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Saline-alkali soil reclamation and utilization in China: progress and prospects REVIEW

《农业科学与工程前沿（英文）》 2024年第11卷第2期页码 216-228 doi: 10.15302/J-FASE-2024551

摘要：

Soil salinity is a global threat to the productivity of arable land. With the impact of population growth and development of social economy in China, the area of arable land has been shrinking in recent decades and is approaching a critical threshold of 120 Mha, the minimum area for maintaining the national food security. Saline-alkaline land, as important backup reserve, has been receiving increased attention as an opportunity to expand land resources. This review first summarizes the general principles and technologies of saline soil reclamation to support plant growth, including leaching salts or blocking the rise of salts, and soil fertility enhancement to improve the buffering capacity. Then the progress in this area in China is described including the customization of technologies and practices used in different saline-alkali regions. Following the soil management strategies, the concept of selecting crops for saline soil is proposed. This encompasses halophyte planting, salt-tolerant crop breeding and the application of saline-adapted functional microorganisms to improve the adaptation of crops. Finally, the current problems and challenges are evaluate, and future research directions and prospects proposed for managing this major soil constraint.

关键词： Food security land reserve reclamation saline-alkali soil utilization

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黄河三角洲滨海盐碱地可持续利用的水土资源约束与均衡配置策略

左强,吴训,石建初,王全九,刘兆辉,朱安宁,尹冬勤,冯权泷,纪文君,康绍忠

《中国工程科学》 2023年第25卷第4期页码 169-179 doi: 10.15302/J-SSCAE-2023.07.028

摘要：

基于现有耕地优势并开发利用好各类后备耕地资源，对确保国家粮食与生态安全意义重大。黄河三角洲（黄三角）盐碱地后备耕地资源丰富，农业开发利用潜力巨大，但因水资源短缺、水土资源配置不平衡而制约了高效可持续利用。本文梳理了黄三角滨海盐碱地治理利用与种植业发展现状，详细分析了地区水土资源条件，从水资源供应、地下水位调控、治理利用体系、科技创新及运行管理等方面明晰了发展挑战。提出的水土资源高效可持续利用与均衡配置策略为：适度增加引黄配额并实施滨海入海河道水系联通工程以优化调配区域水资源，启动高标准灌排体系完善与配套建设工程以促进耕地提质增效，加快盐碱地治理利用关键技术集成示范推广以发挥科技支撑作用。相关成果可为我国滨海盐碱地综合治理与高效利用、农业可持续发展等研究提供启发和参考。

关键词：黄河三角洲；滨海盐碱地；治理与利用；水土资源配置；农业可持续发展

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Adsorption and desorption of steroid hormones on saline soil

《环境科学与工程前沿（英文）》 2022年第16卷第11期 doi: 10.1007/s11783-022-1575-y

摘要：

● Organic matter content significantly affected adsorption of E2/EE2 on saline soil.

关键词： Saline soil Steroid hormones Adsorption Desorption Soil organic matter

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Analysis of mobilization of inorganic ions in soil by electrokinetic remediation

Xiaojing LI, Lige WANG, Xueming SUN, Yuansheng CONG

《结构与土木工程前沿（英文）》 2019年第13卷第6期页码 1463-1473 doi: 10.1007/s11709-019-0569-8

摘要： Saline soil has imposed a serious threat on many expressway engineering and agricultural areas. This paper describes the performance of saline soil treatment using electrokinetic remediation technology. Comparison study involving sample soil and soil is carried out. Two different electric fields, i.e., uniform and non-uniform are utilized to promote the migration of inorganic ions contained in the soil toward the electrode area. The effects of different electric field types and potential gradient ion migration rate in soil are investigated. The test result reveals that a uniform electric field of a constant potential gradient of 1 V/cm drives the Cl through the sample soil at a rate of 1.36 cm/h. Moreover, larger potential gradients could make ions migrate faster, but more electrical energy is consumed in such a way. Compared with uniform electric field, the non-uniform process maintains the soil pH values more effectively and consumes less electrical energy. A desirable result of removing Na in soil is expected using electrokinetic remediation technology under four-times scaling up of soil volume.

关键词： electromigration electric fields saline soil soil-remediation

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Process study on adsorption of glycerin from saline wastewater by strong base anion resin

Haitao ZHANG, Xiaoqing MA, Xian QU, Jeanpierre Arcangeli

《化学科学与工程前沿（英文）》 2011年第5卷第1期页码 113-116 doi: 10.1007/s11705-010-0547-0

摘要： A physicochemical method was used to adsorb glycerin in saline wastewater by strong base anion resin (D201). Boric acid, a kind of weak acid, can combine with glycerin, and a specific complex can be produced, which possess bigger molecule than glycerin. Then, this specific complex could be adsorbed by strong base anion resin. Via the experiment, the equation of adsorption isotherm with D201 at 20°C can be shown by lg / = 1.74lg - 5.72; for column test with simulative glycerin wastewater, the treatment capability was more than nine bed volumes, and 39.77 mg glycerin could be removed by per gram resin. When the NaCl concentration was 10 g/L, five bed volumes of simulative wastewater could be treated, and the adsorb mass was 29.09 mg/g. When the NaCl concentration was 30 g/L, only three bed volumes of simulative wastewater could be treated, and the adsorb mass was 14.83 mg/g.

关键词： glycerin anion resin boric acid wastewater NaCl

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Layered alkali titanates (ATiO): possible uses for energy/environment issues

《能源前沿（英文）》 2021年第15卷第3期页码 631-655 doi: 10.1007/s11708-021-0776-6

摘要： Uses of layered alkali titanates (A₂Ti_nO₂_n₊₁; Na₂Ti₃O₇, K₂Ti₄O₉, and Cs₂Ti₅O₁₁) for energy and environmental issues are summarized. Layered alkali titanates of various structural types and compositions are regarded as a class of nanostructured materials based on titanium oxide frameworks. If compared with commonly known titanium dioxides (anatase and rutile), materials design based on layered alkali titanates is quite versatile due to the unique structure (nanosheet) and morphological characters (anisotropic particle shape). Recent development of various synthetic methods (solid-state reaction, flux method, and hydrothermal reaction) for controlling the particle shape and size of layered alkali titanates are discussed. The ion exchange ability of layered alkali titanate is used for the collection of metal ions from water as well as a way of their functionalization. These possible materials design made layered alkali titanates promising for energy (including catalysis, photocatalysts, and battery) and environmental (metal ion concentration from aqueous environments) applications.

关键词： layered alkali titanates photocatalysis hydrogen evdution metal ions collection

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碱硅酸反应与碱碳酸盐反应

唐明述

《中国工程科学》 2000年第2卷第1期页码 34-40

摘要：

碱集料反应（AAR）可分为两类，即碱硅酸反应（ASR）与碱碳酸盐反应（ACR）。二者的共同点是与碱发生的化学反应可导致混凝土中集料的体积增大，从而可能使混凝土甚至整个建筑物或构筑物发生膨胀开裂。文章着重从膨胀过程和机理以及岩石的结构特征探讨二者的特性与差异。ASR类型岩石具有碱活性的前提条件是较低的二氧化硅结晶完整度。只有隐晶质、微晶质、玻璃质或发生过应变的二氧化硅才会具有较高的化学活性，导致混凝土破坏。通过系统研究证实，对碱碳酸盐反应，虽然结晶的完整程度以及白云石（CaCO₃·MgCO₃）分子式中Ca/Mg比也将影响其与碱反应的速率，但起决定作用的是白云石晶体的尺寸及其在岩石中的分布状态和被基质包围的紧密程度。从微观结构得出的这些特征将有助于加深对碱集料反应膨胀机理的认识。文中还介绍了形成活性白云石的地质环境和碱硅酸反应与碱碳酸盐反应的区分方法。

关键词：碱集料硅酸碳酸盐混凝土开裂机理

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The development of ultralightweight expanded perlite-based thermal insulation panel using alkali activator

Damla Nur ÇELİK; Gökhan DURMUŞ

《结构与土木工程前沿（英文）》 2022年第16卷第11期页码 1486-1499 doi: 10.1007/s11709-022-0881-6

摘要： The International Energy Agency (IEA) states that global energy consumption will increase by 53% by 2030. Turkey has 70% of the world’s perlite reserves, and in order to reduce energy consumption a thermal insulation panel was developed in Turkey using different particle sizes of expanded perlite (EP). In this study, 0–1.18 mm (powder) and 0–3 mm (granular) EP particle sizes were selected, since they have the lowest thermal conductivity coefficients among all the particle sizes. In addition, an alkali activator solution was used as a binder in the mixtures. The alkaline activator solution was obtained by mixing sodium hydroxide solution (6, 8, 10, and 12 mol·L⁻¹) and sodium silicate (Module 3) at the different ratios of Na₂SiO₃ to NaOH of 1, 1.5, 2, and 2.5. This study aimed to experimentally determine the optimum binder and distribution ratio of EP, with the lowest coefficient of thermal conductivity and the lowest density. The lowest thermal conductivity and the lowest density were determined as 0.04919 W·m⁻¹·K⁻¹ and 133.267 kg/m³, respectively, in the sample prepared with 83.33% powder-size EP, 6 mol·L⁻¹ sodium hydroxide solution, and ratio of Na₂SiO₃ to NaOH of 1.5. The density, thermal conductivity, and compressive strength of the sample showed the same trends of behavior when the Na₂SiO₃ to NaOH ratio was increased. In addition, the highest compressive strength was measured in 12 mol·L⁻¹ NaOH concentration regardless of particle size. In conclusion, the study predicts that the EP-based thermal insulation panel can be used as an insulation material in the construction industry according to the TS825 Thermal Insulation Standard.

关键词： expanded perlite alkali activator thermal insulation panel thermal conductivity

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基于BH-1模拟月壤的低碱高强地聚合物的制备与表征 Article

周思齐, 鲁乘鸿, 朱兴一, 李峰

《工程（英文）》 2021年第7卷第11期页码 1631-1645 doi: 10.1016/j.eng.2020.10.016

摘要：

建设月球基地以支持月面科研任务和资源利用一直是各国研究人员的目标。使用月球材料进行原位资源利用制备建筑材料对于节省昂贵的太空运费具有重要意义。本文研制了一种新型模拟月壤，名为北航（BH）-1。通过X射线荧光光谱（XRF）、X射线衍射（XRD）、扫描电子显微镜（SEM）和反射光谱结果证实，BH-1 的化学矿物组成和微观结构与真实月壤非常相似。本研究还在模拟月球环境条件下合成了一种基于BH-1 模拟月壤的地聚合物，并研究了补充铝源对地聚合物强度的影响。测定了碱激发BH-1 浆体的流变性能。采用XRF、XRD、傅里叶红外光谱、SEM能谱分析和27Al 魔角旋转核磁共振分析对地聚合物进行表征。试验结果表明，BH-1 浆体的流变曲线符合Herschel-Bulkley 模型，表现为剪切变稀流体。添加铝源的BH-1 地聚合物与对照组相比，28 天抗压强度可提高100.8%。同时，产生单位强度所需的添加剂的质量降低，显著减少了从地球运输至月球用于地聚合物制备的材料质量，有望节约太空运输成本。微观实验分析表明，通过添加额外的铝源来改善BH-1 地聚合物的力学性能机理为：促进了硅氧基中铝原子基团对硅原子基团的取代作用，生成更致密的无定形凝胶结构。

关键词：深空探测月球基地地聚合物模拟月壤流变学

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Biological removal of selenate in saline wastewater by activated sludge under alternating anoxic/oxic

Yuanyuan Zhang, Masashi Kuroda, Shunsuke Arai, Fumitaka Kato, Daisuke Inoue, Michihiko Ike

《环境科学与工程前沿（英文）》 2019年第13卷第5期 doi: 10.1007/s11783-019-1154-z

摘要： Removal of selenate in saline wastewater by activated sludge was examined. Sequencing batch reactor was operated under alternating anoxic/oxic conditions. Above 97% removal of soluble selenium (Se) was achieved continuously. Major Se removal mechanism varied depending on the length of aeration period. Various Se-reducing bacteria likely contributed to coordinately to Se removal. Selenium (Se)-containing industrial wastewater is often coupled with notable salinity. However, limited studies have examined biological treatment of Se-containing wastewater under high salinity conditions. In this study, a sequencing batch reactor (SBR) inoculated with activated sludge was applied to treat selenate in synthetic saline wastewater (3% w/v NaCl) supplemented with lactate as the carbon source. Start-up of the SBR was performed with addition of 1–5 mM of selenate under oxygen-limiting conditions, which succeeded in removing more than 99% of the soluble Se. Then, the treatment of 1 mM Se with cycle duration of 3 days was carried out under alternating anoxic/oxic conditions by adding aeration period after oxygen-limiting period. Although the SBR maintained soluble Se removal of above 97%, considerable amount of solid Se remained in the effluent as suspended solids and total Se removal fluctuated between about 40 and 80%. Surprisingly, the mass balance calculation found a considerable decrease of Se accumulated in the SBR when the aeration period was prolonged to 7 h, indicating very efficient Se biovolatilization. Furthermore, microbial community analysis suggested that various Se-reducing bacteria coordinately contributed to the removal of Se in the SBR and main contributors varied depending on the operational conditions. This study will offer implications for practical biological treatment of selenium in saline wastewater.

关键词： Activated sludge Selenate reduction Saline wastewater Sequencing batch reactor Alternating anoxic/oxic conditions Selenium biovolatilization

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HQ in inland saline-alkaline water under different light qualities

《环境科学与工程前沿（英文）》 2022年第16卷第4期 doi: 10.1007/s11783-021-1479-2

摘要：

• Optimal growth of Chlorella in inland saline-alkaline water was achieved by blue LED.

关键词： Light quality Chlorella Inland saline-alkaline water Fatty acid Biodiesel property

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Adhesion performance of alkali-activated material for 3-dimensional printing of tunnel linings at different

《结构与土木工程前沿（英文）》 2024年第18卷第1期页码 66-79 doi: 10.1007/s11709-024-1067-1

摘要： Robotic-based technologies such as automated spraying or extrusion-based 3-dimensional (3D) concrete printing can be used to build tunnel linings, aiming at reducing labor and mitigating the associated safety issues, especially in the high-geothermal environment. Extrusion-based 3D concrete printing (3DCP) has additional advantages over automated sprayings, such as improved surface quality and no rebound. However, the effect of different temperatures on the adhesion performance of 3D-printed materials for tunnel linings has not been investigated. This study developed several alkali-activated slag mixtures with different activator modulus ratios to avoid the excessive use of Portland cement and enhance sustainability of 3D printable materials. The thermal responses of the mixtures at different temperatures of 20 and 40 °C were studied. The adhesion strength of the alkali-activated material was evaluated for both early and later ages. Furthermore, the structural evolution of the material exposed to different temperatures was measured. This was followed by microstructure characterization. Results indicate that elevated temperatures accelerate material reactions, resulting in improved early-age adhesion performance. Moreover, higher temperatures contribute to the development of a denser microstructure and enhanced mechanical strength in the hardened stage, particularly in mixtures with higher silicate content.

关键词： alkali-activated material 3DCP tunnel lining high-geothermal environment adhesion

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Utilization of alkali-activated copper slag as binder in concrete

《结构与土木工程前沿（英文）》 2021年第15卷第3期页码 773-780 doi: 10.1007/s11709-021-0722-z

摘要： This study was focused on developing concrete using alkali-activated copper slag (AACS) as a binder. The properties of alkali-activated copper slag concrete (AACSC) were compared with portland cement concrete (PCC). Different AACSC mixes were prepared with varying Na₂O dosage (6% and 8% of the binder by weight) and curing methods. Hydration products in AACSC were retrieved using Fourier-transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD) techniques. The test results indicate that the workability of AACSC was lesser than that of PCC. The AACSC mix with 6% Na₂O dosage has exhibited similar mechanical properties as that of PCC. The mechanical properties of AACSC were higher than PCC when 8% of Na₂O dosage was used. Heat curing was effective to upgrade the strength properties of AACSC at an early age of curing, but at a later age mechanical properties of ambient cured and heat-cured AACSC were comparable. The hydration products of AACSC were not identified in XRD patterns, whereas, in FTIR spectra of AACSC some alkali-activated reaction products were reflected. The AACSC mixes were found to be more sustainable than PCC. It has been concluded that AACSC can be produced similarly to that of PCC and ambient curing is sufficient.

关键词： binder concrete mechanical properties mineralogy workability

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柴达木盐湖产业生态文明建设战略研究

杨荣金,舒俭民,李秀红,孙美莹,张一

《中国工程科学》 2017年第19卷第4期页码 48-53 doi: 10.15302/J-SSCAE-2017.04.008

摘要：

盐湖产业事关我国粮食安全，也是新能源和新材料产业的重要支撑。柴达木盆地是中国盐湖产业的核心，建设其产业生态文明重要而迫切。为推进柴达木盐湖产业生态文明建设，做强中国盐湖产业，本文从柴达木盐湖产业生态文明建设的现状出发，辨识产业生态文明建设面临的严峻挑战，提出了盐湖产业生态文明建设的四大战略。

关键词：柴达木盆地盐湖产业生态文明综合开发利用可持续发展

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Seasonal microbial community shift in a saline sewage treatment plant

Qingmei YAN, Xuxiang ZHANG, Tong ZHANG, Herbert H P FANG

《环境科学与工程前沿（英文）》 2011年第5卷第1期页码 40-47 doi: 10.1007/s11783-011-0304-8

摘要： Activated sludge was monthly sampled from a saline sewage treatment plant of Hong Kong (China) during June 2007 to May 2008 to analyze the microbial community shift along with environmental variations using denaturing gradient gel electrophoresis of polymerase chain reaction amplified 16S rDNA fragments. Environmental changes resulted into a seasonal microbial community shift characterized by alterations in species number and abundance in the sewage treatment plant. Correspondence analysis and cluster analysis on community structure profile showed that the 12 monthly samples fell into four groups, which is in accordance with season changing in Hong Kong. Canonical correspondence analysis revealed that and posed more significant effects on community structure than total phosphorus and total nitrogen, respectively. Compared with sludge retention time, influent total phosphorus had an inverse effect on the community structure shift, and chemical oxygen demand and showed a similar effects. Results of this study may contribute to the development of new knowledge involving the microbial community shift in sewage treatment plants.

关键词： sewage treatment plants polymerase chain reaction (PCR) denaturing gradient gel electrophoresis (DGGE) canonical correspondence analysis correspondence analysis