost completely photodegraded by UV irradiation within 20 min, except that at 1.07 mmol/L, NDMA could be photodegraded almost completely in the acidic and neutral solutions, while the removal efficiency decreased remarkably in the alkaline solution. Dissolved oxygen enhanced the NDMA photodegradation, and the presence of humic acid inhibited the degradation of NDMA. Depending on the initial concentration of NDMA, NDMA photodegradation by UV obeyed the pseudo-first-order kinetics. Dimethylamine, nitrite, and nitrate were detected as the photodegradation products of NDMA. O was found to be the reactive oxygen species present in the NDMA photodegradation process by UV, based on the inhibiting experiments using tert-butanol and sodium azide.

关键词

N-nitrosodimethylamine (NDMA) ; ultraviolet irradiation ; degradation kinetic ; dimethylamine ; photodegradation product