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Zero E-waste: Regulatory impediments and blockchain imperatives

Mengjun Chen, Oladele A. Ogunseitan

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1402-x

摘要： Abstract • Copyrights on electronic products are impediments in promoting circular economy. • Manufacturers antagonize refurbishment and remanufacturing to maximize profit. • International harmonization of copyright laws will aid repair and remanufacture. • Blockchain–digital immutable ledgers–can promote trust among stakeholders. The concept of zero waste is an ideal situation that will require different solutions for different categories of waste. Electronic waste (E-waste), the fastest growing category of solid hazardous waste presents various unique challenges. Electronic product repair, reuse and remanufacture (3re) are crucial for effective source reduction of E-waste and the integration of the electronics industry into a circular or zero-waste economy framework. Increasingly, 3re implementation is restricted by regulatory difficulties, particularly the invocation of copyright laws. Here, we use the examples of electronic printer cartridges and restored compact discs (CDs) to identify the challenges and to explore solutions for managing the risks associated with E-waste through circular economy and the opportunities presented by innovative Blockchain solutions. A set of international consensuses on judicial definitions, such as 3re, refurbish fake/counterfeit product and copyright exhaustion, are proposed to accelerate source reduction in E-waste management toward the goal of zero waste.

关键词： Blockchain E-waste Regulatory Policy Copyright Laws Repair-Reuse-Remanufacture Toxicity

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Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

《环境科学与工程前沿（英文）》 2014年第8卷第5期页码 792-796 doi: 10.1007/s11783-014-0705-6

摘要： The amount of spent rechargeable lithium batteries (RLBs) is growing rapidly owing to wide application of these batteries in portable electronic devices and electric vehicles, which obliges that spent RLBs should be handled properly. Identification of spent RLBs can supply fundamental information for spent RLBs recycling. This study aimed to determine the differences of physical components and chemical compositions among various spent RLBs. All the samplings of RLBs were rigorously dismantled and measured by an inductive coupled plasma atomic emission spectrometer. The results indicate that the average of total weight of the separator, the anode and the cathode accounted for over 60% of all the RLBs. The weight ratio of valuable metals ranged from 26% to 76%, and approximately 20% of total weight was Cu and Al. Moreover, no significant differences were found among different manufacturers, applications, and electrolyte types. And regarding portable electronic devices, there is also no significant difference in the Co-Li concentration ratios in the leaching liquid of RLBs.

关键词： rechargeable lithium batteries e-waste physical components difference analysis recycling

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risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins/furans at e-waste

《环境科学与工程前沿（英文）》 2023年第17卷第7期 doi: 10.1007/s11783-023-1679-z

摘要：

● Heavy metals and organic toxins may persist in legacy sites for a long time.

关键词： E-waste Human health risk Organ risk Heavy metal toxicity PBDE PCDD/F

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Colloid-facilitated release of polybrominated diphenyl ethers at an e-waste recycling site: evidence

《环境科学与工程前沿（英文）》 2023年第18卷第2期 doi: 10.1007/s11783-024-1781-x

摘要：

● Surface infiltration results in downward migration of PBDEs in soil core.

关键词： Polybrominated diphenyl ether Colloid-facilitated transport E-waste recycling site Undisturbed soil core Groundwater quality

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E-waste environmental contamination and harm to public health in China

null

《医学前沿（英文）》 2015年第9卷第2期页码 220-228 doi: 10.1007/s11684-015-0391-1

摘要：

The adverse effects of electronic waste (e-waste) on the human body have stirred up concern in recent years. China is one of the countries that confront serious pollution and human exposure of e-waste, and the majority of the population is exposed to potentially hazardous substances that are derived from informal e-waste recycling processes. This study reviews recent reports on human exposure to e-waste in China, with particular focus on exposure routes (e.g., inhalation and ingestion) and several toxicities of human (e.g., endocrine system, respiratory system, reproductive system, developmental toxicity, neurotoxicity, and genetic toxicity). Pieces of evidence that associate e-waste exposure with human health effects in China are assessed. The role of toxic heavy metals (e.g., lead, cadmium, chromium, mercury, and nickel) and organic pollutants (e.g., polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyl (PCBs), polycyclic aromatic hydrocarbons (PAHs), polybrominated biphenyls (PBBs), polyhalogenated aromatic hydrocarbons (PHAHs), bisphenol A (BPA)) on human health is also briefly discussed.

关键词： e-waste heavy metal organic pollutant hazardous toxicity human health China

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Sustainability of metal recovery from E-waste

Biswajit Debnath, Ranjana Chowdhury, Sadhan Kumar Ghosh

《环境科学与工程前沿（英文）》 2018年第12卷第6期 doi: 10.1007/s11783-018-1044-9

摘要：

Metal recovery techniques from electronic waste reported in literature.

Metal recovery processes followed in Industries from electronic waste.

Sustainability analysis of metal recovery processes from electronic waste.

关键词： E-waste Metal recovery Metal Recovery from E-waste (MREW) Sustainability

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Analyses of levels of thyroid hormones and its receptor expression in puerperants and newborns from an e-waste

JU Ying, CHEN Lan, JIANG Qi, YANG Kedi, CHEN Xuemin, XU Guojian, LI Liping

《医学前沿（英文）》 2008年第2卷第3期页码 276-282 doi: 10.1007/s11684-008-0052-8

摘要： In this study, the serum levels, including thyroid hormones free triiodothyronine (FT), free thyroxine(FT),thyroid stimulating hormone(TSH)among the subjects from the exposed group ( = 48) and the control group ( = 45) were detected by immuno radiometric assay (IRMA). The expression levels of TR?1, TR?1, TSHR mRNA in placentas and umbilical cords were detected by fluorescent quantitative real-time PCR (FQ-PCR). The correlations between the thyroid hormone levels in maternal serum and umbilical serum, and between the expression levels of its receptors mRNA in placentas and umbilical cords were determined. We found that the FT levels of both maternal serum and umbilical cord serum in the exposed group were lower than those in the control ( < 0.05). However, the increased TSH levels in the exposed group had statistically significance compared to those in the control group ( < 0.05). The TR?1 and TR?1 mRNA levels both in placentas and umbilical cords in the exposed group were lower than those in the control group ( < 0.05 and 0.01). However, the TSHR mRNA levels in the exposed group were significantly different compared to those in the control group ( < 0.01). The serum FT4 and TSH levels of parturient women were positively correlated with those of the newborns in both groups ( < 0.05 and 0.01). The mRNA levels of TR?1, TR?1 and TSHR in the placentas were positively correlated with those in umbilical cords in both groups ( < 0.01). The findings suggest that some environmental pollutants existing in the electronic waste (e-waste) dismantling region may affect the health of local parturient women and newborns, representing changes both in serum levels of thyroid hormones and in mRNA expression of its receptors.

关键词： control immuno radiometric FT TSH exposed

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An updated review and conceptual model for optimizing WEEE management in China from a life cycle perspective

Xiaolong Song, Jingwei Wang, Jianxin Yang, Bin Lu

《环境科学与工程前沿（英文）》 2017年第11卷第5期 doi: 10.1007/s11783-017-0985-8

摘要： Waste electrical and electronic equipment (WEEE) is a rapidly growing category of solid waste. China is now facing WEEE problems from both growing domestic generation and illegal imports. Currently, the amount of WEEE formally treated has increased steadily in China. The layout of the formal sector has been basically completed. Meanwhile, by controlling illegal disassembly activities, the informal sector has been gradually transformed to formal one. Beginning with the overview of the WEEE recycling industry in China, this paper first lists the latest progress in WEEE management from such aspects as the new edition of China RoHS Directive (Restriction of Hazardous Substances Directive), the updated WEEE Treatment List, the updated WEEE fund standard, the revised National Hazardous Waste List, and a brand-new plan on extended producer responsibility. In so doing, we elucidate the current challenges on WEEE management in detail: the imbalance between fund levies and subsidies, the gap in the supervision scope, the homogenization of recycling industry and the lack of life cycle approaches. Finally, a conceptual framework for integrated management of WEEE is proposed from a life cycle perspective. Overall, the life cycle management of WEEE includes three aspects: developing life cycle information for decision-making, implementing life cycle engineering with life cycle tools, and improving WEEE legislation based on life cycle thinking. By providing specific operating strategies, this life cycle framework should help to optimize WEEE management in developing countries where legislation is imperfect and the recycling system is relatively immature.

关键词： Waste electrical and electronic equipment E-waste Life cycle management China

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Recycling polymeric waste from electronic and automotive sectors into value added products

Angadi, Ganapathy E. Paruthy, Partha S. Mukherjee, Miles Park

《环境科学与工程前沿（英文）》 2017年第11卷第5期 doi: 10.1007/s11783-017-0991-x

摘要： The environmentally sustainable disposal and recycling of ever increasing volumes of electronic waste has become global waste management issue. The addition of up to 25% polymeric waste PCBs (printed circuit boards) as fillers in polypropylene (PP) composites was partially successful: while the tensile modulus, flexural strength and flexural modulus of composites were enhanced, the tensile and impact strengths were found to decrease. As a lowering of impact strength can significantly limit the application of PP based composites, it is necessary to incorporate impact modifying polymers such as rubbery particles in the mix. We report on a novel investigation on the simultaneous utilization of electronic and automotive rubber waste as fillers in PP composites. These composites were prepared by using 25 wt.% polymeric PCB powder, up to 9% of ethylene propylene rubber (EPR), and PP: balance. The influence of EPR on the structural, thermal, mechanical and rheological properties of PP/PCB/EPR composites was investigated. While the addition of EPR caused the nucleation of the β crystalline phase of PP, the onset temperature for thermal degradation was found to decrease by 8%. The tensile modulus and strength decreased by 16% and 19%, respectively; and the elongation at break increased by ~71%. The impact strength showed a maximum increase of ~18% at 7 wt.%–9 wt.% EPR content. Various rheological properties were found to be well within the range of processing limits. This novel eco-friendly approach could help utilize significant amounts of polymeric electronic and automotive waste for fabricating valuable polymer composites.

关键词： E-waste Polymer composites Recycling Rubber Waste PCBs Filler

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Ammonia and phosphorus removal from agricultural runoff using cash crop waste-derived biochars

Alisa Salimova, Jian’e Zuo, Fenglin Liu, Yajiao Wang, Sike Wang, Konstantin Verichev

《环境科学与工程前沿（英文）》 2020年第14卷第3期 doi: 10.1007/s11783-020-1225-1

摘要： • Orange tree residuals biochar had a better ability to adsorb ammonia. • Modified tea tree residuals biochar had a stronger ability to remove phosphorus. • Partially-modified biochar could remove ammonia and phosphorus at the same time. • The real runoff experiment showed an ammonia nitrogen removal rate of about 80%. • The removal rate of total phosphorus in real runoff experiment was about 95%. Adsorption of biochars (BC) produced from cash crop residuals is an economical and practical technology for removing nutrients from agricultural runoff. In this study, BC made of orange tree trunks and tea tree twigs from the Laoguanhe Basin were produced and modified by aluminum chloride (Al-modified) and ferric sulfate solutions (Fe-modified) under various pyrolysis temperatures (200°C–600°C) and residence times (2–5 h). All produced and modified BC were further analyzed for their abilities to adsorb ammonia and phosphorus with initial concentrations of 10–40 mg/L and 4–12 mg/L, respectively. Fe-modified Tea Tree BC 2h/400°C showed the highest phosphorus adsorption capacity of 0.56 mg/g. Al-modified Orange Tree BC 3h/500°C showed the best performance for ammonia removal with an adsorption capacity of 1.72 mg/g. FTIR characterization showed that P = O bonds were formed after the adsorption of phosphorus by modified BC, N-H bonds were formed after ammonia adsorption. XPS analysis revealed that the key process of ammonia adsorption was the ion exchange between K+ and NH4+. Phosphorus adsorption was related to oxidation and interaction between PO43– and Fe3+. According to XRD results, ammonia was found in the form of potassium amide, while phosphorus was found in the form of iron hydrogen phosphates. The sorption isotherms showed that the Freundlich equation fits better for phosphorus adsorption, while the Langmuir equation fits better for ammonia adsorption. The simulated runoff infiltration experiment showed that 97.3% of ammonia was removed by Al-modified Orange tree BC 3h/500°C, and 92.9% of phosphorus was removed by Fe-modified Tea tree BC 2h/400°C.

关键词： Biochar Adsorption Ammonia removal Phosphorus removal Agricultural runoff

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Process stability and microbial community composition in pig manure and food waste anaerobic co-digesters

Lawlor, Gillian E. Gardiner, Yan Jiang, Paul Cormican, Matthew S. McCabe, Xinmin Zhan

《环境科学与工程前沿（英文）》 2017年第11卷第3期 doi: 10.1007/s11783-017-0923-9

摘要： This study assessed the effects of reducing hydraulic retention times (HRTs) from 21 days to 10.5 days when anaerobically co-digesting pig manure and food waste. Continuously stirred tank reactors of 3.75 L working volume were operated in triplicate at 42°C. Digester HRT was progressively decreased from 21 to 15 days to 10.5 days, with an associated increase in organic loading rate (OLR) from 3.1 kg volatile solids (VS)·m ·day to 5.1 kg VS·m ·day to 7.25 kg VS·m ·day . Reducing HRT from 21 days to 15 days caused a decrease in specific methane yields and VS removal rates. Operation at a HRT of 10.5 days initially resulted in the accumulation of isobutyric acid in each reactor. High throughput 16S rRNA gene sequencing revealed that this increase coincided with a shift in acidogenic bacterial populations, which most likely resulted in the increased isobutyric acid concentrations. This may in turn have caused the increase in relative abundance of bacteria, which syntrophically degrade non-acetate volatile fatty acids (VFAs) into H and CO . This, along with the increase in abundance of other syntrophic VFA oxidizers, such as suggests that VFA oxidation plays a role in digester operation at low HRTs. Reducing the HRT to below 21 days compromised the ability of the anaerobic digestion system to reduce enteric indicator organism counts below regulatory limits.

关键词： Biogas Sequencing Clocamonaceae Spiorchatetes Isobutyrate Biosafety

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使用分布式富碳废弃物模块化生产附加值产品及燃料 Perspective

Weber, Johnathan E. Holladay

《工程（英文）》 2018年第4卷第3期页码 330-335 doi: 10.1016/j.eng.2018.05.012

摘要：

我们对电解反应堆进行了改造和表征，以完善区域和社区规模的废物向燃料或化学品的转换。整个过程必须能够适应各种原料以及具有内在的安全性，并且不应依赖外部设施获得共反应物或增加排热量和供热量。我们目前的方法是基于对含碳废料的水热液化（HTL）生产的生物油进行升级。水热液化可以将各种原料转化为生物油，与其他解构生物质的方式相比，其需要的升级要少得多。我们目前正在研究将电化学过程用于将生物油通过水热液化转化为燃料或更高价值化学品所需的进一步转化。我们和其他研究者已经证明，电化学还原可以提供足够的反应速率，以及在很小的程度上提供一些必要的通用性。此外，电化学反应器必须在反应器的一侧氧化（去除电子）并在另一侧还原（添加电子）。因此，原则上，这两种类型的反应可以结合以升级生物油，并同时改善在上游水热液化中用作反应物和载体的水。在这里，我们对假定流程、可能的转换化学和水热液化电化学过程的经济性进行了概述。

关键词：减少污染物的产生和排放化学工程

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Take back and treatment of discarded electronics: a scientific update

Ab STEVELS, Jaco HUISMAN, Feng WANG, Jinhui LI, Boyang LI, Huabo DUAN

《环境科学与工程前沿（英文）》 2013年第7卷第4期页码 475-482 doi: 10.1007/s11783-013-0538-8

摘要： This paper indicates that the performance of tack-back and treatment of electronic waste (e-waste) system can be improved substantially. This can be reached by better taking into account in a better way the big variety in material composition and potential toxicity of electrical and electronic products – from a technical, organizational and regulatory perspective. Realizing that there is no ‘one size fit for all’ and combining smart tailor made solutions with economic of sale will result in the best environmental gain/cost ratio. Several examples show how science and engineering have supported or will support this approach.

关键词： e-waste take back treatment substantially

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Integrated approach to winery waste: waste generation and data consolidation

Margarida OLIVEIRA,Elizabeth DUARTE

《环境科学与工程前沿（英文）》 2016年第10卷第1期页码 168-176 doi: 10.1007/s11783-014-0693-6

摘要： The winemaking process involves the generation of a significant amount of waste and wastewater. These residues should be addressed for recycling or treatment before being returned to environment. As each winery is unique in waste generation and disposal, plans for environmentally friendly waste management are not universal and should be tested for their effectiveness. In this study, a diagnostic was made during three years, in different wineries, throughout Portugal, in order to quantify and characterize the waste and the wastewater produced. The results showed that solid waste and wastewater are mainly produced during the harvest period, corresponding to 74% and 87%, respectively. One ton of processed grape approximately produce 0.13 t marc, 0.06 t lees, 0.03 t of stalks and 1.65 m of wastewater. No significant differences ( ≤0.05) were observed for grape marc, lees and wastewater ratios, between years or wineries. With respect to the stalk ratio, there was no effect of year but the winery significantly affected this ratio ( ≤0.05). During the study period the treated wastewater, since diluted, revealed suitable characteristics for irrigation representing an additional source of water. In this regard, the data acquisition and consolidation ensure the transfer of information and experience which constitute an essential step in a support decision tool design.

关键词： waste management wastewater reuse winery wastewater

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The road to sustainable use and waste management of plastics in Portugal

《环境科学与工程前沿（英文）》 2022年第16卷第1期页码 5-5 doi: 10.1007/s11783-021-1439-x

摘要：

• Portugal recycles 34% of the 40 kg/hab year of plastic packaging waste.

关键词： Single-use plastics Plastic packaging Plastic waste Waste management Waste shipment Lightweight plastic bags

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标题作者时间类型操作

Zero E-waste: Regulatory impediments and blockchain imperatives

Mengjun Chen, Oladele A. Ogunseitan

期刊论文

Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

期刊论文

risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins/furans at e-waste

期刊论文

Colloid-facilitated release of polybrominated diphenyl ethers at an e-waste recycling site: evidence

期刊论文

E-waste environmental contamination and harm to public health in China

null

期刊论文

Sustainability of metal recovery from E-waste

Biswajit Debnath, Ranjana Chowdhury, Sadhan Kumar Ghosh

期刊论文

Analyses of levels of thyroid hormones and its receptor expression in puerperants and newborns from an e-waste

JU Ying, CHEN Lan, JIANG Qi, YANG Kedi, CHEN Xuemin, XU Guojian, LI Liping

期刊论文

An updated review and conceptual model for optimizing WEEE management in China from a life cycle perspective

Xiaolong Song, Jingwei Wang, Jianxin Yang, Bin Lu

期刊论文

Recycling polymeric waste from electronic and automotive sectors into value added products

Angadi, Ganapathy E. Paruthy, Partha S. Mukherjee, Miles Park

期刊论文

Ammonia and phosphorus removal from agricultural runoff using cash crop waste-derived biochars

Alisa Salimova, Jian’e Zuo, Fenglin Liu, Yajiao Wang, Sike Wang, Konstantin Verichev

期刊论文

Process stability and microbial community composition in pig manure and food waste anaerobic co-digesters

Lawlor, Gillian E. Gardiner, Yan Jiang, Paul Cormican, Matthew S. McCabe, Xinmin Zhan

期刊论文

使用分布式富碳废弃物模块化生产附加值产品及燃料

Weber, Johnathan E. Holladay

期刊论文

Take back and treatment of discarded electronics: a scientific update

Ab STEVELS, Jaco HUISMAN, Feng WANG, Jinhui LI, Boyang LI, Huabo DUAN

期刊论文

Integrated approach to winery waste: waste generation and data consolidation

Margarida OLIVEIRA,Elizabeth DUARTE

期刊论文

The road to sustainable use and waste management of plastics in Portugal

期刊论文

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