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Effective remediation of organic-metal co-contaminated soil by enhanced electrokinetic-bioremediation

Fu Chen, Qi Zhang, Jing Ma, Qianlin Zhu, Yifei Wang, Huagen Liang

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1401-y

摘要: Abstract • A new EK-BIO technology was developed to decontaminate e-waste contaminated soil. • Adding sodium citrate in electrolyte was a good choice for decontaminating the soil. • The system has good performance with low cost. This work investigates the influence of electrokinetic-bioremediation (EK-BIO) on remediating soil polluted by persistent organic pollutants (POPs) and heavy metals (mainly Cu, Pb and Ni), originated from electronic waste recycling activity. The results demonstrate that most of POPs and metals were removed from the soil. More than 60% of metals and 90% of POPs in the soil were removed after a 30-day EK-BIO remediation assisted by citrate. A citrate sodium concentration of 0.02 g/L was deemed to be suitable because higher citrate did not significantly improve treatment performance whereas increasing dosage consumption. Citrate increased soil electrical current and electroosmotic flow. After remediation, metal residues mainly existed in stable and low-toxic states, which could effectively lower the potential hazard of toxic metals to the surrounding environment and organisms. EK-BIO treatment influenced soil microbial counts, dehydrogenase activity and community structure.

关键词: Electrokinetic     Co-contamination     Debromination    

Spatial prediction of soil contamination based on machine learning: a review

《环境科学与工程前沿(英文)》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1693-1

摘要:

● A review of machine learning (ML) for spatial prediction of soil contamination.

关键词: Soil contamination     Machine learning     Prediction     Spatial distribution    

Strategies to manage the risk of heavy metal(loid) contamination in agricultural soils

Fang-Jie ZHAO

《农业科学与工程前沿(英文)》 2020年 第7卷 第3期   页码 333-338 doi: 10.15302/J-FASE-2020335

摘要:

Soil contamination with heavy metal(loid)s threatens soil ecological functions, water quality and food safety; the latter is the focus of this review. Cadmium (Cd) and arsenic (As) are the toxic elements of most concern for food safety because they are relatively easily taken up by food crops. Rice is a major contributor of both Cd and As intakes to the Chinese population. Contamination and soil acidification are the main causes of high Cd levels in rice grains produced in some areas of southern China. The risk of Cd and As accumulation in food crops can be mitigated through agronomic practices and crop breeding. Liming is effective and economical at reducing Cd uptake by rice in acid soils. Paddy water management can produce opposite effects on Cd and As accumulation. Many genes controlling Cd and As uptake and translocation have been characterized, paving the way to breeding low accumulating crop cultivars through marker-assisted molecular breeding or genetic engineering. It is important to protect agricultural soils from future contamination. Long-term monitoring of anthropogenic additions and accumulation of heavy metal(loid)s in agricultural soils should be undertaken. Mass-balance models should be constructed to evaluate future trends of metal(loid)s in agricultural soils at a regional scale.

关键词: arsenic     cadmium     food safety     heavy metals     soil contamination    

Nitrobenzene contamination of groundwater in a petrochemical industry site

Yongsheng Zhao, Lin Lin, Mei Hong

《环境科学与工程前沿(英文)》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1107-6

摘要:

The contaminant transport distance is predicted using numerical model.

Zero-valent iron can be used to effectively transform nitrobenzene to aniline.

Experiment shows that two-layer PRB systems have a very good treatment effect.

关键词: Nitrobenzene     Benzene     Groundwater     Zero-valent iron     Permeable reactive barrier    

Evaluating heavy metal contamination of riverine sediment cores in different land-use areas

Wenzhong Tang, Liu Sun, Limin Shu, Chuang Wang

《环境科学与工程前沿(英文)》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1283-4

摘要: Abstract • Metal pollution was studied in riverine sediments from different land-use areas. • Cd was the most serious heavy metal contaminant in riverine sediment cores. • Riverine sediment cores from industrial area were most polluted by heavy metals. • B1 fraction determined metal pollution, risk and toxicity in riverine sediments. Anthropogenic activities are regarded as the main sources of heavy metal pollution, yet few studies have investigated the effects of land-use setting on heavy metal accumulation in riverine sediments. Based on both total contents and geochemical fractions, heavy metal pollution, risk and toxicity were determined in riverine sediment cores from different land-use areas (mountain area- MA, farm area- FA, city area- CA, and industrial area- IA) of the Yang River Basin in North China. The results showed that FA had higher contents of riverine sedimentary Cu; CA had higher contents of Cd; IA had higher contents of both Cd and Zn. Most riverine sediments from FA and IA were contaminated with the investigated metals, although these concentrations were evaluated to have low potential ecological risk and no toxicity to benthic organisms. However, a high proportion of Cd in the B1 fraction of riverine sediments in IA indicating high risk should receive more attention. The B1 fraction largely determined the contamination, risk and toxicity levels associated with heavy metals in the riverine sediments of the Yang River Basin.

关键词: Heavy metals     Riverine sediments     Pollution     Land-use    

E-waste environmental contamination and harm to public health in China

null

《医学前沿(英文)》 2015年 第9卷 第2期   页码 220-228 doi: 10.1007/s11684-015-0391-1

摘要:

The adverse effects of electronic waste (e-waste) on the human body have stirred up concern in recent years. China is one of the countries that confront serious pollution and human exposure of e-waste, and the majority of the population is exposed to potentially hazardous substances that are derived from informal e-waste recycling processes. This study reviews recent reports on human exposure to e-waste in China, with particular focus on exposure routes (e.g., inhalation and ingestion) and several toxicities of human (e.g., endocrine system, respiratory system, reproductive system, developmental toxicity, neurotoxicity, and genetic toxicity). Pieces of evidence that associate e-waste exposure with human health effects in China are assessed. The role of toxic heavy metals (e.g., lead, cadmium, chromium, mercury, and nickel) and organic pollutants (e.g., polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyl (PCBs), polycyclic aromatic hydrocarbons (PAHs), polybrominated biphenyls (PBBs), polyhalogenated aromatic hydrocarbons (PHAHs), bisphenol A (BPA)) on human health is also briefly discussed.

关键词: e-waste     heavy metal     organic pollutant     hazardous     toxicity     human health     China    

Hazard and vulnerability evaluation of water distribution system in cases of contamination intrusion

Kunlun XIN, Tao TAO, Yong WANG, Suiqing LIU

《环境科学与工程前沿(英文)》 2012年 第6卷 第6期   页码 839-848 doi: 10.1007/s11783-012-0409-8

摘要: In this paper, it proposed an index system for hazard and vulnerability evaluations of water distribution networks, based on the simulation of contamination events caused by pollutant injections at different junctions. It attempted to answer the following two questions in the case of contamination events: 1) Which are the most hazardous junctions? 2) Which are the most vulnerable junctions? With EPANET toolkit, it simulated the propagation of the contaminant, and calculated the peak concentration of the contaminant and mass delivered at different nodes. According to types of consumers, different weights were assigned to the consumer nodes for assessing the influence of the contaminant on the consumers. Using the method proposed herein, both the hazard index and vulnerability index were calculated for each node in the pipe network. The presented method was therefore applied to the water network of the city of Zhenjiang, which contains two water plants, two booster pump stations with storage tanks. In conclusion, the response time, the relationships between the peak concentration of contaminant and the total absorption are the most important factors in hazard and vulnerability evaluation of the water distribution network.

关键词: water distribution network     hazard     vulnerability     contaminant accident    

Strain and process engineering toward continuous industrial fermentation

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1336-1353 doi: 10.1007/s11705-022-2284-6

摘要: Most current biotechnology industries are based on batch or fed-batch fermentation processes, which often show low productivity and high production costs compared to chemical processes. To increase the economic competitiveness of biological processes, continuous fermentation technologies are being developed that offer significant advantages in comparison with batch/fed-batch fermentation processes, including: (1) removal of potential substrates and product inhibition, (2) prolonging the microbial exponential growth phase and enhancing productivity, and (3) avoiding repeated fermentation preparation and lowering operation and installation costs. However, several key challenges should be addressed for the industrial application of continuous fermentation processes, including (1) contamination of the fermentation system, (2) degeneration of strains, and (3) relatively low product titer. In this study, we reviewed and discussed metabolic engineering and synthetic biology strategies to address these issues.

关键词: continuous fermentation     productivity     contamination     strain degeneration     metabolic engineering    

Analysis and assessment of heavy metal contamination in surface water and sediments: a case study from

Zhaoming WANG,Ranhao SUN,Haiping ZHANG,Liding CHEN

《环境科学与工程前沿(英文)》 2015年 第9卷 第2期   页码 240-249 doi: 10.1007/s11783-014-0646-0

摘要: Concentrations of the heavy metals Cu, Ni, Pb, Zn, Cd, and Cr were examined in surface water and sediment from the Luan River inChina,. With a decline in Cu and Ni concentration found in surface water at downstream stations. This finding suggests that water currents are a major explanatory factor in heavy metal contamination. The abundance of Cr, Pb, and Cd observed in the middle reaches of the river indicates heavy metal contamination in local areas, although there was an obvious decrease in concentrations in the water downstream of the Daheiting Reservoir. The significant rising trend in Cu, Pb, and Ni seen the sediment farther away from the river also suggests that anthropogenic activities contribute to heavy metal pollution Sediments were therefore used as environmental indicators, with sediment assessment was conducted using the geo-accumulation index ( ) and the potential ecological risk index ( ). The values revealed that Cd (3.13) and Cr (2.39) had accumulated significantly in the Luan River. The values for most (89%) of the sampling stations were higher than 300, suggesting that sediment from the Luan River poses a severe ecological risk, with the potential ecological risks downstream higher than that in the upper and middle streams. Good correlations among Pb/Ni, Pb/Cd, Cu/Pb, and Cu/Cd in the water and Cr/Ni in the sediment were observed. Cluster analysis suggested that Cd may have various origins, being derived from anthropogenic sources.

关键词: heavy metal     water     sediment     geo-accumulation index     Luan River    

Comprehensive evaluation of heavy metal contamination of sediment in Lake Dianchi by using modified AHP

ZHANG Yan, GAO Xiang, ZHONG Zhenyu, PENG Buzhuo, DENG Xihai

《环境科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 370-379 doi: 10.1007/s11783-008-0054-4

摘要: Through the use of general sampling and measurement by Cs dating, problems regarding the absence of monitoring data can easily be resolved. Further, weighted values need to be determined while Environment Quality Comprehensive Index (EQCI) is commonly used as applied in environmental quality comprehensive evaluation. In order to overcome the subjectivity in determining weights, the modified Analytical Hierarchy Process (AHP) method was designed. The modified AHP method involved the following key procedures: First, the parameters and were calculated based on the monitoring data; second, the factors were put in order according to the symbol and value of and ; third, the continuous odd integers, which represented the importance of factors, were given to factors according to their seating order; and, fourth, the factor weights were determined from the pair-wise comparison matrix calculated by the ratio of the given odd integers. Therefore, the weights were completely based on the monitoring data. In the present study, the comprehensive quality of sediments in five sections of Lake Dianchi were evaluated and the results indicated that the current contamination of sediments in each lake section is much more serious than at any other time in history.

关键词: Dianchi     Analytical Hierarchy     monitoring     modified Analytical     importance    

抗多种污染的仿海藻全亲水自漂浮太阳能光热蒸发器 Article

文驰宇, 郭洪爽, 朱迎男, 白浩宇, 赵维强, 王新生, 杨静, 曹墨源, 张雷

《工程(英文)》 2023年 第20卷 第1期   页码 153-161 doi: 10.1016/j.eng.2021.06.029

摘要:

强亲水材料可以在太阳能驱动的海水蒸馏中实现快速的液态水运输和盐结晶溶解。然而,强亲水材料在水中饱和吸水,通常具有与水相近甚至大于水的密度,无法独立自漂浮,从而难以将热量集中在空气/水界面进行界面蒸馏。自然界中,具有内部微气泡的海藻可以漂浮在水面以保证吸收太阳能,从而进行光合作用。受此启发,本研究开发了一种全亲水自漂浮(SIFS)的太阳能光热蒸发器。蒸发器中密集填充的空心玻璃微球赋予蒸发器独立自漂浮和隔热的性能,不需要额外提供浮力支撑,能将热量集中在空气/水界面。两性离子磺基甜菜碱凝胶作为黏合剂和涂层,使蒸发器具有全亲水性质,从而保证持续的水运输,溶解潜在的盐结晶,克服油污染、微生物腐蚀和蛋白质吸附。凭借其独特的全亲水自漂浮性质和优异的抗污性能,该蒸发器有望为新型功能材料的设计和解决复杂环境下光热海水蒸馏的实际问题提供新的思路。

关键词: 超亲水     仿生     自漂浮     抗污     太阳能蒸发器    

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

《能源前沿(英文)》 2023年 第17卷 第3期   页码 428-445 doi: 10.1007/s11708-023-0865-9

摘要: In this work, using fractured shale cores, isothermal adsorption experiments and core flooding tests were conducted to investigate the performance of injecting different gases to enhance shale gas recovery and CO2 geological storage efficiency under real reservoir conditions. The adsorption process of shale to different gases was in agreement with the extended-Langmuir model, and the adsorption capacity of CO2 was the largest, followed by CH4, and that of N2 was the smallest of the three pure gases. In addition, when the CO2 concentration in the mixed gas exceeded 50%, the adsorption capacity of the mixed gas was greater than that of CH4, and had a strong competitive adsorption effect. For the core flooding tests, pure gas injection showed that the breakthrough time of CO2 was longer than that of N2, and the CH4 recovery factor at the breakthrough time (RCH4) was also higher than that of N2. The RCH4 of CO2 gas injection was approximately 44.09%, while the RCH4 of N2 was only 31.63%. For CO2/N2 mixed gas injection, with the increase of CO2 concentration, the RCH4 increased, and the RCH4 for mixed gas CO2/N2 = 8:2 was close to that of pure CO2, about 40.24%. Moreover, the breakthrough time of N2 in mixed gas was not much different from that when pure N2 was injected, while the breakthrough time of CO2 was prolonged, which indicated that with the increase of N2 concentration in the mixed gas, the breakthrough time of CO2 could be extended. Furthermore, an abnormal surge of N2 concentration in the produced gas was observed after N2 breakthrough. In regards to CO2 storage efficiency (Sstorage-CO2), as the CO2 concentration increased, Sstorage-CO2 also increased. The Sstorage-CO2 of the pure CO2 gas injection was about 35.96%, while for mixed gas CO2/N2 = 8:2, Sstorage-CO2 was about 32.28%.

关键词: shale gas     gas injection     competitive adsorption     enhanced shale gas recovery     CO2 geological storage    

CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2

Kechao Zhao,Zhenhua Li,Li Bian

《化学科学与工程前沿(英文)》 2016年 第10卷 第2期   页码 273-280 doi: 10.1007/s11705-016-1563-5

摘要: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

关键词: Mn promotion     nickel catalysts     CO2 methanation     co-methanation of CO and CO2    

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

《化学科学与工程前沿(英文)》 2022年 第16卷 第6期   页码 950-962 doi: 10.1007/s11705-022-2162-2

摘要: A series of Cu–Ce–Zr catalysts with different Ce contents are applied to the hydrogenation of CO2 to CO/CH3OH products. The Cu–Ce–Zr catalyst with 2 wt% Ce loading shows higher CO selectivity (SCO = 0.0%–87.8%) from 200–300 °C, while the Cu–Ce–Zr catalyst with 8 wt% Ce loading presents higher CO2 conversion ( XCO2 = 5.4%–15.6%) and CH3OH selectivity ( SCH3OH = 97.8%–40.6%). The number of hydroxyl groups and solid solution nature play a significant role in changing the reaction pathway. The solid solution enhances the CO2 adsorption ability. At the CO2 adsorption step, a larger number of hydroxyl groups over the Cu–Ce–Zr catalyst with 8 wt% Ce loading leads to the production of H-containing adsorption species. At the CO2 hydrogenation step, a larger number of hydroxyl groups assists in encouraging the further hydrogenation of intermediate species to CH3OH and improving the hydrogenation rate. Hence, the Cu–Ce–Zr catalyst with 8 wt% Ce loading favors CH3OH selectivity and CO2 activation, while CO is preferred on the Cu–Ce–Zr catalyst with 2 wt% Ce loading, a smaller number of hydroxyl groups and a solid solution nature. Additionally, high-pressure in situ diffuse reflectance infrared Fourier transform spectroscopy shows that CO is produced from formate decomposition and that both monodentate formate and bidentate formate are active intermediate species of CO2 hydrogenation to CH3OH.

关键词: CO2 hydrogenation     Cu–Ce–Zr     hydroxyls     CO/CH3OH selectivity    

Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework

《化学科学与工程前沿(英文)》 2022年 第16卷 第7期   页码 1139-1148 doi: 10.1007/s11705-021-2111-5

摘要: The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd+ Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution of PdNi nanoparticles, and lower dissociation and desorption barriers. Comparison of the catalysts synthesized by MIL-101(Cr) and MIL-101-NH2(Cr) as the supports of metals showed that Pd/MIL-101-NH2(Cr) outperforms Pd/MIL-101-(Cr) because of the higher electron density of Pd resulting from the electron donor ability of the NH2 functional group. However, the same activities were observed for Pd70Ni30/MIL-101(Cr) and Pd70Ni30/MIL-101-NH2(Cr), which is due to a less uniform distribution of Pd nanoparticles in Pd70Ni30/MIL-101-NH2(Cr) originated from amorphization of MIL-101-NH2(Cr) structure during the reduction process. In contrast, Pd70Ni30/MIL-101(Cr) revealed the stable structure and activity during reduction and CO oxidation for a long time.

关键词: CO oxidation     heterogeneous catalysis     metal-organic framework     NH2 functional group     PdNi    

标题 作者 时间 类型 操作

Effective remediation of organic-metal co-contaminated soil by enhanced electrokinetic-bioremediation

Fu Chen, Qi Zhang, Jing Ma, Qianlin Zhu, Yifei Wang, Huagen Liang

期刊论文

Spatial prediction of soil contamination based on machine learning: a review

期刊论文

Strategies to manage the risk of heavy metal(loid) contamination in agricultural soils

Fang-Jie ZHAO

期刊论文

Nitrobenzene contamination of groundwater in a petrochemical industry site

Yongsheng Zhao, Lin Lin, Mei Hong

期刊论文

Evaluating heavy metal contamination of riverine sediment cores in different land-use areas

Wenzhong Tang, Liu Sun, Limin Shu, Chuang Wang

期刊论文

E-waste environmental contamination and harm to public health in China

null

期刊论文

Hazard and vulnerability evaluation of water distribution system in cases of contamination intrusion

Kunlun XIN, Tao TAO, Yong WANG, Suiqing LIU

期刊论文

Strain and process engineering toward continuous industrial fermentation

期刊论文

Analysis and assessment of heavy metal contamination in surface water and sediments: a case study from

Zhaoming WANG,Ranhao SUN,Haiping ZHANG,Liding CHEN

期刊论文

Comprehensive evaluation of heavy metal contamination of sediment in Lake Dianchi by using modified AHP

ZHANG Yan, GAO Xiang, ZHONG Zhenyu, PENG Buzhuo, DENG Xihai

期刊论文

抗多种污染的仿海藻全亲水自漂浮太阳能光热蒸发器

文驰宇, 郭洪爽, 朱迎男, 白浩宇, 赵维强, 王新生, 杨静, 曹墨源, 张雷

期刊论文

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

期刊论文

CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2

Kechao Zhao,Zhenhua Li,Li Bian

期刊论文

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

期刊论文

Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework

期刊论文