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《中国工程科学》 >> 2014年 第16卷 第12期

渗透汽化膜技术及其应用

清华大学化工系膜技术工程研究中心,北京 100084

资助项目 :国家自然科学基金项目(21176135);国家863计划项目(2012AA03A607);国家专项资金项目(2013EG111129) 收稿日期: 2014-09-16 发布日期: 2015-01-05 14:06:12.000

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摘要

膜分离技术是当代化工领域的高新技术。由于它是解决人类面临的能源、资源、环境等重大问题的新技术,所以近30多年来取得了极为迅速的发展。渗透汽化膜分离技术是一种新型膜分离技术,是典型的节能技术和清洁生产技术。用于恒沸体系分离,与传统的恒沸蒸馏和萃取精馏相比,节能1/3~1/2,运行费节约至少50 %。本文介绍了国内外渗透汽化脱水膜工业应用情况,并重点介绍了渗透汽化汽油脱硫膜、透甲醇膜、透乙醇膜、透碳酸二甲酯膜、芳烃/烷烃分离膜研究进展及其应用的可能性。

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参考文献

[ 1 ] 高从堦. 膜分离技术与海水淡化和水再用[J]. 水处理信息报导, 2010,(5):1-3,25.

[ 2 ] 徐南平,李卫星,赵宜江,等.面向过程的陶瓷膜材料设计理论 与方法 (I)膜性能与微观结构关系模型的建立[J]. 化工学报, 2003,54(9):1284-1289. 链接1

[ 3 ] 侯立安,高 鑫,赵 兰. 纳滤膜技术净化饮用水的应用研究进 展[J]. 膜科学与技术,2012,32(5):1-7. 链接1

[ 4 ] Raffin M,Germain E,Judd S.Wastewater polishing using membrane technology:A review of existing installations [J]. Environmentan Technology,2013,34(5):617-627. 链接1

[ 5 ] 李继定,陈 剑,叶 宏. 渗透汽化节能膜技术及其在石化领域 中应用[J]. 化工进展,2006,25(增刊):25-29.

[ 6 ] Jonquieres A,Clement R,Lochon P,et al. Industrial state- ofthe- art of pervaporation and vapour permeation in the western countries [J]. Journal of Membrane Science,2002,206 (1-2): 87-117. 链接1

[ 7 ] Smitha B,Suhanya D,Sridhar S,et al. Separation of organic-organic mixtures by pervaporation - a review [J]. Journal of Membrane Science,241(1):1-21. 链接1

[ 8 ] Stefan Sommer,Thomas Melin. Design and optimization of hybrid separation processes for the dehydration of 2- propanol and other organics [J]. Industrial and Engineering Chemistry Researc,2004,43:5248-5259. 链接1

[ 9 ] 李继定,陈翠仙,蒋维钧,等. 渗透汽化从C6溶剂油中脱除微量 水的研究[J]. 膜科学与技术,2000,20(2):15-18. 链接1

[10] Li Jiding,Chen Cuixian,Han Binbing,et al. Labortory and pilot-scale study on dehydration of benzene by pervaporation [J]. Journal of Membrane Science,2002,203:127-136. 链接1

[11] Mortaheb,Hamid Reza,Ghaemmaghami,et al. A review on removal of sulfur components from gasoline by pervaporation [J]. Chemical Engineering Research & Design,2012,90(3A):409- 432. 链接1

[12] 吕宏凌,孔 瑛. 渗透汽化膜材料在汽油脱硫中的研究进展 [J]. 高分子材料科学与工程,2010,26(4):171-174. 链接1

[13] Wang Lihua,Tian Ye,Ding Huaiyu,et al. Microstructure and properties of organosoluble polyimide/silica hybrid films [J]. European Polymer Journal,2006,42 (11):2921-2930. 链接1

[14] Wang Lihua,Zhao Zhiping,Li Jiding,et al. Synthesis and pervaporation performance to gasoline deorganicsulfide of soluble polyimide [J]. Acta Polymerica Sinica,2006,(3):496-499. 链接1

[15] Qi Rongbin,Wang Yujun,Chen Jian,et al. Removing thiophenes from n- octane using PDMS- AgY zeolite mixed matrix membranes [J]. Journal of Membrane Science ,2007,295: 114-120. 链接1

[16] Qi Rongbin,Wang Yujun,Chen Jian,et al. Pervaporative desulfurization of model gasoline with Ag2O- filled PDMS membranes [J]. Separation and Purification Technology,2007,57 (1):170-175. 链接1

[17] Qi Rongbin,Zhao Changwei,Li Jiding,et al. Removal of thiophenes from n- octane/thiophene mixtures by pervaporation [J]. Journal of Membrane Science,2006,269 (1-2):94-100. 链接1

[18] Qi Rongbin,Wang Yujun,Li Jiding,et al. Pervaporation separation of alkane/thiophene mixtures with PDMS membrane [J]. Journal of Membrane Science,2006,280:545-552. 链接1

[19] Qi Rongbin,Wang Yujun,Li Jiding,et al. Sulfur removal from gasoline by pervaporation:The effect of hydrocarbon specie s [J].Separation and Purification Technology,2006,51:258-264. 链接1

[20] Cao Ruijian,Zhang Xiongfei,Wu Hong,et al. Enhanced pervaporative desulfurization by polydimethylsiloxane membranes embedded with silver/silica core-shell microspheres [J]. Journal of Hazardous Materials,2011,187(1-3):324-332. 链接1

[21] Li Ben,Xu Dan,Zhang Xiongfei,et al. Rubbery polymer-inorganic nanocomposite membranes:Free volume characteristics on separation property [J]. Industrial & Engineering Chemistry Research,2010,49(2-4):12444-12451. 链接1

[22] Li Ben,Liu Wanpeng,Wu Hong,et al. Desulfurization of model gasoline by bioinspired oleophilic nanocomposite membranes [J]. Journal of Membrane Science,2012,415:278-287. 链接1

[23] Chen Jian,Li Jiding,Chen Jinxun,et al. Pervaporation separation of ethyl thioether/heptane mixtures by polyethylene glycol membranes [J]. Separation and Purification Technology,2009, 66(3):606-612. 链接1

[24] Chen Jian,Li Jiding,Qi Rongbin,et al. Pervaporation performance of crosslinked polydimethylsiloxane membranes for deep desulfurization of FCC gasoline I. Effect of different sulfur species [J]. Journal of Membrane Science,2008,322:113-121. 链接1

[25] Yang Zhengjin,Zhang Weiyu,Li Jiding,et al. Polyphosphazene membrane for desulfurization:Selecting poly[bis(trifluoroethoxy) phosphazene] for pervaporative removal of thiophene [J]. Separation and Purification Technology,2012,93:15-24. 链接1

[26] Yang Zhengjin,Wang Zhiqiang,Li Jiding,et al. Enhancing FCC gasoline desulfurization performance in a polyphosphazenepervaporative membrane [J]. Separation and Purification Technology,2013,109:48-54. 链接1

[27] Yang Zhengjin,Wang Tao,Zhan Xia,et al. Poly [bis(p-methyl phenyl) phosphazene] pervaporative membranes for separating organosulfur compounds from n- heptane and its surface functionalization [J]. Industrial and Engineering Chemistry Research,2013,52 (38):13801-13809. 链接1

[28] Yang Zhengjin,Zhang Wei,Wang Tao,et al. Improved thiophene solution selectivity by Cu2 + ,Pb2 + and Mn2 + ions in pervaporative poly[bis(p-methyl phenyl) phosphazene] desulfurization membrane [J]. Journal of Membrane Science,2014,454: 463-469. 链接1

[29] Xia Zhan,Li J D,Huang J Q,et al. Enhanced pervaporation performance of multi-layer PDMS/PVDF composite membrane for ethanol recovery from aqueous solution [J]. Applied Biochemistry And Biotechnology,2010,160(2):632-642. 链接1

[30] Han Xiaolong,Wang Lei,Li Jiding,et al. Tuning the hydrophobicity of ZSM-5 zeolites by surface silanization using alkyltrichlorosilane [J]. Applied Surface Science,2011,257:9525- 9531. 链接1

[31] Smitha B,Shaik. A pervaporation-based separation of methanol/ MTBE mixtures - a review [J]. Separation and Purification Reviews,2005,34(1):1-33. 链接1

[32] Wang Luying,Li Jiding,Lin Yangzheng ,et al. Separation of dimethyl carbonate/methanol mixtures by pervaporation with poly(acrylic acid)/poly(vinyl alcohol) blend membranes [J]. Journal of Membrane Science,2007,305:238-246. 链接1

[33] Wang Luying,Li Jiding,Lin Yangzheng ,et al. Crosslinked poly(vinyl alcohol) membranes for separation of dimethyl carbonate/methanol mixtures by pervaporation [J]. Chemical Engineering Journal,2009,146:71-78. 链接1

[34] Wang Lei ,Han Xiaolong,Li Jiding,et al. Separation of azeotropic dimethyl carbonate/methanol mixtures by pervaporation: Sorption and diffusion behaviors in the pure and nano silica filled PDMS membranes [J]. Separation Science and Technology,2011,46:1396-1405. 链接1

[35] Wang Lei,Han Xiaolong,Li Jiding,et al. Hydrophobic nanosilica/ polydimethyl siloxane membrane for dimethylcarbonatemethanol separation via pervaporation [J]. Chemical Engineering Journal,2011,171:1035-1044. 链接1

[36] Ye Hong,Li Jiding,Lin Yangzheng,et al. Preparation and pervaporation performances of PEA- based polyurethaneurea and polyurethaneimide membranes to benzene/cyclohexane mixture [J]. Journal of Macromolecular Science,Part A,2008,45(7): 563-571. 链接1

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