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Formation of disinfection by-products during sodium hypochlorite cleaning of fouled membranes from membrane

《环境科学与工程前沿（英文）》 2021年第15卷第5期 doi: 10.1007/s11783-021-1389-3

摘要：

•HAAs was dominant among the DBPs of interest.

关键词： MBR Biofouling EPS Chemical cleaning DBPs CLSM

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Using loose nanofiltration membrane for lake water treatment: A pilot study

《环境科学与工程前沿（英文）》 2021年第15卷第4期 doi: 10.1007/s11783-020-1362-6

摘要：

• A pilot study was conducted for drinking water treatment using loose NF membranes.

关键词： Nanofiltration Drinking water Membrane fouling Aluminum carryover Chemical cleaning

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Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning

《化学科学与工程前沿（英文）》 2023年第17卷第10期页码 1450-1459 doi: 10.1007/s11705-023-2310-3

摘要： Membrane technology is ideal for removing aqueous humic acid, but humic acid deposits cause membrane fouling, a significant challenge that limits its application. Herein, this work proposed an alternative approach to the controllably magnetically induced magneto-hybrid polyoxometalate (magneto-HPOM) nanocomposite migration toward the polyethersulfone (PES) membrane surface under a magnetic field to enhance the self-cleaning and antifouling functionalities of the membrane. Before incorporating magneto-HPOM nanocomposite into the PES casting solution, functionalized magnetite nanoparticles (F-MNP) were first coated with HPOM photocatalyst to fabricate a magneto-HPOM-PES membrane. It was shown that the apparent impacts of this novel magneto-HPOM-PES membrane on the hydrophilic behavior and photocatalytic properties of the magneto-HPOM nanocomposite improve the hydrophilicity, separation performance, antifouling and self-cleaning properties of the membrane compared with neat PES membrane. Furthermore, after exposure to ultraviolet light, the magneto-HPOM-PES membrane can be recovered after three cycles with a flux recovery ratio of 107.95%, 100.06%, and 95.56%, which is attributed to the temporal super hydrophilicity effect. Meanwhile, the magneto-HPOM-PES membrane could efficiently maintain 100% humic acid rejection for the first and second cycles and 99.81% for the third cycle. This study revealed a novel approach to fabricating membranes with high antifouling and self-cleaning properties for water treatment.

关键词： magneto-hybrid polyoxometalate nanocomposite composite membrane antifouling self-cleaning magnetic and photocatalytic responsiveness

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Performance of landfill leachate treatment system with disc-tube reverse osmosis units

WANG Baozhen, LIU Shuo, LIU Yanping, LI Xiujin

《环境科学与工程前沿（英文）》 2008年第2卷第1期页码 24-31 doi: 10.1007/s11783-008-0024-x

摘要： Reverse osmosis system with the disc-tube module (DT-RO) was applied to treat landfill leachate on full scale at the Changshengqiao Sanitary Landfill, Chongqing City, China. In the first six-mouth operation phase, the treatment performance of DT-RO system had been excellent and stable. The removal rate of chemical oxygen demand (COD), total organic carbon (TOC), electrical conductivity (EC), and ammonia nitrogen (NH-N) reached 99.2–99.7%, 99.2%, 99.6%, and over 98%, respectively. The rejection of Ca, Ba, and Mg was over 99.9%, respectively. Suspended solid (SS) was not detected in product water. Effective methods had been adopted to control membrane fouling, of which chemical cleaning is of utmost importance to guarantee the long smooth operation of the DT-RO system. The DT-RO system is cleaned in turns with Cleaner A and Cleaner C. At present, the 1st stage cleaning cycle by Cleaner A and Cleaner C is conducted every 100 and 500 h, respectively, depending on raw the water quality.

关键词： chemical cleaning product organic nitrogen Effective

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一种新型的多功能油——清洁润滑防护武器三用油

冯薇荪,汪孟言

《中国工程科学》 2000年第2卷第4期页码 53-58

摘要：

武器三用油是一种不同于传统润滑油的油品。它不仅功能多，而且性能优异，可供陆、海、空三军在各种不同气候条件下使用；也可以广泛用于车辆、船舶、工厂、建筑物等民用设施。由于一种油品同时要具备多种功能，因此必需精心设计配方，考虑不同基础油及各种添加剂的配伍性，扬长避短，发挥增效作用，避免不利因素。在三用油研制过程中，考察了各种影响因素，将矛盾的各个方面很好地统一在一个油品中，获得了能满足各项要求的清洁、润滑、防护武器三用油。

关键词：武器三用油基础油添加剂清洁润滑防护

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A thermodynamic study of the removal of HCl and H

Joseph LEE, Bo FENG

《化学科学与工程前沿（英文）》 2012年第6卷第1期页码 67-83 doi: 10.1007/s11705-011-1162-4

摘要： Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IFGC) systems require high-temperature sorbents that are capable of removing hydrogen chloride and hydrogen sulfide from coal derived gases to very low levels. HCl and H S are highly reactive, corrosive, and toxic gases that must be removed to meet stringent environmental regulations, to protect power generation equipment and to control the emissions of contaminants. The thermodynamic behavior of 13 sorbents for the removal of HCl and H S under various conditions including: initial toxic gas concentration (1–10000 ppm), operating pressure (0.1–11 Mpa), temperature (300 K–1500 K), and the presence of H O were investigated. The correlation between HCl and H S was also examined. Thermodynamic calculations were carried out for the reactions of the 13 sorbents using a FactSage 5.2 software package based on free energy minimization. The sorbents, Na CO , NaHCO , K CO , and CaO are capable of completely removing chlorine at high temperatures (up to ~1240 K) and at high pressures. Water vapor did not have any significant effects on the dechlorination capability of the sorbents. Nine of the sorbents namely; Cu O, Na CO , NaHCO , K CO , CaO, ZnO, MnO, FeO, and PbO, were determined to have great potential as desulfurization sorbents. Cu O and ZnO had the best performance in terms of the optimum operating temperature. The addition of water vapor to the reactant gas produces a slightly detrimental effect on most of the sorbents, but FeO exhibited the worst performance with a reduction in the maximum operating temperature of about 428 K. The dechlorination performance of the alkali sorbents was not affected by the presence of H S in the reactions. However, the desulfurization capability of some sorbents was greatly affected by the presence of HCl. Particularly, the performance of Cu O was significantly reduced when HCl was present, but the performance of FeO improved remarkably. The thermodynamic results gathered are valuable for the developments of better sorbents.

关键词： syngas cleaning sorbent desulfurization dechlorination

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Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

《化学科学与工程前沿（英文）》 2022年第16卷第6期页码 775-776 doi: 10.1007/s11705-022-2172-0

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Special issue on “Green chemical process and intensification”

《化学科学与工程前沿（英文）》 2022年第16卷第11期页码 1533-1535 doi: 10.1007/s11705-022-2263-y

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Insight of chemical environmental risk and its management from the vinyl chloride accident

《环境科学与工程前沿（英文）》 2023年第17卷第4期 doi: 10.1007/s11783-023-1652-x

摘要： The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023 has caused widespread concern around the world. This paper tried to analyze several issues concerning the accident, including the appropriateness of the VC combustion in the emergency response in this accident, the meanings of so-called “controlled combustion”, the potential environmental risks caused by VC and combustion by-products, and follow-up work. In our view, this accident had surely caused environmental and health risks to some extent. Hence, a comprehensive environmental risk assessment is necessary, and then the site with risk should be comprehensively remediated, hazardous waste should be harmlessly treated as soon as possible. Finally, this accident suggests that further efforts should be taken to bridge the gap between chemical safety management and their environmental risk management.

关键词： Vinyl chloride Combustion Chemical safety management Environmental risk Emerging contaminants

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铸钢粗晶的成因及消除方法的研究

邹安全,邓沛然

《中国工程科学》 2005年第7卷第4期页码 79-82

摘要：

通过对ZG32Cr06铸钢粗晶成因的分析及消除粗晶的工艺性能试验，探讨了粗晶导致铸件断裂的机理。试验证明，由于浇铸温度过高，水爆清砂时开箱过早而产生的粗晶可以用热处理方法消除，同时提出了铸件在浇铸时防止粗晶的措施。

关键词：铸钢粗晶水爆清砂消除方法

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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

《环境科学与工程前沿（英文）》 2023年第17卷第10期 doi: 10.1007/s11783-023-1728-7

摘要：

● A higher sulfur content reduced the curing rate of Cr in glass.

关键词： Dechlorinated fly ash SO₃ Heavy metal Chemical speciation Glass solidification

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nanofibre interlayer supported forward osmosis composite membranes and its evaluation in fouling study with cleaning

《环境科学与工程前沿（英文）》 2022年第16卷第9期 doi: 10.1007/s11783-022-1550-7

摘要：

• A fine fibre (40–60 nm diameter) interlayer (~1 µm thickness) was electrospun.

关键词： Forward osmosis Electro-spinning Interfacial polymerisation Fouling Polyvinylidene fluoride

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Evaluation of precipitation behavior of zirconium molybdate hydrate

Liang ZHANG, Masayuki TAKEUCHI, Tsutomu KOIZUMI, Izumi HIRASAWA

《化学科学与工程前沿（英文）》 2013年第7卷第1期页码 65-71 doi: 10.1007/s11705-013-1314-9

摘要： In the dissolution step of spent nuclear fuel, there is a world-concern problem that zirconium molybdate hydrate precipitates as a byproduct, and accumulates in some reprocessing equipments. In order to prevent this accumulation, we have developed a new method based on the controlled reaction crystallization of zirconium molybdate hydrate (ZMH) in the reprocessing solution, followed by solid liquid separation. In order to measure the particle size of ZMH, batch crystallization experiments were conducted by varying nitric acid concentration and operating temperature. In result, almost all particle sizes scatter around 1 μm on average, despite the higher concentration of nitric aid and operating temperature, and then small particles grow up as an aggregate sticking to the crystallizer. Moreover, polymorph and color changing were observed by varying the concentration of nitric acid and reaction time. These results suggest that crystal color and adhesiveness are closely related to the particle size of ZMH. And the control of nitric acid concentration and small particle growth would be the useful technique to prevent the ZMH sticking.

关键词： spent nuclear fuel zirconium molybdate hydrate cleaning method accumulation