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《工程(英文)》 >> 2021年 第7卷 第9期 doi: 10.1016/j.eng.2020.01.018

双金属羟基氧化物——一种应用于工业相关条件下的高性能水氧化电催化剂

a Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
b Institute of Zhejiang University–Quzhou, Quzhou 324000, China
c State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China
d Department of Electrical Engineering, The Hong Kong Polytechnic University, Hong Kong, China
e School of Chemistry, Physics, and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD 4001, Australia

收稿日期: 2019-07-09 修回日期: 2019-10-28 录用日期: 2020-01-02 发布日期: 2021-06-11

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摘要

开发高电流密度条件下的高性能析氧反应(OER)电催化剂,对于碱性电解水未来清洁能源的商业应用非常重要。鉴于此,我们通过将泡沫镍(NF)浸入Fe(NO3)3溶液,在泡沫镍基底上原位制备了三维(3D)双金属羟基氧化物杂化物(NiFeOOH/NF)。在这种独特的3D结构中,NiFeOOH/NF 杂化物由均匀生长在NF表面的晶态Ni(OH)2和无定形FeOOH物种组成。作为双金属羟基氧化物电催化剂,NiFeOOH/NF杂化物表现出优异的电催化OER活性,其性能不仅超过被报道的其他Ni-Fe 基电催化剂,而且超过商业Ir/C 催化剂。拉曼光谱结果表明,NiFeOOH/NF 杂化物在电催化OER过程中产生的FeOOH和NiOOH物种,被认为是实际的催化活性相。得益于Fe 和Ni 催化位点的协同作用,在严苛的80 ℃、10.0 mol·L1 KOH电解液的工业测试条件下,NiFeOOH/NF杂化物表现出了优异的电催化OER性能,仅需1.47 V和1.51 V的应用电势就能分别达到100 mA·cm2和500 mA·cm2的高催化电流密度。

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