Using crosslinked polyvinyl alcohol polymer membrane as a separator in the microbial fuel cell

2014年第8卷第1期

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《环境科学与工程前沿（英文）》 >> 2014年第8卷第1期 doi: 10.1007/s11783-013-0534-z

Using crosslinked polyvinyl alcohol polymer membrane as a separator in the microbial fuel cell

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1. The Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science & Engineering, Sun Yat-Sen University, Guangzhou 510275, China; 2. South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655, China

发布日期：2014-02-01

摘要

Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system performance. In this study we used polyvinyl alcohol (PVA) polymer membrane crosslinked with sulfosuccinic acid (SSA) as a new separator for the MFC. The highest power density of 759±4 mW·m was obtained when MFC using the PVA membrane crosslinked with 15% of SSA due to its desirable proton conductivity (5.16 × 10 S·cm ). The power density significantly increased to 1106±30?mW·m with a separator-electrode-assembly configuration, which was comparable with glass fiber (1170±46?mW·m ). The coulombic efficiencies of the MFCs with crosslinked PVA membranes ranged from 36.3% to 45.7% at a fix external resistance of 1000 ?. The crosslinked PVA membrane could be a promising alternative to separator materials for constructing practical MFC system.

关键词

microbial fuel cell ; crosslinked polyvinyl alcohol (PVA) membrane ; separator material ; power generation ; coulombic efficiency

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