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绿色化工 4

碳中和 3

催化剂 2

催化裂化 2

催化裂解 2

蒸汽裂解 2

裂纹扩展 2

过程强化 2

CO 1

H₂S 1

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PH₃ 1

pH值 1

三台阶七步开挖法 1

丙烯 1

两个反应区 1

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催化裂解架起了炼油与化工之间的桥梁

李再婷

《中国工程科学》 1999年第1卷第2期页码 67-71

摘要：

催化裂解是以石油中的重油为原料，用催化方法生产丙烯等基本有机化工原料的技术。在世界上我国首先研究开发了此新工艺及催化剂，并于1990年成功进行了工业示范。迄今，国内外已有七套应用该技术的工业装置建成并投产。生产的丙烯等化工原料已分别用来合成了高质量的聚丙烯、聚乙烯及丙烯腈等化学品。目前催化裂解已可应用更重质的原料，如常压渣油，并开发出能适合不同原料的多种催化剂。文中重点介绍了应用该技术在泰国建成的一套催化裂解装置的生产情况。

关键词：催化裂解石油化学工业丙烯异丁烯

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A novel fluid catalytic cracking process for maximizing

Youhao Xu, Shouye Cui

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 9-23 doi: 10.1007/s11705-017-1696-1

摘要： The maximizing iso-paraffins (MIP) developed by RIPP has improved gasoline quality to meet the demand of motor gasoline specification. A concept that two different reaction zones include cracking zone and conversion zone is proposed as the fundamental of MIP by research on fluid catalytic cracking (FCC) reaction chemistry. Based on the concept, the MIP process is featured by applying a novel sequential two-zone riser in conjunction with proprietary catalyst and engineering technique. The developed MIP process can not only improve gasoline yield or gasoline plus propylene yields but also produce gasoline with a higher content of -paraffins and a lower content of sulfur. A minimum octane number loss is achieved when MIP gasoline is treated by downstream desulfurization technology (RSDS/S Zorb). The combination of MIP and RSDS/S Zorb processes creates a very competitive route, which is different from the technical route used by other developed countries, to upgrade the quality of motor gasoline with the lowest economic costs in China. In just one decade, the processing capacity of MIP units has accounted for about 60% of the domestic total processing capacity of FCC units. The MIP process is gradually becoming a new generation of FCC technology.

关键词： gasoline iso-paraffins FCC desulfurization octane number

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Study on reformulation of fluid catalytic cracking gasoline and increasing production of light olefins

YAN Pingxiang, MENG Xianghai, GAO Jinsen, XU Chunming, SUI Zhiyu

《化学科学与工程前沿（英文）》 2008年第2卷第1期页码 74-79 doi: 10.1007/s11705-008-0016-1

摘要： The effects of reaction temperature, mass ratio of catalyst to oil, space velocity, and mass ratio of water to oil on the product distribution, the yields of light olefins (light olefins including ethylene, propylene and butylene) and the composition of the fluid catalytic cracking (FCC) gasoline upgraded over the self-made catalyst GL in a confined fluidized bed reactor were investigated. The experimental results showed that FCC gasoline was obviously reformulated under appropriate reaction conditions. The olefins (olefins with C atom number above 4) content of FCC gasoline was markedly reduced, and the aromatics content and octane number were increased. The upgraded gasoline met the new standard of gasoline, and meanwhile, higher yields of light olefins were obtained. Furthermore, higher reaction temperature, higher mass ratio of catalyst to oil, higher mass ratio of water to oil, and lower space velocity were found to be beneficial to FCC gasoline reformulation and light olefins production.

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Investigation of phosphate adsorption from an aqueous solution using spent fluid catalytic cracking catalyst

Zhen Li, Zhaofu Qiu, Ji Yang, Benteng Ma, Shuguang Lu, Chuanhui Qin

《环境科学与工程前沿（英文）》 2018年第12卷第6期 doi: 10.1007/s11783-018-1082-3

摘要：

Spent FCC catalyst with lanthanum is proposed as a novel P-removal adsorbent.

The spent FCC catalyst exhibits 99% adsorption efficiency for low P-concentration wastewater (C₀<5.0 mg/L).

High affinity, endothermic reaction and fast sorption kinetics are achieved.

The phosphate is adsorbed in the form of LaPO₄ and KH₂PO₄.

关键词： Spent FCC catalyst Phosphate removal Adsorption Lanthanum

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Effect of hierarchical ZSM-5 zeolite crystal size on diffusion and catalytic performance of n-heptanecracking

Shuman Xu, Xiaoxiao Zhang, Dangguo Cheng, Fengqiu Chen, Xiaohong Ren

《化学科学与工程前沿（英文）》 2018年第12卷第4期页码 780-789 doi: 10.1007/s11705-018-1733-8

摘要： Hierarchical ZSM-5 zeolite aggregates with different sizes of nanocrystals were synthesized using different amounts of the mesoporogen 3-aminopropyltriethoxysilane. The effect of the crystal size on the catalytic cracking of -heptane was investigated and the Thiele modulus and effectiveness factor were used to determine the reaction rate-limiting step. The crystal size affected the textual properties of the catalysts but not the acidic properties of the catalysts. The reaction rate was first order with respect to the -heptane concentration. Cracking over hierarchical zeolites with nanocrystal sizes larger than about 50 nm took place under transition-limiting conditions, whereas the reaction over hierarchical zeolites with nanocrystal sizes of 15 or 30 nm proceeded under reaction control conditions. Hierarchical ZSM-5 zeolite aggregates with smaller nanocrystals had better selectivity for light olefins which can be ascribed to the shorter diffusion path lengths and lower diffusion resistance in these catalysts. Furthermore, these catalysts had lower coking levels which can be attributed to the substantial number of mesopores which prevent the formation of coke precursors.

关键词： hierarchical ZSM-5 crystal size catalytic cracking Thiele modulus effectiveness factor

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Catalytic cracking of endothermic fuels in coated tube reactor

LI Jia, ZOU Jijun, ZHANG Xiangwen, GUO Wei, MI Zhentao

《化学科学与工程前沿（英文）》 2008年第2卷第2期页码 181-185 doi: 10.1007/s11705-008-0032-1

摘要： Suspensoid of HZSM-5 or HY zeolites mixed with a self-made ceramic-like binder was coated on the inner wall of a tubular reactor by gas-aided fluid displacement technology. The coated zeolites were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The coating thickness is 10–20 ?m and the particle size of the zeolites is in the range of 1–5 ?m. In the coated reactor, cracking of endothermic fuels including -dodecane and aviation fuel RP-3 was carried out separately under supercritical conditions at 600°C and 625°C to investigate their heat sinks and conversion of catalytic reactions. For the reaction catalyzed by HY(25% mass fraction) coating, the heat sink capacity of -dodecane are 815.7 and 901.9 kJ/kg higher than that of the bare tube at 600°C and at 625°C, respectively. Conversion of -dodecane also increases from 42% to 60% at 600°C and from 66% to 80% at 625°C. The coated zeolite can significantly inhibit the carbon deposition during supercritical cracking reactions.

关键词： HZSM-5 self-made ceramic-like gas-aided Conversion Suspensoid

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Desulfurization mechanism of FCC gasoline: A review

Liang ZHAO, Yan CHEN, Jinsen GAO, Yu CHEN,

《化学科学与工程前沿（英文）》 2010年第4卷第3期页码 314-321 doi: 10.1007/s11705-009-0271-9

摘要： This paper reviews the most important developments on the desulfurization mechanism of Fluid Catalytic Cracking (FCC) gasoline. First, the origin of sulfur compounds in FCC gasoline and the current developed desulfurization approaches and technologies are briefly introduced, and then the researches on desulfurization mechanism are summarized from experimental and theoretical perspectives. Further researches on the desulfurization mechanism will lay a foundation for optimizing desulfurization sorbents and technologies.

关键词： Catalytic Cracking foundation developed desulfurization desulfurization mechanism important

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催化裂化过程反应化学的进展

许友好,汪燮卿

《中国工程科学》 2007年第9卷第8期页码 6-14

摘要：

面对催化裂化工艺所遇到的挑战，提出了催化裂化过程反应化学的多维反应结构模式。多维反应结构模式的建立是基于对烃类在酸性催化剂上反应化学认识而进行的知识创新，但多维反应结构不同于烃类在酸性催化剂上反应化学。具有多维反应结构的催化裂化工艺更具有多样性和灵活性，基于此已成功地开发了多产异构烷烃的催化裂化工艺和生产清洁汽油和多产丙烯的催化裂化工艺。

关键词：催化裂化反应化学催化剂多维反应结构两个反应区

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Gas-solids separation model of a novel FCC riser terminator device: super short quick separator (SSQS)

LU Chunxi, LI Ruxin, SHI Mingxian, LIU Xiancheng

《化学科学与工程前沿（英文）》 2008年第2卷第4期页码 462-467 doi: 10.1007/s11705-008-0068-2

摘要： The gas flow field and the separation efficiency of a novel fluid catalytic cracking (FCC) riser terminal device, named as Super Short Quick Separator (SSQS), were studied. On the basis of above investigations, a section-lateral-mixing separation model was proposed, which included both the effect of inertia and structure of gas outlet on particles capture. After final modification, the results predicted with this model could be in good agreement with the cold experimental data. According to this model, the separation efficiency of SSQS is mainly influenced by the difference between the arc radius and the center pipe radius as well as the magnitude of particle tangential velocity.

关键词： catalytic cracking separation efficiency tangential velocity agreement magnitude

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Effects of microfine aggregate in manufactured sand on bleeding and plastic shrinkage cracking of concrete

Branavan ARULMOLY; Chaminda KONTHESINGHA; Anura NANAYAKKARA

《结构与土木工程前沿（英文）》 2022年第16卷第11期页码 1453-1473 doi: 10.1007/s11709-022-0877-2

摘要： Construction industries have started to utilize manufactured sand (MS) as an effective alternative for river sand in concrete. High-grade parent rocks are crushed to obtain MS, which also produces a considerable amount of microfine aggregate (MFA). The higher percentage of MFA could lead to both positive and negative effects on the performance of cement-based mixes. This research was done to examine the influence of varying MFA levels, specifically 0%, 3%, 6%, 9%, and 12% (by weight) as the partial replacements of MS on bleeding and plastic shrinkage cracking of concrete. In addition to the varying MFA levels, some concrete mixes also included fly ash (FA) and superplasticizer to investigate the effect of free-water content in the mixes. The bleeding test data were taken as on-site measurements, while the cracks from the plastic shrinkage cracking test were evaluated using an image processing technique. The results concluded that the MFA replacements and the effective water-to-cement ratio have a significant effect on the selected concrete properties. With the increasing replacement levels, cumulative bleeding and crack initiation life gradually decreased, while a progressive increase was observed for crack width, crack length, and crack area.

关键词： manufactured sand fresh concrete microfines admixtures shrinkage cracking

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Theoretical study on the confine-stiffening effect and fractal cracking of square concrete filled steel

《结构与土木工程前沿（英文）》 2021年第15卷第6期页码 1317-1336 doi: 10.1007/s11709-021-0763-3

摘要： Tension stress in steel-concrete composite is widely observed in engineering design. Based on an experimental program on tension performance of three square concrete-filled tubes (SCFT), the tension theory of SCFT is proposed using a mechanics-based approach. The tension stiffening effect, the confining strengthening effect and the confining stiffening effect, observed in tests of SCFTs are included in the developed tension theory model. Subsequently, simplified constitutive models of steel and concrete are proposed for the axial tension performance of SCFT. Based on the MSC.MARC software, a special fiber beam-column element is proposed to include the confining effect of SCFTs under tension and verified. The proposed analytical theory, effective formulas, and equivalent constitutive laws are extensively verified against three available tests reported in the literature on both global level (e.g., load-displacement curves) and strain level. The experimental verification proves the accuracy of the proposed theory and formulations in simulating the performance of SCFT members under tension with the capability to accurately predict the tensile strength and stiffness enhancements and realistically simulate the fractal cracking phenomenon.

关键词： square concrete filled tubes confine-stiffening confine-strengthening fractal cracking fracture

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FUNCTIONAL GAIN OF FRUIT NETTED-CRACKING IN AN INTROGRESSION LINE OF TOMATO WITH HIGHER EXPRESSION OF

《农业科学与工程前沿（英文）》 2021年第8卷第2期

摘要：

Fruit cracking is a major disorder that affects the integrity of fruit and reduces the commercial value of tomato and other fleshy fruit. Here, we have found a novel fruit ‘netted-cracking’ (FNC) phenotype in tomato introgression line IL4-4 which is present in neither the donor parent (LA0716) nor the receptor parent (M82). An F₂ population was generated by crossing IL4-4 with M82 to genetically characterize the FNC gene and this showed that a single dominant gene determined fruit netted-cracking. Further map-based cloning narrowed down the FNC locus to a 230 kb region on chromosome 4. Sequencing and annotation analysis show that FNC(Solyc04 g082540) was the most likely candidate gene. Functional characterization of FNC by overexpressing FNC^AC and FNC^IL4-4resulted in the fruit netted-cracking phenotype, suggesting that the FNC transcript level results in the functional gain of fruit netted-cracking. These findings were further confirmed by FNC ortholog in netted-cracking pepper and melon, indicating a common regulatory mechanism in different plant species. Furthermore, cytoplasm and nucleus-localized FNC indicates increased expression of genes involved in suberin, lignin, lipid transport and cell wall metabolism. These findings provide novel genetic insights into fruit netted-cracking and offer a way to promote molecular improvement toward cracking resistant cultivars.

关键词： fine mapping / fruit netted-cracking / introgression line / transcript level

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Hierarchical approach for fatigue cracking performance evaluation in asphalt pavements

Ibrahim ONIFADE, Yared DINEGDAE, Björn BIRGISSON

《结构与土木工程前沿（英文）》 2017年第11卷第3期页码 257-269 doi: 10.1007/s11709-017-0410-1

摘要： In this paper, a hierarchical approach is proposed for the evaluation of fatigue cracking in asphalt concrete pavements considering three different levels of complexities in the representation of the material behaviour, design parameters characterization and the determination of the pavement response as well as damage computation. Based on the developed hierarchical approach, three damage computation levels are identified and proposed. The levels of fatigue damage analysis provides pavement engineers a variety of tools that can be used for pavement analysis depending on the availability of data, required level of prediction accuracy and computational power at their disposal. The hierarchical approach also provides a systematic approach for the understanding of the fundamental mechanisms of pavement deterioration, the elimination of the empiricism associated with pavement design today and the transition towards the use of sound principles of mechanics in pavement analysis and design.

关键词： fatigue cracking energy based crack initiation mechanistic approach pavement analysis

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Tuning of the active phase structure and hydrofining performance of alumina-supported tri-metallic WMoNi catalysts via phosphorus incorporation

Shufeng Shan, Haiyan Liu, Gang Shi, Xiaojun Bao

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 59-69 doi: 10.1007/s11705-017-1686-3

摘要： The effects of phosphorus on the structure and hydrofining performance of tri-metallic WMoNi/Al O catalysts prepared with W/Mo-based hybrid precursor nanocrystals were investigated. The incorporation of phosphorus weakened the metal-support interactions (MSIs) and facilitated the formation of more synergetic NiWMoS phases with higher stacks. Catalytic tests using a fluid catalytic cracking diesel fuel showed that the changes in the MSIs and the morphology of the active phases had a more positive effect on the hydrodenitrogenation activity than on the hydrodesulfurization activity. In contrast, when phosphorus was incorporated into a tri-metallic WMoNiP/Al O catalyst prepared by a conventional incipient impregnation method, the MSIs decreased causing aggregation of the metal species which resulted in poorer hydrofining performance of the catalyst. These results show that incorporating phosphorus into a WMoNi/Al O catalyst can finely tune the structure of the active phase to enhance the hydrogenation and hydrodenitrogenation activity of the resulting tri-metallic catalyst.

关键词： fluid catalytic cracking diesel hydrofining performance WMoNiP/Al₂O₃ synergetic effect and structure of NiWMoS phases

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A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2021年第15卷第1期页码 4-17 doi: 10.1007/s11705-020-1933-x

摘要： This review article summarizes the key published research on the topic of bio-oil upgrading using catalytic and non-catalytic supercritical fluid (SCF) conditions. The precious metal catalysts Pd, Ru and Pt on various supports are frequently chosen for catalytic bio-oil upgrading in SCFs. This is reportedly due to their favourable catalytic activity during the process including hydrotreating, hydrocracking, and esterification, which leads to improvements in liquid yield, heating value, and pH of the upgraded bio-oil. Due to the costs associated with precious metal catalysts, some researchers have opted for non-precious metal catalysts such as acidic HZSM-5 which can promote esterification in supercritical ethanol. On the other hand, SCFs have been effectively used to upgrade crude bio-oil without a catalyst. Supercritical methanol, ethanol, and water are most commonly used and demonstrate catalyst like activities such as facilitating esterification reactions and reducing solid yield by alcoholysis and hydrolysis, respectively.

关键词： bio-oil upgrading supercritical review

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标题作者时间类型操作

催化裂解架起了炼油与化工之间的桥梁

李再婷

期刊论文

A novel fluid catalytic cracking process for maximizing

Youhao Xu, Shouye Cui

期刊论文

Study on reformulation of fluid catalytic cracking gasoline and increasing production of light olefins

YAN Pingxiang, MENG Xianghai, GAO Jinsen, XU Chunming, SUI Zhiyu

期刊论文

Investigation of phosphate adsorption from an aqueous solution using spent fluid catalytic cracking catalyst

Zhen Li, Zhaofu Qiu, Ji Yang, Benteng Ma, Shuguang Lu, Chuanhui Qin

期刊论文

Effect of hierarchical ZSM-5 zeolite crystal size on diffusion and catalytic performance of n-heptanecracking

Shuman Xu, Xiaoxiao Zhang, Dangguo Cheng, Fengqiu Chen, Xiaohong Ren

期刊论文

Catalytic cracking of endothermic fuels in coated tube reactor

LI Jia, ZOU Jijun, ZHANG Xiangwen, GUO Wei, MI Zhentao

期刊论文

Desulfurization mechanism of FCC gasoline: A review

Liang ZHAO, Yan CHEN, Jinsen GAO, Yu CHEN,

期刊论文

催化裂化过程反应化学的进展

许友好,汪燮卿

期刊论文

Gas-solids separation model of a novel FCC riser terminator device: super short quick separator (SSQS)

LU Chunxi, LI Ruxin, SHI Mingxian, LIU Xiancheng

期刊论文

Effects of microfine aggregate in manufactured sand on bleeding and plastic shrinkage cracking of concrete

Branavan ARULMOLY; Chaminda KONTHESINGHA; Anura NANAYAKKARA

期刊论文

Theoretical study on the confine-stiffening effect and fractal cracking of square concrete filled steel

期刊论文

FUNCTIONAL GAIN OF FRUIT NETTED-CRACKING IN AN INTROGRESSION LINE OF TOMATO WITH HIGHER EXPRESSION OF

期刊论文

Hierarchical approach for fatigue cracking performance evaluation in asphalt pavements

Ibrahim ONIFADE, Yared DINEGDAE, Björn BIRGISSON

期刊论文

Tuning of the active phase structure and hydrofining performance of alumina-supported tri-metallic WMoNi catalysts via phosphorus incorporation

Shufeng Shan, Haiyan Liu, Gang Shi, Xiaojun Bao

期刊论文

A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

期刊论文

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