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《化学科学与工程前沿(英文)》 >> 2021年 第15卷 第1期 doi: 10.1007/s11705-020-1931-z

Long-lasting photoluminescence quantum yield of cesium lead halide perovskite-type quantum dots

. Department of Chemistry, Konkuk University, Seoul 05029, Korea.. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

录用日期: 2020-05-28 发布日期: 2020-05-28

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摘要

Cesium lead halide perovskite (CsPbX , X= Cl, Br, I) quantum dots (QDs) and their partly Mn -substituted QDs (CsPb Mn X ) attract considerable attention owing to their unique photoluminescence (PL) efficiencies. The two types of QDs, having different PL decay dynamics, needed to be further investigated in a form of aggregates to understand their solid-state-induced exciton dynamics in conjunction with their behaviors upon degradation to achieve practical applications of those promising QDs. However, thus far, these QDs have not been sufficiently investigated to obtain deep insights related to the long-term stability of their PL properties as aggregated solid-states. Therefore, in this study, we comparatively examined CsPbX - and CsPb Mn X -type QDs stocked for>50 d under dark ambient conditions by using excitation wavelength-dependent PL quantum yield and time-resolved PL spectroscopy. These investigations were performed with powder samples in addition to solutions to determine the influence of the inter-QD interaction of the aged QD aggregates on their radiative decays. It turns out that the Mn -substituted QDs exhibited long-lasting PL quantum efficiencies, while the unsubstituted CsPbX -type QDs exhibited a drastic reduction of their PL efficiencies. And the obtained PL traces were clearly sensitive to the sample status. This is discussed with the possible interaction depending on the size and distance of the QD aggregates.

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