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δN-stable isotope analysis of NH: An overview on analytical measurements, source sampling and its source apportionment

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1414-6

摘要：

• Challenges in sampling of NH3 sources for d15N analysis are highlighted.

关键词： Aerosol ammonium     Atmospheric gaseous ammonia     Isotope fingerprinting     Isotope-based source apportionment     Ammonia gas-to-particle conversion    

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GREENHOUSE GAS AND AMMONIA EMISSION MITIGATION PRIORITIES FOR UK POLICY TARGETS

《农业科学与工程前沿（英文）》 2023年 第10卷 第2期   页码 268-280 doi: 10.15302/J-FASE-2023495

摘要：

● An expert survey highlighted the most effective strategies for GHG and ammonia mitigation.

关键词： agriculture     ammonia     greenhouse gas     mitigation     net zero    

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Experimental study on capturing CO 2 greenhouse gas by mixture of ammonia and soil

Ying WU, Yifei WANG, Qinghua ZENG, Xin GONG, Zunhong YU,

《化学科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 468-473 doi: 10.1007/s11705-009-0257-7

摘要： This paper presents our study on removal of carbon dioxide (CO) greenhouse gas emissions by using the mixture of ammonia and soil. CO capture capacity using this method is 15% higher than the sum of ammonia chemical absorption capacity and soil physical adsorption capacity. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) are utilized to study this synergism. The removal effect is not only reflected in ammonia chemical reaction with CO. CO can also be absorbed by ammonium bicarbonate (NHHCO) crystal, which is the main component of the product, or wrapped in the pore of the crystal or packed in the gap between the crystal and the soil. CO can be permanently deposited as carbonated minerals in the subsoil earth layers.

关键词： electron microscopy     product     physical adsorption     capacity     spectroscopy    

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Gold modified cobalt-based Fischer-Tropsch catalysts for conversion of synthesis gas to liquid fuels

Alan J. McCue, Jura Aponaviciute, Richard P.K. Wells, James A. Anderson

《化学科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 262-269 doi: 10.1007/s11705-013-1334-5

摘要： The addition of Au as a promoter/modifier for alumina supported Co catalyst has been studied by combined high temperature, high pressure Fourier transform infrared (FTIR) and on-line gas chromatography. The combination of these tools permitted the state of the active catalyst surface to be monitored while following the elution of reaction products during the first 5–7 h on stream of the catalyst. The catalysts under study were a 10%Co/Al O and a 2.5%Au/10%Co/Al O Samples were characterised before use using Raman and temperature programmed reduction (TPR). During the initial stages of reaction, hydrocarbons were built up on the surface of the catalyst as monitored by FTIR and the nature and amount of these species were assessed in terms of CH /CH ratio and the density of these alkyl fragments by employing absorption coefficients for the individual components. The nature and reducibility of the Co particles were modified by the presence of Au while the later also shifted the CO/H balance by acting as an effective water-gas shift catalyst during the early stages of reaction. This characteristic was lost during reaction as a consequence of redistribution of the two metallic phases.

关键词： gold modified catalyst     conversion of synthesis gas    

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NO conversion by positive streamer discharge—effects of gas compositions and reaction conditions

HE Wei, ZHU Tianle, LI Jing

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 153-158 doi: 10.1007/s11783-007-0027-z

摘要： The effects of gas compositions and reaction conditions on NO conversion by positive streamer discharge were experimentally investigated by using a link tooth wheel-cylinder reactor. The results showed that NO conversion increased w

关键词： conversion     streamer discharge     wheel-cylinder     positive streamer    

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Effect of adjusted mesoscale drag model on flue gas desulfurization in powder-particle spouted beds

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 909-920 doi: 10.1007/s11705-021-2100-8

摘要： An energy minimum multiscale model was adjusted to simulate the mesoscale structure of the flue gas desulfurization process in a powder-particle spouted bed and verified experimentally. The obtained results revealed that the spout morphology simulated by the adjusted mesoscale drag model was unstable and discontinuous bubbling spout unlike the stable continuous spout obtained using the Gidaspow model. In addition, more thorough gas radial mixing was achieved using the adjusted mesoscale drag model. The mass fraction of water in the gas mixture at the outlet determined by the heterogeneous drag model was 1.5 times higher than that obtained by the homogeneous drag model during the simulation of water vaporization. For the desulfurization reaction, the experimental desulfurization efficiency was 75.03%, while the desulfurization efficiencies obtained by the Gidaspow and adjusted mesoscale drag models were 47.63% and 75.08%, respectively, indicating much higher accuracy of the latter technique.

关键词： adjusted mesoscale drag model     particle image velocimetry     water vaporization     desulfurization reaction     numerical simulation    

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hydrogels with uniform and gradient chemical structures using dialdehyde cellulose and diamine by aerating ammoniagas

Peiwen Liu, Carsten Mai, Kai Zhang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 383-389 doi: 10.1007/s11705-018-1718-7

摘要：

Hydrogels with precisely designed structures represent promising materials with a broad application spectrum, such as for sensor, tissue engineering and biomimetic technology. However, with highly reactive compounds, the preparation of hydrogels still needs an efficient approach for desired distribution of each component within hydrogels. In addition, a method for in situ preparation of gradient hydrogels is still lacking. Herein, we report the formation of hydrogels with either uniform or gradient internal structures via a novel, simple but very efficient method by aerating ammonia gas (NH3 gas) into the solution of dialdehyde cellulose (DAC) and a diamine. As-prepared hydrogels exhibited uniform microscopic and chemical structure or gradient distribution of functional groups. Due to lots of aldehyde groups on DAC chains, functional hydrogels can be prepared by using diverse diamines. For instance, hydrogels prepared by using 1,6-hexanediamine as a cross-linker were responsive to pH values. Moreover, this controllable process of aerating NH3 gas allows the in situ formation of gradient hydrogels; for instance, by using cyanamide as a reaction counterpart, gradient hydrogels with gradient distributions of cyanide groups were prepared.

关键词： hydrogel     uniform     gradient     dialdehyde cellulose     ammonia gas     diamine    

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Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

《化学科学与工程前沿（英文）》   页码 1681-1687 doi: 10.1007/s11705-022-2180-0

摘要： Bubbles and foams are ubiquitous in daily life and industrial processes. Studying their dynamic behaviors is of key importance for foam manufacturing processes in food packaging, cosmetics and pharmaceuticals. Bare bubbles are inherently fragile and transient; enhancing their robustness and shelf lives is an ongoing challenge. Their rupture can be attributed to liquid evaporation, thin film drainage and the nuclei of environmental dust. Inspired by particle-stabilized interfaces in Pickering emulsions, armored bubbles and liquid marble, bubbles are protected by an enclosed particle-entrapping liquid thin film, and the resultant soft object is termed gas marble. The gas marble exhibits mechanical strength orders of magnitude higher than that of soap bubbles when subjected to overpressure and underpressure, owing to the compact particle monolayer straddling the surface liquid film. By using a water-absorbent glycerol solution, the resulting gas marble can persist for 465 d in normal atmospheric settings. This particle-stabilizing approach not only has practical implications for foam manufacturing processes but also can inspire the new design and fabrication of functional biomaterials and biomedicines.

关键词： bubble     particles     interfaces     armored bubble     liquid marble     gas marble     Pickering emulsion    

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Influence of mass air flow ratio on gas-particle flow characteristics of a swirl burner in a 29 MW pulverized

Rong YAN, Zhichao CHEN, Shuo GUAN, Zhengqi LI

《能源前沿（英文）》 2021年 第15卷 第1期   页码 68-77 doi: 10.1007/s11708-020-0697-9

摘要： In a gas/particle two-phase test facility, a three-component particle-dynamics anemometer was used to measure the characteristics of gas/particle two-phase flows in a 29 megawatt (MW) pulverized coal industrial boiler equipped with a new type of swirling pulverized coal burner. The distributions of three-dimensional gas/particle velocity, particle volume flux, and particle size distribution were measured under different working conditions. The mean axial velocity and the particle volume flux in the central region of the burner outlet were found to be negative. This indicated that a central recirculation zone was formed in the center of the burner. In the central recirculation zone, the absolute value of the mean axial velocity and the particle volume flux increased when the external secondary air volume increased. The size of the central reflux zone remained stable when the air volume ratio changed. Along the direction of the jet, the peak value formed by the tertiary air gradually moved toward the center of the burner. This tertiary air was mixed with the peak value formed by the air in the adiabatic combustion chamber after the cross-section of / = 0.7. Large particles were concentrated near the wall area, and the particle size in the recirculation zone was small.

关键词： industrial pulverized coal boiler     swirl burner     air/particle flow     particle dynamic analyzer (PDA)    

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Mesoporous zeolites as efficient catalysts for oil refining and natural gas conversion

Jie ZHU, Xiangju MENG, Fengshou XIAO

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 233-248 doi: 10.1007/s11705-013-1329-2

摘要： Zeolites have been regarded as one of the most important catalysts in petrochemical industry due to their excellent catalytic performance. However, the sole micropores in zeolites severely limit their applications in oil refining and natural gas conversion. To solve the problem, mesoporous zeolites have been prepared by introducing mesopores into the zeolite crystals in recent years, and thus have the advantages of both mesostructured materials (fast diffusion and accessible for bulky molecules) and microporous zeolite crystals (strong acidity and high hydrothermal stability). In this review, after giving a brief introduction to preparation, structure, and characterization of mesoporous zeolites, we systematically summarize catalytic applications of these mesoporous zeolites as efficient catalysts in oil refining and natural gas conversion including catalytic cracking of heavy oil, alkylation, isomerization, hydrogenation, hydrodesulfurization, methane dehydroaromatization, methanol dehydration to dimethyl ether, methanol to olefins, and methanol to hydrocarbons.

关键词： mesoporous zeolite     catalysis     oil refining     natural gas conversion    

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洁净煤技术的新发展——一种火电厂SO2的资源化技术

肖文德,袁渭康

《中国工程科学》 2000年 第2卷 第5期   页码 77-83

摘要：

火电厂烟气脱硫（FGD）是重要的洁净煤技术之一。发达国家主要采用以石灰石为脱硫剂的钙法，投资大，成本高，石膏无利用价值，不适合我国的国情。作者提出了一种以合成氨为基础的新氨法（NADS），回收烟气中的SO2，生产硫酸铵、磷酸铵或硝酸铵化肥，并联产工业浓硫酸，已在2.5万kW机组试验成功，建立了计算机模拟软件。与现有同类技术相比，NADS可节省投资70%以上，减少运行成本70%以上。文中给出了一个20万kW机组和一个30万kW机组的经济分析，NADS的投资分别为6000万元和8000万元，投资回收期分别为8年和5年。该技术在我国具有十分巨大的应用。

关键词： 烟气脱硫     洁净煤技术     二氧化硫     电厂     氨     化肥    

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Effects of seed particles Al

Xiao Zhang, Biwu Chu, Junhua Li, Chaozhi Zhang

《环境科学与工程前沿（英文）》 2017年 第11卷 第4期 doi: 10.1007/s11783-017-0936-4

摘要： Seed particles Al O , Al (SO ) and H SO were selected to investigate their effects on secondary aerosol (SA) formation in toluene/NO photooxidation under sulfur dioxide (SO ) and ammonia (NH ). Effect of seed particles on SA formation was related to their acid-base properties and the presence of acid or alkaline gases. Under NH -poor condition, SA formation increased with increasing SO concentration due to the acid-catalyzing effect of the oxidation products of SO (i.e. H SO ). The enhancing effect of SO became unobvious under NH -rich condition, because NH would eliminate the acid-catalyzing effect by neutralizing the acid products. Acidic seeds H SO accelerated SA formation under either SO or NH condition. Weak acidic Al (SO ) seeds didn’t affect obviously on SA formation. The inhibiting effect of amphoteric seeds Al O on SA formation was related to the presence of SO / NH due to their acid-base property. Under NH -poor condition, the inhibiting effect of Al O on SA formation decreased with increasing concentration of SO , while under NH -rich condition, the inhibiting effect wasn’t remarkable.

关键词： Seed particle     Secondary aerosol     Sulfur dioxide     Ammonia     Acid-catalyzing effect    

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Particle-scale simulation of fluidized bed with immersed tubes

ZHAO Yongzhi, JIANG Maoqiang, CHENG Yi

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 341-345 doi: 10.1007/s11705-008-0046-8

摘要： In order to simulate gas-solids flows with complex geometry, the boundary element method was incorporated into the implementation of a combined model of computational fluid dynamics and discrete element method. The resulting method was employed to simulate hydrodynamics in a fluidized bed with immersed tubes. The transient simulation results showed particle and bubble dynamics. The bubble coalescence and break-up behavior when passing the immersed tubes was successfully predicted. The gas-solid flow pattern in the fluidized bed is changed greatly because of the immersed tubes. As particles and gas are come in contact with the immersed tubes, the gas bubbles will be deformed. The collisions between particles and tubes will make the tubes surrounded by air pockets most of the time and this is unfavorable for the heat transfer between particles and tubes.

关键词： unfavorable     computational     gas-solid     particle     discrete    

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Production of hydrogen from fossil fuel: A review

《能源前沿（英文）》 2023年 第17卷 第5期   页码 585-610 doi: 10.1007/s11708-023-0886-4

摘要： Production of hydrogen, one of the most promising alternative clean fuels, through catalytic conversion from fossil fuel is the most technically and economically feasible technology. Catalytic conversion of natural gas into hydrogen and carbon is thermodynamically favorable under atmospheric conditions. However, using noble metals as a catalyst is costly for hydrogen production, thus mandating non-noble metal-based catalysts such as Ni, Co, and Cu-based alloys. This paper reviews the various hydrogen production methods from fossil fuels through pyrolysis, partial oxidation, autothermal, and steam reforming, emphasizing the catalytic production of hydrogen via steam reforming of methane. The multicomponent catalysts composed of several non-noble materials have been summarized. Of the Ni, Co, and Cu-based catalysts investigated in the literature, Ni/Al2O3 catalyst is the most economical and performs best because it suppresses the coke formation on the catalyst. To avoid carbon emission, this method of hydrogen production from methane should be integrated with carbon capture, utilization, and storage (CCUS). Carbon capture can be accomplished by absorption, adsorption, and membrane separation processes. The remaining challenges, prospects, and future research and development directions are described.

关键词： methane     catalytic conversion     natural gas     hydrogen production     CCUS    

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Methane, Nitrous Oxide and Ammonia generation in full-scale swine wastewater purification facilities

Takashi Osada, Makoto Shiraishi, Teruaki Hasegawa, Hirofumi Kawahara

《环境科学与工程前沿（英文）》 2017年 第11卷 第3期 doi: 10.1007/s11783-017-0933-7

摘要： The activated sludge process to remove nitrogen and biochemical oxygen demand (BOD) is reportedly cost-effective for swine wastewater treatment, and it use has thus increased in pig farming. Nitrous oxide (N O) is generated on farms as an intermediate product in nitrification and denitrification, and methane (CH ) is also generated from organic degradation under anaerobic conditions by microorganisms in manure or wastewater. This study was carried out at five activated sludge treatment facilities across Japan between August 2014 and January 2015. Measurements were conducted over several weeks at wastewater purification facilities for swine farms: two in Chiba prefecture (East Japan), two in Okayama prefecture (West Japan), and one in Saga (Southern Japan). Taking several environmental fluctuations into account, we collected measurement data continuously day and night, during both high-temperature and low-temperature periods. The results indicated that CH and N O emission factors were 0.91% (kgCH · kg volatile solids ) and 2.87% (g N O-N· kg total N ), respectively. Ammonia emissions were negligible in all of the measurements from the wastewater facilities. The N O emission factor calculated under this experiment was low compared to our previous finding (5.0%; g N O-N· kg N ) in a laboratory experiment. In contrast, the CH emission factor calculated herein was rather high compared to the laboratory measurements. There was great variation in daily GHG emission factors measured in the actual wastewater treatment facilities. In particular, the N O emission rate was affected by several environmental conditions at each facility location, as well as by the management of the wastewater treatment.

关键词： Manure     Greenhouse gas     Denitrification     BOD/N     Nitrous oxide     Methane    

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标题 作者 时间 类型 操作

δN-stable isotope analysis of NH: An overview on analytical measurements, source sampling and its source apportionment

期刊论文

GREENHOUSE GAS AND AMMONIA EMISSION MITIGATION PRIORITIES FOR UK POLICY TARGETS

期刊论文

Experimental study on capturing CO 2 greenhouse gas by mixture of ammonia and soil

Ying WU, Yifei WANG, Qinghua ZENG, Xin GONG, Zunhong YU,

期刊论文

Gold modified cobalt-based Fischer-Tropsch catalysts for conversion of synthesis gas to liquid fuels

Alan J. McCue, Jura Aponaviciute, Richard P.K. Wells, James A. Anderson

期刊论文

NO conversion by positive streamer discharge—effects of gas compositions and reaction conditions

HE Wei, ZHU Tianle, LI Jing

期刊论文

Effect of adjusted mesoscale drag model on flue gas desulfurization in powder-particle spouted beds

期刊论文

hydrogels with uniform and gradient chemical structures using dialdehyde cellulose and diamine by aerating ammoniagas

Peiwen Liu, Carsten Mai, Kai Zhang

期刊论文

Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

期刊论文

Influence of mass air flow ratio on gas-particle flow characteristics of a swirl burner in a 29 MW pulverized

Rong YAN, Zhichao CHEN, Shuo GUAN, Zhengqi LI

期刊论文

Mesoporous zeolites as efficient catalysts for oil refining and natural gas conversion

Jie ZHU, Xiangju MENG, Fengshou XIAO

期刊论文

洁净煤技术的新发展——一种火电厂SO2的资源化技术

肖文德,袁渭康

期刊论文

Effects of seed particles Al

Xiao Zhang, Biwu Chu, Junhua Li, Chaozhi Zhang

期刊论文

Particle-scale simulation of fluidized bed with immersed tubes

ZHAO Yongzhi, JIANG Maoqiang, CHENG Yi

期刊论文

Production of hydrogen from fossil fuel: A review

期刊论文

Methane, Nitrous Oxide and Ammonia generation in full-scale swine wastewater purification facilities

Takashi Osada, Makoto Shiraishi, Teruaki Hasegawa, Hirofumi Kawahara

期刊论文