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Effects of time-varying liquid bridge forces on rheological properties, and resulting extrudability and

《结构与土木工程前沿（英文）》 2023年 第17卷 第9期   页码 1295-1309 doi: 10.1007/s11709-023-0999-1

摘要： Extrudability and constructability are two important, yet contradictory issues pertaining to the construction of three-dimensional (3D) printing concrete. Extrudability is easily achieved when 3D printing cement mortar has a high water content and low cohesion, but the printed structure is easily collapsible. However, a 3D printing cement mortar with a low water content and high cohesion has a relatively stable printed structure although the cement mortar might not be extrudable. This study proposes a particle-based method to simulate 3D printing mortar extrusion and construction as an overall planning tool for building design. First, a discrete element model with time-varying liquid bridge forces is developed to investigate the microscopic effects of these forces on global rheological properties. Next, a series of numerical simulations relevant to 3D printable mortar extrudability and constructability are carried out. The study demonstrates that the effects of time-varying liquid bridge forces on rheological properties and the resulting extrudability and constructability of 3D printing mortar are considerable. Furthermore, an optimized region that satisfies both the extrusion and construction requirements is provided for 3D printing industry as a reference.

关键词： particle-based simulation     liquid bridge force     rheological property     3D printing mortar     extrudability     constructability    

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Micro-nanoarchitectonic of aluminum-hydrogel propellant with static stability and dynamic rheology

《化学科学与工程前沿（英文）》 2024年 第18卷 第4期 doi: 10.1007/s11705-024-2404-6

摘要： The aluminum-water system is a promising propellant due to high energy and low signal characteristics, and the gel form is easier to store and utilize. In this work, hydrogels of water and aluminum particles were prepared using the low-molecular-weight gellant agarose. The various physical properties of gel systems, including the water loss rate, phase transition temperature, and centrifugal stability at different gellant and aluminum contents, were examined. Rheological properties were assessed through shear thinning tests, thixotropy tests, strain sweep analysis, and frequency sweep experiments. The microstructure of the gel was obtained through scanning electron microscopy images. The results show that the aluminum-hydrogel network structure is composed of micron-scale aluminum and agarose nanosheets, and the unique micro-nanostructure endows the gel with excellent mechanical strength and thermal stability, which improve with increasing gellant and aluminum contents. Notably, the gel with 2% agarose and 20% aluminum had the best performance; the storage modulus reached 90647 Pa, which was within the linear viscoelastic region, and the maximum withstand pressure was 111.2 kPa, which was 118.8% greater than that of the pure hydrogel. Additionally, the gel demonstrates remarkable shear thinning behavior and can undergo gel-sol transformation upon shearing or heating to exceeding 114 °C.

关键词： aluminum-water propellant     gelled propellant     rheological property     mechanical strength    

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Effect of polyethylene glycol on the crystallization, rheology and foamability of poly(lactic acid) containing generated polyamide 6 nanofibrils

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2074-2087 doi: 10.1007/s11705-023-2342-8

摘要： In this study, the rheological properties, crystallization and foaming behavior of poly(lactic acid) with polyamide 6 nanofibrils were examined with polyethylene glycol as a compatibilizer. Polyamide 6 particles were deformed into nanofibrils during drawing. For the 10% polyamide 6 case, polyethylene glycol addition reduced the polyamide 6 fibril diameter from 365.53 to 254.63 nm, owing to the smaller polyamide 6 particle size and enhanced interface adhesion. Rheological experiments revealed that the viscosity and storage modulus of the composites were increased, which was associated with the three-dimensional entangled network of polyamide 6 nanofibrils. The presence of higher aspect ratio polyamide 6 nanofibrils substantially enhanced the melt strength of the composites. The isothermal crystallization kinetics results suggested that the polyamide 6 nanofibrils and polyethylene glycol had a synergistic effect on accelerating poly(lactic acid) crystallization. With the polyethylene glycol, the crystallization half-time reduced from 103.6 to 62.2 s. Batch foaming results indicated that owing to higher cell nucleation efficiency, the existence of polyamide 6 nanofibrils led to a higher cell density and lower expansion ratio. Furthermore, the poly(lactic acid)/polyamide 6 foams exhibited a higher cell density and expansion ratio than that of the foams without polyethylene glycol.

关键词： poly(lactic acid)     foaming     microfibrillation     rheological property     crystallization    

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Properties and printability evaluation of three-dimensional printing magnesium oxychloride cement by fully utilizing aeolian sand

《结构与土木工程前沿（英文）》 2023年 第17卷 第11期   页码 1675-1689 doi: 10.1007/s11709-023-0994-6

摘要： Three-dimensional concrete printing (3DCP) is increasingly being applied in harsh environments and isolated regions. However, the effective utilization of aeolian sand (AS) resources and by-products derived from arid zones for 3DCP is yet to be fully realized. This study developed a three-dimensional (3D) printing composite using AS and magnesium oxychloride cement (MOC) from local materials. The effects of the mole ratio of MgO/MgCl2 and sand/binder (S/B) ratio on the mechanical properties such as water resistance, drying shrinkage strain, rheology, and printability, were investigated systematically. The results indicated that the optimal mole ratio of MgO/MgCl2 was 8, which yielded the desired mechanical performance and water resistance. Furthermore, the S/B ratio can be increased to three within the desired printability to increase the AS utilization rate. The rheological recovery and buildability of the 3D-printed MOC with AS were verified. These findings provide a promising strategy for construction in remote deserts.

关键词： 3DCP     AS     magnesium oxychloride cement     mechanical behavior     drying shrinkage     rheological property    

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Effect of different high viscosity modifiers on rheological properties of high viscosity asphalt

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1390-1399 doi: 10.1007/s11709-021-0775-z

摘要： High viscosity asphalt (HVA) has been a great success as a drainage pavement material. However, the larger porosity of drainage asphalt mixtures weakens the cohesion and adhesion and leads to premature rutting, water damage, spalling and cracking. The purpose of this study was to investigate the rheological properties of HVA prepared using different high viscosity modifiers through conventional tests, Brookfield viscosity tests, dynamic shear rheometer tests and bending beam rheometer tests. The conventional performance results demonstrated SBS + rubber asphalt (SRA-1/2) exhibited excellent elastic recovery and low-temperature flexibility. The 60°C dynamic viscosity results indicated TPS + rubber asphalt (TRA) had the excellent adhesion. The rotational viscosity results and rheological results indicated that SRA-2 not only exhibited excellent temperature stability and workability, as well as excellent resistance to deformation and rutting resistance, but also exhibited excellent low-temperature cracking resistance and relaxation performance. Based on rheological results, the PG classification of HVA was 16% rubber + asphalt for PG76-22, 20% rubber + asphalt for PG88-22, TRA and SRA-1/2 for PG88-28. From comprehensive evaluation of the viscosity, temperature stability and sensitivity, as well as high/low temperature performance of HVA, SRA-2 was found to be more suited to the requirements of drainage asphalt pavement materials.

关键词： high viscosity asphalt     rheological properties     rubber     modifier     viscosity    

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Vibration control of a structure using Magneto-Rheological grease damper

Shinya SUGIYAMA, Tomoki SAKURAI, Shin MORISHITA

《机械工程前沿（英文）》 2013年 第8卷 第3期   页码 261-267 doi: 10.1007/s11465-013-0268-4

摘要：

This paper describes an application study of Magneto-Rheological (MR) grease damper to a structure with three stories. MR fluid is known as one of successful smart materials whose rheological properties can be varied by magnetic field strength, and has been applied to various kinds of device such as dampers, clutches, engine mounts, etc. However, ferromagnetic particles dispersed in MR fluid settle out of the suspension after a certain interval due to the density difference between the particles and their career fluid. To overcome this defect, we have developed a new type of controllable working fluid using grease as the career of magnetic particles. Network of thickener in grease is expected to hold the magnetic particles and prevent them from settled down. No or little sedimentation was observed in MR grease whose characteristics could be controlled by the magnetic field strength. MR grease was introduced into a cylindrical damper and its performance was studied. As a result, it was confirmed that the damping force of MR grease damper could be controlled by the applied electric current to the coil in the cylinder of damper. Furthermore, vibration response of a three-story model structure equipped with MR grease damper was investigated experimentally, and it was shown that MR grease damper worked effectively as a semi-active damper.

关键词： vibration control     damper     smart material     Magneto-Rheological (MR) grease     MR fluid    

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Influence of pressure and density on the rheological properties of rockfills

Erich BAUER, Zhongzhi FU, Sihong LIU

《结构与土木工程前沿（英文）》 2012年 第6卷 第1期   页码 25-34 doi: 10.1007/s11709-012-0143-0

摘要： Long-term deformations of rockfill dams can be related to the type of dam, the pre-compaction achieved during the construction of the dam, the history of loading events, the rheological properties of the rockfill material used, the seepage behavior caused by defects of the sealing, the interactions of the dam building with the foundation, and the hydrothermal phenomena of the stressed rockfill material. The present paper investigates the rheological properties of coarse grained rockfill materials using a hypoplastic constitutive model. Particular attention is paid to wetting deformation under different deviatoric loading states and pre-compactions. To quantify the state of weathering a so-called “solid hardness” is used in the sense of a continuum description. It is shown that an appropriate modeling of wetting deformations requires a unified description of the interaction at least between the state of weathering, the stress state, the density and the rate of deformation. The results obtained from the numerical simulations are compared with available experimental data for a rockfill material used in Xiaolangdi earth dam.

关键词： rockfills     solid hardness     wetting deformation     hypoplasticity     creep    

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Aging properties and aging mechanism of activated waste rubber powder modified asphalt binder based on rheological

《结构与土木工程前沿（英文）》 2023年 第17卷 第4期   页码 625-636 doi: 10.1007/s11709-023-0938-1

摘要： The research and development of high-performance pavement materials has been intensified owing to the demand for long-life pavements. This study is performed to develop a novel pavement material using waste rubber powder, waste lubricating by-product (LBP), and asphalt. Subsequently, the aging properties and aging mechanism of activated waste rubber powder modified asphalt (ARMA) are investigated based on its rheological properties and micro-characterization. The rheological results show that, compared with waste rubber powder modified asphalt (RMA), ARMA offers a higher aging resistance and a longer fatigue life. A comparison and analysis of the rheological aging parameters of ARMA and RMA show that LBP activation diminishes the aging sensitivity of ARMA. The micro-characterization result shows that the aging of ARMA may be caused by the fact that LBP-activated waste rubber powder is more reactive and can form a dense colloidal structure with asphalt. Therefore, the evaporation loss of asphalt light components by heat and the damage to the colloidal structure by oxygen during the aging process are impeded, and the thermal-oxidative aging resistance of ARMA is improved.

关键词： rubber powder modified asphalt     aging     mechanism     rheological     characterization    

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Effect of magneto rheological damper on tool vibration during hard turning

P. Sam PAUL, A. S. VARADARAJAN

《机械工程前沿（英文）》 2012年 第7卷 第4期   页码 410-416 doi: 10.1007/s11465-012-0341-4

摘要：

Recently, the concept of hard turning has gained considerable attention in metal cutting as it can apparently replace the traditional process cycle of turning, heat treating, and finish grinding for assembly of hard wear resistant steel parts. The present investigation aims at developing a magneto rheological (MR) fluid damper for suppressing tool vibration and promoting better cutting performance during hard turning. The magneto rheological Fluid acts as a viscoelastic spring with non-linear vibration characteristics that are controlled by the composition of the magneto rheological fluid, the shape of the plunger and the electric parameters of the magnetizing field. Cutting experiments were conducted to arrive at a set of electrical, compositional and shape parameters that can suppress tool vibration and promote better cutting performance during turning of AISI 4340 steel of 46 HRC with minimal fluid application using hard metal insert with sculptured rake face. It was observed that the use of MR fluid damper reduces tool vibration and improves the cutting performance effectively. Also commercialization of this idea holds promise to the metal cutting industry.

关键词： tool vibration     magneto rheological damper     hard turning     surface finish     tool wear    

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Preparation and rheological behaviors of PA6/SiO2 nanocompiste

WEI Shanshan, LIU Yuejun, LI Xianggang, HUANG Yugang, WANG Xiayu, ZHANG Ping

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 332-337 doi: 10.1007/s11705-007-0060-2

摘要： The polyamide 6 (PA6)/SiO nanocomposites were prepared by in situ polymerization and the rheological behaviors were investigated. The morphology of resultant materials was characterized by scanning electron microscopy (SEM) and the rheological behaviors were characterized by capillary rheometer. The results showed that the SiO particle size was around 50 nm and the particles dispersed evenly in PA6 matrix. The nanocomposites were pesudoplastic fluids and the apparent viscosities of nanocomposites increased initially and then decreased with the increase in nano-SiO content at the same temperature. The non-Newtonian indexes of nanocomposites were smaller than those of pure PA6. With the increase in nano-SiO content the apparent viscous activation energies of nanocomposites increased initially and then decreased. The rheological behaviors revealed that there were strong interactions between PA6 macromolecule chains and nano-SiO particles.

关键词： polyamide     temperature     rheological     activation     pesudoplastic    

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Investigation of effects of Cocamide Diethanolamide chemical on physical and rheological properties of

《结构与土木工程前沿（英文）》 2022年 第16卷 第1期   页码 99-116 doi: 10.1007/s11709-021-0799-4

摘要： In this study, bituminous binder was modified with Cocamide Diethanolamide chemical, a non-ionic surfactant, and the physical and rheological properties of modified binders were investigated. In addition, Cocamide Diethanolamide has been used for the first time to modify bituminous binder, and this situation makes the study distinctive. Bituminous binder was modified more than once with the chemical by changing modification parameters and using certain additive ratios (1%, 3%, and 5%). The effects of different modification parameters and chemical additive on modified samples were investigated with conventional bitumen tests (softening point, penetration, ductility) and Superpave tests (rotational viscometer, rolling thin film oven test, pressure aging vessel, dynamic shear rheometer, bending beam rheometer). In addition, the structural characteristics of the reference binder and modified samples were examined by X-ray diffraction, Fourier Transform Infrared Spectroscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy. The examinations showed that Cocamide Diethanolamide softens bituminous binder and lowers processing temperatures. In addition, compared to reference binder, rutting resistances of modified bituminous binders decreased with the increase of additive ratio. However, modification with Cocamide Diethanolamide increased the resistance to fatigue cracks and thermal cracks.

关键词： Cocamide Diethanolamide     bitumen modification     rheology     Superpave tests    

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Studies on the rheological, phase morphologic, thermal and mechanical properties of poly(trimethylene

RUN Mingtao, SONG Hongzan, WANG Yingjin, YAO Chenguang, GAO Jungang

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 238-245 doi: 10.1007/s11705-007-0043-3

摘要： The rheological, phase morphologic, thermal and mechanical properties of poly(trimethylene terephthalate)/metallocene polyethylene (PTT/mPE) blends in the presence of ethylene propylene diene monomer copolymer grafted with maleic anhydride (EPDM--MAH) as compatibilizer are studied by means of a capillary rheometer, scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). Results suggest that the compatibility of PTT/mPE blends is improved greatly after the addition of a compatibilizer. The radius of the dispersed phase in the system decreases greatly when the compatibilizer is added into the blend. When the amount of compatibilizer exceeds 8 wt-%, the size of dispersed phase becomes larger again. This phenomena could be attributed to the higher viscosity of the EPDM--MAH phase, which is dispersed more difficulty in the PTT phase of lower viscosity, thus the mixing efficiency is apparently decreased during the melt blending process. Moreover, the melt viscosity of the blend reaches the maximal value in case of 4 wt-% compatibilizer content, above which it would decrease again. This result is associated with the generation of more and bigger dispersed phase inside the bulk phase, thus the grafting efficiency at the interface is decreased, which could result in lower viscosity. The DSC results suggest that the mPE component shows a nucleating effect, and could increase the overall degree and rate of PTT crystallization, while the addition of a compatibilizer might slightly diminish these effects. In addition, the blend with 4 wt-% compatibilizer shows the best thermal stability. Furthermore, the Izod impact strength and the tensile strength at room temperature of the blend are also markedly improved by the addition of a 4 8 wt-% compatibilizer.

关键词： /metallocene polyethylene     presence     rheological     phenomena     trimethylene terephthalate    

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Influence of morphology on high-temperature rheological properties of bitumen modified with styrene-butadiene-styrene

《结构与土木工程前沿（英文）》 2021年 第15卷 第3期   页码 806-819 doi: 10.1007/s11709-021-0731-y

摘要： Different microstructures of the same polymer-modified bitumen (PMB) were obtained by subjecting the bitumen modified with styrene-butadiene-styrene (SBS) copolymer to isothermal annealing at various temperatures. The effects of the morphology on the rheological properties of SBS-modified bitumen were investigated within the high-temperature range. The PMB microstructures were quantitatively evaluated using image analysis. A dynamic shear rheometer was used to measure the rheological parameters of the PMB samples and perform the multiple stress creep and recovery (MSCR) test. A quantitative basis could be established on which to discuss the relationship between the PMB morphology and rheology. The image analysis indicated that conditioning by isothermal annealing evidently led to a difference in the microstructure of the samples. Variation of the thermal history is demonstrated to be a practical way to vary the morphology of the PMB with the same raw materials and formulation. Compared with the two-phase morphology, the single-phase microstructure tended to have a narrower linear viscoelastic (LVE) region of the PMB. Within the LVE region, especially at low frequencies, the homogenous PMB can store more energy when experiencing loadings and is more elastic. Outside the LVE region, based on the MSCR test results, the homogenous morphology could assist in reaching a higher percentage of strain recovery after the creep period.

关键词： polymer     bitumen     microstructure     rheology     viscoelasticity    

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Rheological behavior of mixed system of ionic liquid [C

Zimeng HE,Ling YUE,Meng LI,Yazhuo SHANG,Honglai LIU

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 232-241 doi: 10.1007/s11705-015-1511-9

摘要： We report on the rheological behavior of wormlike micelles constructed by ionic liquid surfactant [C mim]Br (1-octyl-3-methylimidazolium bromide) and anionic surfactant sodium oleate (NaOA) in aqueous solution. The effects of surfactant composition, total surfactant concentration, added salts, and temperature were investigated. The prevailing surfactant effect at lower concentration and the leading cosolvent effect at higher concentration of [C mim]Br may be the main reasons for appearance of well-established maximum in key rheological parameters with variation of surfactant composition and total surfactant concentration. The Cole-Cole plots demonstrate that the systems (total surfactant concentration falls within 0.17–0.35 mol·L and molar ratio 0.33≤ ≤0.50) fit the Maxwell’s mechanical model as linear viscoelastic fluid. The addition of NaBr or sodium salicylate decreases significantly the viscosity and the relaxation time of the wormlike micelle solution but cannot change the value of plateau modulus . The present system has low rheological tolerance to temperature. The increase of temperature decreases the average contour length and viscosity of wormlike micelles and thus strengthens the relaxation progress of diffusion and weakens the relaxation progress of reptation. Increasing the temperature also decreases the value of plateau modulus and shifts the minimum value of the loss modulus to higher frequencies.

关键词： rheological behavior     ionic liquid surfactant     sodium oleate     wormlike micelles     viscoelasticity    

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A computational toolbox for molecular property prediction based on quantum mechanics and quantitativestructure-property relationship

《化学科学与工程前沿（英文）》 2022年 第16卷 第2期   页码 152-167 doi: 10.1007/s11705-021-2060-z

摘要： Chemical industry is always seeking opportunities to efficiently and economically convert raw materials to commodity chemicals and higher value-added chemical-based products. The life cycles of chemical products involve the procedures of conceptual product designs, experimental investigations, sustainable manufactures through appropriate chemical processes and waste disposals. During these periods, one of the most important keys is the molecular property prediction models associating molecular structures with product properties. In this paper, a framework combining quantum mechanics and quantitative structure-property relationship is established for fast molecular property predictions, such as activity coefficient, and so forth. The workflow of framework consists of three steps. In the first step, a database is created for collections of basic molecular information; in the second step, quantum mechanics-based calculations are performed to predict quantum mechanics-based/derived molecular properties (pseudo experimental data), which are stored in a database and further provided for the developments of quantitative structure-property relationship methods for fast predictions of properties in the third step. The whole framework has been carried out within a molecular property prediction toolbox. Two case studies highlighting different aspects of the toolbox involving the predictions of heats of reaction and solid-liquid phase equilibriums are presented.

关键词： molecular property     quantum mechanics     quantitative structure-property relationship     heat of reaction     solid-liquid phase equilibrium    

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标题 作者 时间 类型 操作

Effects of time-varying liquid bridge forces on rheological properties, and resulting extrudability and

期刊论文

Micro-nanoarchitectonic of aluminum-hydrogel propellant with static stability and dynamic rheology

期刊论文

Effect of polyethylene glycol on the crystallization, rheology and foamability of poly(lactic acid) containing generated polyamide 6 nanofibrils

期刊论文

Properties and printability evaluation of three-dimensional printing magnesium oxychloride cement by fully utilizing aeolian sand

期刊论文

Effect of different high viscosity modifiers on rheological properties of high viscosity asphalt

期刊论文

Vibration control of a structure using Magneto-Rheological grease damper

Shinya SUGIYAMA, Tomoki SAKURAI, Shin MORISHITA

期刊论文

Influence of pressure and density on the rheological properties of rockfills

Erich BAUER, Zhongzhi FU, Sihong LIU

期刊论文

Aging properties and aging mechanism of activated waste rubber powder modified asphalt binder based on rheological

期刊论文

Effect of magneto rheological damper on tool vibration during hard turning

P. Sam PAUL, A. S. VARADARAJAN

期刊论文

Preparation and rheological behaviors of PA6/SiO2 nanocompiste

WEI Shanshan, LIU Yuejun, LI Xianggang, HUANG Yugang, WANG Xiayu, ZHANG Ping

期刊论文

Investigation of effects of Cocamide Diethanolamide chemical on physical and rheological properties of

期刊论文

Studies on the rheological, phase morphologic, thermal and mechanical properties of poly(trimethylene

RUN Mingtao, SONG Hongzan, WANG Yingjin, YAO Chenguang, GAO Jungang

期刊论文

Influence of morphology on high-temperature rheological properties of bitumen modified with styrene-butadiene-styrene

期刊论文

Rheological behavior of mixed system of ionic liquid [C

Zimeng HE,Ling YUE,Meng LI,Yazhuo SHANG,Honglai LIU

期刊论文

A computational toolbox for molecular property prediction based on quantum mechanics and quantitativestructure-property relationship

期刊论文