《工程管理前沿(英文)》 >> 2019年 第6卷 第1期 doi: 10.1007/s42524-019-0001-z
Solvability and thermal response of cellulose with different crystal configurations
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摘要
Cellulose is a biodegradable and renewable natural material that it is naturally resistant to breaking and modification. Moreover, the crystalline structure of cellulose is a major factor restricting its industrial utilization. In this study, cellulose polymorphs were prepared from natural cellulose, and their solvability and thermal response were investigated. Using liquid- and solid-state NMR signals, the distinct types and dissolving states of cellulose polymorphs were identified. The thermal behavior of the polymorphic forms of cellulose-d was also evaluated, and cellulose II exhibited the poorest thermal stability and a unique exothermic reaction.
关键词
cellulose ; crystal structure ; thermal response ; XRD ; CP/MAS 13C NMR