期刊首页 优先出版 当期阅读 过刊浏览 作者中心 关于期刊 English

《中国工程科学》 >> 2010年 第12卷 第1期

酯交换反应在制备生物柴油上的应用

中南大学生物科学与技术学院生物化学系,长沙 410078

资助项目 :湖南省科技计划资助项目( 2008SK4057 ) 收稿日期: 2009-09-30 发布日期: 2010-01-14 11:24:58.000

下一篇 上一篇

摘要

生物柴油因其环境友好且可再生作为矿物柴油的替代燃料而备受关注,生物柴油主要通过均相酸碱催化、脂肪酶催化、超临界法和固体酸碱催化的酯交换反应制备得到,但各种制备方法各有优劣,均相酸碱催化法反应迅速,转化率高但存在后续处理复杂,污染严重等问题;脂肪酶催化法反应条件温和,对原料中的水和游离脂肪酸不敏感,不需要过量的甲醇参与反应,后续处理工序简单,但酶的成本过高,这是制约其商业化发展的最大阻碍;超临界法是制备生物柴油的新技术,反应迅速,不需要催化剂,油脂转化率非常高,但其反应需要高温高压且能耗很大;固体酸碱催化剂

参考文献

[ 1 ] Energy Information Administration: International Energy Outlook 2008 [ DB /OL] .http: //www.eia.doe.gov 链接1

[ 2 ] Zhang Y, DubéM A, McLean D D, et al.Biodiesel production from waste cooking oil: 1.Process design and technological as- sessment [ J] .Bioresource Technology,2003 ,89 :1 -16 链接1

[ 3 ] 建修,刘志平.生物柴油的制备方法及其发展前景[J].化工中间体,2007,(12):25-28 链接1

[ 4 ] 黄斌.生物柴油制备技术研究进展[J].四川化工,2008,(3):25-29 链接1

[ 5 ] Sharma Y C, Singh B.Development of biodiesel: Current sce- nario [ J] .Renew Sustain Energy Rev 2009 ,13 ( 6 -7 ) :1646 - 1651 链接1

[ 6 ] Vicente G, Martínez M, Aracil J.Integrated biodiesel production :a comparison of different homogeneous catalyst systems [ J ] . Bioresource Technology,2004 ,92 :297 -305 链接1

[ 7 ] Kyong -Hwan Chung, Jin Kim, Ki -Young Lee.Biodiesel pro- duction by transesterification of duck tallow with methanol on alka- li catalysts [ J] .Biomass and Bioenergy,2009 ,33 :155 -158 链接1

[ 8 ] 宋吉彬,银建中,张礼鸣.生物柴油制备技术研究进展[J].化工技术与开发,2007,36(9):22-27 链接1

[ 9 ] Shieh C J, Liao H F, Lee C C.Optimization of lipase -catalyzed biodiesel by response surface methodology [ J] .Bioresource Tech- nology, 2003 ,88 :103 -106 链接1

[10] Shimada Yuji, Watanabea Yomi, Samukawab Taichi, et al.Con- version of vegetable oil to biodiesel using immobilized Candida antarctica lipase [ J] .J Am Oil Chem Soc,1999 ,77 :789 -793 链接1

[11] Wei Li, Wei Du, Dehua Liu.Rhizopus oryzae Whole -Cell - Catalyzed Biodiesel Production from Oleic Acid in tert -Butanol Medium [ J] .Energy & Fuels,2008 ,22 :155 -158 链接1

[12] Shinji Hama, Hideki Yamaji, Takahiro Fukumizu.Biodiesel - fuel production in a packed -bed reactor using lipase -producing Rhizopus oryzae cells immobilized within biomass support parti- cles [ J] .Biochemical Engineering Journal,2007 ,34 :273 -278 链接1

[13] Fukuda H, Hama S, Tamalampudi S, et al.Whole -cell biocat- alysts for biodiesel fuel production [ J] .Trends in Biotechnology, 2008 ,26 ( 12 ) :668 -673 链接1

[14] Shinji Hama, Hideki Yamaji, Masaru Kaieda.Effect of fatty acid membrane composition on whole -cell biocatalysts for biodiesel - fuel production [ J ] .Biochemical Engineering Journal, 2004 , 21 :155 -160 链接1

[15] Ayhan Demirbas.Biodiesel from vegetable oils via transesterifica- tion in supercritical Methanol [ J] .Energy Conversion and Man- agement,2002 ,43 :2349 - 2356 链接1

[16] Bunyakiat K, Makmee S, Sawangkeaw R.Continuous Production of Biodiesel via transesterification from Vegetable Oils in Super- critical Methanol [ J] .Energy&Fuels, 2006 ,20 :812 -817 链接1

[17] Furuta Satoshi,Mat suhashi Hiromi ,Arata Kazushi.Biodiesel fuel production with solid superacid catalysis in fixed bed reactor un- der atmospheric pressure [ J] .Catalysis Communications,2005 ,5 ( 12 ) :721 -723 链接1

[18] Furuta Satoshi, Mat suhashi Hiromi, Arata Kazushi.Biodieselfuel production with solid amorphous zirconia catalysis in fixed bed reactor [ J] .Biomass and Bioenergy,2006 ,30 ( 10 ) :870 - 873 链接1

[19] Kulkarni Mangesh G, Gopinat h Rajesh, Meher Lekha Charan, et al.Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification [ J ] .Green Chem, 2006 , 8 ( 12 ) :1056 -1062 链接1

[20] Leclercq E, Finiels A, Moreau C.Transesterification of Rape- seed Oil in the Presence of Basic Zeolites and Related Solid Cata- lysts [ J] .J Amer Oil Chem Soc,2001 ,78 :1161 -1165 链接1

[21] Cantrell D, Gillie G, Lee L J, et al.Structure -reactivity corre- lations in MgAl hydrotalcite catalysts for biodiesel synthesis [ J] . Appl Catal A,2005 ,287 :1983 -1990 链接1

[22] Shumaker J L, Crofcheck C, Tackett S A.Biodiesel production from soybean oil using calcined Li – Al layered double hydroxide catalysts [ J] .Cat Lett, 2007 ,115 :56 -61 链接1

[23] 崔士贞,刘纯山.固体碱催化大豆油酯交换反应的研究[J].工业催化,2005,(7):32-35 链接1

[24] Wimonrat Trakarnpruk, Suriya Porntangjitlikit.Palm oil biodiesel synthesized with potassium loaded calcined hydrotalcite and effect of biodiesel blend on elastomer properties [ J] .Renewable Ener- gy,2008 ,33 :1558 -1563 链接1

[25] Serio Di, Ledda M.Transesterification of soybean oil to biodiesel by using heterogeneous basic catalysts [ J] .Ind Eng Chem Res, 2006 ,45 :3009 -3014 链接1

相关研究