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期刊论文 6

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2023 1

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催化磷化 1

异质纳米晶 1

快速充电 1

磷化锡 1

锂离子电池 1

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How diplomacy saved the COP21 Paris Climate Conference, but now, can we save ourselves?

D. Nathaniel MULCAHY, David L. MULCAHY

《能源前沿(英文)》 2018年 第12卷 第3期   页码 344-352 doi: 10.1007/s11708-017-0498-y

摘要:

To solve a problem, three things are necessary: awareness, means, and will. The 2015 COP21 Paris accord was a masterful, perhaps even world-saving, diplomatic advance toward making the world aware of climate change. Some of that success may have been because publications from the IPCC and the National Academy of Science were made available, on line, as prepublication offerings, in order to be widely viewed before the Paris Climate Conference. This provided diplomats and negotiators with the latest information about climate change, its nearness in time, its consequences, and how well current mitigation technologies can succeed. Whatever the reasons, the Paris Climate Conference, was a success. Leaders of 195 nations agreed that climate change is a real and present danger to life as is known to all. This important understanding was accomplished despite the presentation of well established scientific facts which, without very diplomatic handling, could easily have evoked overwhelming political opposition to an agreement and thus another COP failure. In this paper, the fact that how some scientific truths, written specifically to be overlooked, were presented in order to prepare COP21 participants for the conference is explained. Besides, the effectiveness and efficiency of currently favored mitigation policies, the extent of ongoing progress to better ones, and finally, how a new appreciation of climate change consequences can strengthen the will of nation states and industries to work toward solutions are evaluated.

关键词: COP21     Paris     climate     agreement     offsets     mitigation     IPCC    

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu2O@CF electrocatalyst

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1430-1439 doi: 10.1007/s11705-023-2320-1

摘要: Transition metal phosphides have been extensively studied for catalytic applications in water splitting. Herein, we report an in situ phosphorization of zeolitic imidazole frameworks (ZIF-67) to generate amorphous cobalt phosphide/ZIF-67 heterojunction on a self-supporting copper foam (CF) substrate with excellent performance for hydrogen evolution reaction (HER). The needle-leaf like copper hydroxide was anchored on CF surface, which acted as implantation to grow ZIF-67. The intermediate product was phosphorized to obtain final electrocatalyst (CoP/Cu2O@CF) with uniform particle size, exhibiting a rhombic dodecahedron structure with wrinkles on the surface. The electrochemical measurement proved that CoP/Cu2O@CF catalyst exhibited excellent HER activity and long-term stability in 1.0 mol·L–1 KOH solution. The overpotential was only 62 mV with the Tafel slope of 83 mV·dec–1 at a current density of 10 mA·cm–2, with a large electrochemical active surface area. It also showed competitive performance at large current which indicated the potential application to industrial water electrolysis to produce hydrogen. First-principle calculations illustrated that benefit from the construction of CoP/ZIF-67 heterojunction, the d-band center of CoP downshifted after bonding with ZIF-67 and the Gibbs free energy (ΔGH*) changed from –0.18 to –0.11 eV, confirming both decrease in overpotential and excellent HER activity. This work illustrates the efficient HER activity of CoP/Cu2O@CF catalyst, which will act as a potential candidate for precious metal electrocatalysts.

关键词: CoP/Cu2O@CF     electrocatalyst     phosphorization     HER     DFT    

原子界面催化合成SnP/CoP异质纳米晶嵌入碳杂化物用于高功率型锂离子电池 Article

胡晨, 胡彦杰, 陈爱平, 段学志, 江浩, 李春忠

《工程(英文)》 2022年 第18卷 第11期   页码 154-160 doi: 10.1016/j.eng.2021.11.026

摘要: 因此,在还原氧化石墨烯(rGO)包裹的碳骨架内合成了SnP/CoP异质纳米晶。充放电机理分析表明尺寸为4.0 nm的SnP/CoP纳米晶具有高反应可逆性,且CoP在较高电位生成的金属Co加速了低电位SnP反应的动力学,从而赋予材料超快充放电能力。

关键词: 催化磷化     磷化锡     异质纳米晶     快速充电     锂离子电池    

《联合国气候变化框架公约》第26次缔约方大会召开

Sean O'Neill

《工程(英文)》 2022年 第11卷 第4期   页码 6-8 doi: 10.1016/j.eng.2022.02.004

ZnO nanorefrigerant in R152a refrigeration system for energy conservation and green environment

D. SENDIL KUMAR,R. ELANSEZHIAN

《机械工程前沿(英文)》 2014年 第9卷 第1期   页码 75-80 doi: 10.1007/s11465-014-0285-y

摘要:

In this paper the reliability and performance of a vapour compression refrigeration system with ZnO nanoparticles in the working fluid was investigated experimentally. Nanorefrigerant was synthesized on the basis of the concept of the nanofluids, which was prepared by mixing ZnO nanoparticles with R152a refrigerant. The conventional refrigerant R134a has a global warming potential (GWP) of 1300 whereas R152a has a significant reduced value of GWP of 140 only. An experimental test rig is designed and fabricated indigenously in the laboratory to carry out the investigations. ZnO nanoparticles with refrigerant mixture were used in HFC R152a refrigeration system. The system performance with nanoparticles was then investigated. The concentration of nano ZnO ranges in the order of 0.1% v, 0.3% v and 0.5%v with particle size of 50 nm and 150 g of R152a was charged and tests were conducted. The compressor suction pressure, discharge pressure and evaporator temperature were measured. The results indicated that ZnO nanorefrigerant works normally and safely in the system. The ZnO nanoparticle concentration is an important factor considered for heat transfer enhancement in the refrigeration system. The performance of the system was significantly improved with 21% less energy consumption when 0.5%v ZnO-R152a refrigerant. Both the suction pressure and discharge pressure were lowered by 10.5% when nanorefrigerant was used. The evaporator temperature was reduced by 6% with the use of nanorefrigerant. Hence ZnO nanoparticles could be used in refrigeration system to considerably reduce energy consumption. The usage of R152a with zero ozone depleting potential (ODP) and very less GWP and thus provides a green and clean environment. The complete experimental results and their analysis are reported in the main paper.

关键词: ZnO nanorefrigerant     reduced GWP     COP     pressure ratio green energy    

Comprehensive performance analysis and optimization of 1,3-dimethylimidazolylium dimethylphosphate-water binary mixture for a single effect absorption refrigeration system

Gorakshnath TAKALKAR, Ahmad K. SLEITI

《能源前沿(英文)》 2022年 第16卷 第3期   页码 521-535 doi: 10.1007/s11708-021-0720-9

摘要: The energy and exergy analyses of the absorption refrigeration system (ARS) using H O-[mmim][DMP] mixture were investigated for a wide range of temperature. The equilibrium Dühring ( - - ) and enthalpy ( - - ) of mixture were assessed using the excess Gibbs free non-random two liquid (NRTL) model for a temperature range of 20°C to 140°C and from 0.1 to 0.9. The performance validation of the ARS cycle showed a better coefficient of performance (COP) of 0.834 for H O-[mmim][DMP] in comparison to NH -H O, H O-LiBr, H O-[emim][DMP], and H O-[emim][BF4]. Further, ARS performances with various operating temperatures of the absorber ( ), condenser ( ), generator ( ), and evaporator ( ) were simulated and optimized for a maximum COP and exergetic COP (ECOP). The effects of from 50°C to 150°C and and from 30°C to 50°C on COP and ECOP, the , , and circulation ratio (CR) of the ARS were evaluated and optimized for from 5°C to 15°C. The optimization revealed that needed to achieve a maximum COP which was more than that for a maximum ECOP. Therefore, this investigation provides criteria to select low grade heat source temperature. Most of the series flow of the cases of cooling water from the condenser to the absorber was found to be better than the absorber to the condenser.

关键词: ionic liquid driven absorption cycle     H2O-[mmim][DMP]     coefficient of performance (COP)     exergy analysis     thermodynamics mixture property    

标题 作者 时间 类型 操作

How diplomacy saved the COP21 Paris Climate Conference, but now, can we save ourselves?

D. Nathaniel MULCAHY, David L. MULCAHY

期刊论文

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu2O@CF electrocatalyst

期刊论文

原子界面催化合成SnP/CoP异质纳米晶嵌入碳杂化物用于高功率型锂离子电池

胡晨, 胡彦杰, 陈爱平, 段学志, 江浩, 李春忠

期刊论文

《联合国气候变化框架公约》第26次缔约方大会召开

Sean O'Neill

期刊论文

ZnO nanorefrigerant in R152a refrigeration system for energy conservation and green environment

D. SENDIL KUMAR,R. ELANSEZHIAN

期刊论文

Comprehensive performance analysis and optimization of 1,3-dimethylimidazolylium dimethylphosphate-water binary mixture for a single effect absorption refrigeration system

Gorakshnath TAKALKAR, Ahmad K. SLEITI

期刊论文