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《中国工程科学》 >> 2013年 第15卷 第2期

固体氧化物电解池共电解H2O/CO2研究进展

中国矿业大学(北京)化学与环境工程学院,煤气化燃料电池联合研究中心,北京 100083

资助项目 :国家重点基础研究发展计划“973计划”资助项目(2012CB215404,2012CB215406);国家自然科学基金资助项目(51110463) 收稿日期: 2012-12-06 发布日期: 2013-01-28 10:49:15.000

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摘要

固体氧化物电解池(SOEC)作为一种新的能源利用方式,可以将电能转化为化学能,具有高效、洁净、环保等优点。本文介绍了固体氧化物电解池的结构特点及其用于H2O/CO2的共电解制备H2和CO的工作原理,综述了固体氧化物电解池的组成形式,以及单片电解池和电解池堆用于H2O/CO2共电解反应的国内外研究进展,并阐述了提高固体氧化物电解池共电解效率所亟需解决的问题。

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参考文献

[ 1 ] Annabelle Brisse,Josef Schefold,Mohsine Zahid. High temperature water electrolysis in solid oxide cells [J]. International Journal of Hydrogen Energy,2008,33:5375-5382. 链接1

[ 2 ] Stephen Herring J,James E O’Brien,Carl M Stoots,et al. Progress in high- temperature electrolysis for hydrogen production using planar SOFC technology [J]. International Journal of Hydrogen Energy,2007,32:440-450.

[ 3 ] Sune Dalgaard Ebbesen,Mogens Mogensen. Electrolysis of carbon dioxide in solid oxide electrolysis cells [J]. Journal of Power Sources,2009,193:349-358. 链接1

[ 4 ] Laguna- Bercero M A. Recent advances in high temperature electrolysis using solid oxide fuel cells:A review [J]. Journal of Power Sources,2012,203:4-16. 链接1

[ 5 ] Mogensen M,Jensen S H,Hauch A,et al. Performance of reversible solid oxide cells [C]// Proceedings of the 7th European SOFC Forum. Lucerne,2006:1-11.

[ 6 ] Christopher Ronald Graves. Recycling CO2 into sustainable hydrocarbon fuels:Electrolysis of CO2 and H2O[D]. New York: Columbia University,2010. 链接1

[ 7 ] Christopher Graves,Sune D Ebbesen,Mogens Mogensen. Coelectrolysis of CO2 and H2O in solid oxide cells:Performance and durability [J]. Solid State Ionics,2011,192:398-403. 链接1

[ 8 ] Carl Stoots,James O’Brien,Joseph Hartvigsen. Results of recent high temperature coelectrolysis studies at the Idaho National Laboratory [J]. International Journal of Hydrogen Energy,2009, 34:4208-4215. 链接1

[ 9 ] Laosiripojana N,Assabumrungrat S. Hydrogen production from steam and autothermal reforming of LPG over high surface area ceria [J]. Journal of Power Sources,2006,158:1348-1357. 链接1

[10] Tatsumi Ishihara, Takao Kannou. Intermediate temperature steam electrolysis using LaGaO3- based electrolyte [J]. Solid State Ionics,2011,192:642-644. 链接1

[11] Laguna-Bercero M A,Skinner S J,Kilner J A. Performance of solid oxide electrolysis cells based on scandia stabilised zirconia [J]. Journal of Power Sources,2009,192:126-131. 链接1

[12] Zhan Zhongliang,Zhao Lin. Electrochemical reduction of CO2 in solid oxide electrolysis cells [J]. Journal of Power Sources, 2010,195:7250-7254. 链接1

[13] Pattaraporn Kim-Lohsoontorn,Yu-Mi Kim,Navadol Laosiripojana,et al. Gadolinium doped ceria-impregnated nickel- yttria stabilised zirconia cathode for solid oxide electrolysis cell [J]. International Journal of Hydrogen Energy,2011,36:9420- 9427. 链接1

[14] Robert D Green,Chung-Chiun Liu,Stuart B Adler. Carbon dioxide reduction on gadolinia- doped ceria cathodes [J]. Solid State Ionics,2008,179:647-660. 链接1

[15] Yang Zhibin,JinChao,Yang Chenghao,etal.Ba0.9Co0.5Fe0.4Nb0.1O3-δ as novel oxygen electrode for solid oxide electrolysis cells [J]. International Journal of Hydrogen Energy,2011,36:11572- 11577. 链接1

[16] Kim-Lohsoontorn P,Brett D J L,Laosiripojana N,et al. Performance of solid oxide electrolysis cells based on composite La0.8Sr0.2MnO3-δ -yttria stabilized zirconia and Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxygen electrodes [J]. International Journal of Hydrogen Energy,2010,35:3958-3966. 链接1

[17] Stoots C M,O’Brien J E,Hartvigsen J. Carbon neutral production of syngas via high temperature electrolytic reduction of steam and CO2 [C]//ASME International Mechanical Engineering Congress and Exposition. Seattle,Washington DC,USA, 2007:185-194. 链接1

[18] Stoots C M,O’Brien J E,Herring J S,et al. Idaho National Laboratory experimental research in high temperature electrolysis for hydrogen and syngas production [C]//Proceedings of the 4th International Topical Meeting on High Temperature Reactor Technology. Washington D C,USA,2008:1-12. 链接1

[19] O’Brien J E,Mckellar M G,Stoots C M,et al. Parametric study of large- scale production of syngas via high-temperature co- electrolysis [J]. International Journal of Hydrogen Energy, 2009,34:4216-4226. 链接1

[20] Stoots C M,O’Brien J E,Hartvigsen J. Results of recent high temperature coelectrolysis studies at the Idaho National Laboratory [J]. International Journal of Hydrogen Energy,2009,34: 4208-4215. 链接1

[21] Stoots C M,O’Brien J E,Herring J S,et al. Syngas production via high-temperature coelectrolysis of steam and carbon dioxide [J]. Journal of FuelCell Science andTechnology,2009(6):11-14. 链接1

[22] O’Brien J E,Mckellar M G,Harvego E A,et al. Hightemperature electrolysis for large- scale hydrogen and syngas production from nuclear energy- summary of system simulation and economic analyses [J]. International Journal of Hydrogen Energy,2010,35:4808-4819. 链接1

[23] O’Brien J E,Stoots C M,Herring J S,et al. High-temperature coelectrolysis of carbon dioxide and steam for the production of syngas,equilibrium model and single-cell tests [C]//International Topical Meeting on the Safety and Technology of Nuclear Hydrogen. Boston,Massachusetts,2007. 链接1

[24] Stoots C,O’Brien J,Hartvigsen J. Carbon neutral production of syngas via high temperature electrolytic reduction of steam and CO2 [C]//2007 ASME International Mechanical Engineering Congress and Exposition. Seattle,Washington,USA,2007:1-10. 链接1

[25] SZren H Jensen,Peter H Larsen,Mogens Mogensen. Hydrogen and synthetic fuel production from renewable energy sources [J]. International Journal of Hydrogen Energy,2007,32: 3253-3257. 链接1

[26] Pattaraporn Kim-Lohsoontorn,Joongmyeon Bae. Electrochemical performance of electrodes under high-temperature coelectrolysis of steam and carbon dioxide [C]//Proceeding of the 9th European Solid Oxide Fuel Cell Forum. Lucerne,Switzerland, 2010:13-26. 链接1

[27] Pattaraporn Kim-Lohsoontorn,Joongmyeon Bae. Electrochemical performance of solid oxide electrolysis cell electrodes under high-temperature coelectrolysis of steam and carbon dioxide [J]. Journal of Power Sources,2011,196:7161-7168. 链接1

[28] Jennifer R Mawdsley,David Carter J,Jeremy Kropf A,et al. Post-test evaluation of oxygen electrodes from solid oxide electrolysis stacks [J]. International Journal of Hydrogen Energy, 2009,34:4198-4207. 链接1

[29] Yue Xiangling,John T S Irvine. Alternative cathode material for CO2 reduction by high temperature solid oxide electrolysis cells [J]. Journal of the Electrochemical Society,2012,159 (8):442-448. 链接1

[30] Li Shisong,Li Yuanxin,Gan Yun,et al. Electrolysis of H2O and CO2 in an oxygen- ion conducting solid oxide electrolyzer with a La0.2Sr0.8TiO3 + δ composite cathode [J]. Journal of Power Sources,2012,218:244-249. 链接1

[31] Zhan Zhongliang,Worawarit Kobsiriphat,James R Wilson, et al. Syngas production by coelectrolysis of CO2/H2O:The basis for a renewable energy cycle [J]. Energy & Fuels,2009,23: 3089-3096. 链接1

[32] Sune Dalgaard Ebbesen, Jens Høgh, Karsten Agersted Nielsen,et al. Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis [J]. International Journal of Hydrogen Energy,2011,36:7363-7373. 链接1

[33] Carl M Stoots,O’Brien J E,Joseph J Hartvigsen. Test results of high temperature steam/CO2 co-electrolysis in a 10-cell stack [C]//Topical International Meeting on Safety and Technology of Nuclear Hydrogen Production, Control, and Management. USA:American Nuclear Society,2007. 链接1

[34] Carl Stoots,Robert O’Brien,Thomas Cable,et al. INL testing of the NASA Bi-electrode supported solid oxide cell as an electrolyzer[C]//Proceedings of 9th European Solid Oxide Fuel Cell Forum. Lucerne,Switzerland,2010:1-12.

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