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Effects of La, Ce on nitrogen removal in sequencing batch reactor

Qing XIA , Rui LIANG , Yuning HONG , Lili DING , Hongqiang REN , Yuxiang MAO , Mingyu ZHAO ,

《环境科学与工程前沿(英文)》 2009年 第3卷 第3期   页码 369-374 doi: 10.1007/s11783-009-0036-1

摘要: Batch experiments were conducted to study the short-term biological effects of rare earth ions (La, Ce) and their mixture on the nitrogen removal in a sequencing batch reactor (SBR). The data showed that higher NH―N removal rate, total inorganic nitrogen removal efficiency, and denitrification efficiency were achieved at lower concentrations of rare earth elements (REEs) (<1mg/L). In the first hour of the aeration stage of SBR, the presence of REEs increased the total inorganic nitrogen removal efficiency and NH―N removal efficiency by 15.7% and 10%―15%, respectively. When the concentrations of REEs were higher than 1mg/L, the total inorganic nitrogen removal efficiency decreased, and nitrate was found to accumulate in the effluent. When the concentrations of REEs was up to 50.0mg/L, the total inorganic nitrogen removal efficiency was less than 30% of the control efficiency with a high level of nitrate. Lower concentrations of REEs were found to accelerate the nitrogen conversion and removal in SBR.

关键词: rare earth     La3+     Ce3+     inorganic nitrogen     nitrogen removal     sequencing batch reactor    

Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 440-449 doi: 10.1007/s11705-018-1700-4

摘要:

In recent years, much effort has been focused on the development of the photocatalysts with high performance under visible light irradiation. In this paper, three-dimensional porous La-doped SrTiO3 (LST) microspheres were prepared by a modified sol–gel method, in which the agarose gel/SrCO3 microsphere and La2O3 were employed as the template and the La resource, respectively. The as-prepared LST microspheres exhibit a porous structure with a diameter of about 10 µm and a surface pore size of about 100 nm. The La element was doped into the crystal lattice of SrTiO3 by the substitution of La3+ for Sr2+. Therefore, the absorption edge of LST samples shifts toward the visible light region, and their photocatalytic activity for the Cr(VI) reduction is enhanced under visible light. Among all LST samples, LST-0.5 (the La3+ doping content is 0.5 wt-%) exhibited the highest visible-light photocatalytic activity, which can reduce 84% Cr(VI) within 100 min. This LST materials may become a promising photocatalyst for the facile treatment of wastewater containing poisonous heavy metal ions.

关键词: SrTiO3     La3+ doping     porous microsphere     visible-light photocatalysis     Cr(VI) reduction    

Preparation and catalytic performance of La0.8Sr0.2CoO3 supported on the mullite fiber ceramic

ZENG Lingke, LIU Yanchun, LIU Ping′an, WANG Hui, SHUI Anze, DUAN Bilin

《化学科学与工程前沿(英文)》 2007年 第1卷 第4期   页码 372-376 doi: 10.1007/s11705-007-0067-8

摘要: The perovskite-type LaSrCoO supported on the mullite fiber porous ceramics was prepared by means of the impregnating method, and was then characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD); thus we can come to the conclusion that the perovskite-type composite oxidant can disperse on the surface of mullite fiber ceramics. The catalytic activity of the LaSrCoO for NO and CO was evaluated. The effect of the doped 0.1 wt-% PdCl on the catalytic activity of the perovskite-type LaSrCoO was also discussed. The results show that the conversion rates of NO and CO respectively reaches 74.5% and 99% at 601°C without doped Pd, and both reach 100% at 350°C with a little doped Pd.

关键词: porous     conversion     catalytic activity     electron microscopy     perovskite-type LaSrCoO    

Properties of La1-xCexCoO3 system perovskite-type catalysts for diesel engine exhaust removal

GONG Cairong, FAN Guoliang, HOU Yanfeng, ZHANG Zhongrong, SONG Chonglin, HUANG Qifei

《化学科学与工程前沿(英文)》 2007年 第1卷 第1期   页码 6-10 doi: 10.1007/s11705-007-0002-z

摘要: A series of complex oxide LaCeCoO catalysts was synthesized at a low temperature through a combustion process, in which x is among 0, 0.1, 0.2, 0.4 and 0.6 corresponding to the quantity of La partial substitution by Ce. The catalysts were characterized for phase composition using chemical analysis and X-ray diffraction. The catalytic activity of the catalysts in removal of NO, total hydrocarbon (THC) and particulate matter (PM) from diesel exhaust gases were examined in detail using temperature-programmed reaction technique. The results show that after partial substitution of La with Ce, the oxygen vacancy concentration increases significantly and a Co-Co system is formed. Consequently, the catalytic activity in the removal of THC and NO is significantly improved. But for the PM, the effect is not so obvious. The possible catalytic mechanism for this was presented. It is also worth noting that the doped catalysts showed good stability.

关键词: catalytic mechanism     combustion     corresponding     LaCeCoO     catalytic activity    

PM-support interfacial effect and oxygen mobility in Pt, Pd or Rh-loaded (Ce,Zr,La)O catalysts

《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1369-z

摘要:

• Pt/CZL exhibits the optimum catalytic performance for HC and NOx elimination.

关键词: Precious metal-loaded (Ce     Zr     La)O2 catalysts     Oxygen mobility     Catalytic performance    

LAND-USE INTENSIFICATION TRENDS IN THE RIO DE LA PLATA REGION OF SOUTH AMERICA: TOWARD SPECIALIZATION

《农业科学与工程前沿(英文)》 2021年 第8卷 第1期

摘要:

• Current intensification trends in the Rio de la Plata need urgent re-direction.

•Integrated crop-livestock systems reconcile food production with ecosystem services.

•Case studies validate recoupling as a sustainable way to ecological intensification.

 

The Rio de la Plata region comprises central Argentina, Uruguay, and southern Brazil. Modern agriculture developed around 1900 with recent decades being characterized by the advance of cropping areas over native grasslands. Highly specialized agriculture has decoupled crop and livestock production but has succeeded in intensifying yields. However, significant losses of ecosystem services have been reported. Thus, questions have been raised on the sustainability of this pathway. A glance at world regions that have experienced similar trends suggests that an urgent course correction is needed. A major concern has been the lack of diversity in regions with highly specialized agriculture, promoting renewed interest in integrated crop-livestock systems (ICLS), not only because ICLS are more diverse than specialized systems, but also because they are rare examples of reconciliation between agroecosystem intensification and environmental quality. Consequently, this paper discusses alternatives to redesign multifunctional landscapes based on ICLS. Recent data provide evidence that recoupling crop and animal production increases the resilience of nutrient cycling functions and economic indicators to external stressors, enabling these systems to face climate-market uncertainty and reconcile food production with the provision of diverse ecosystem services. Finally, these concepts are exemplified in case studies where this perspective has been successfully applied.

Degradation of antipyrine in the Fenton-like process with a La-doped heterogeneous catalyst

Shicheng Wei, Cuiping Zeng, Yaobin Lu, Guangli Liu, Haiping Luo, Renduo Zhang

《环境科学与工程前沿(英文)》 2019年 第13卷 第5期 doi: 10.1007/s11783-019-1149-9

摘要: Abstract A La-doped Co-Cu-Fe catalyst was synthesized for the antipyrine (ANT) removal. The La-doped catalyst had higher ANT removal than the control (95% vs. 54%). La reduced the particle size and increased the specific surface area of catalyst. The aim of this study was to synthesize a novel lanthanum (La) doped catalyst and to investigate antipyrine removal in wastewater using the Fenton-like process with the catalyst. The La-doped Co-Cu-Fe catalyst was synthesized using the modified hydrothermal method. Results showed that the La-doped catalyst had higher specific surface area and lower particle size than the catalyst without La doping (i.e., the control) (267 vs. 163 m2/g and 14 vs. 32 nm, respectively). Under the conditions of catalyst dosage 0.5 g/L, H2O2 concentration 1.70 g/L, and NaHCO3 0.1 g/L, the antipyrine removal within 60 min using the Fenton-like process with the La-doped catalyst was much higher than that with the control (95% vs. 54%). The hydroxyl radical concentration with the La-doped catalyst within 60 min was two times higher than that with the control (49.2 vs. 22.1 mg/L). The high catalytic activity of La-doped catalyst was mainly attributed to its high specific surface area based on the X-ray photoelectron spectroscopy result. Our La-doped catalyst should have great potential to remove antipyrine in wastewater using the heterogeneous Fenton-like process.

关键词: Antipyrine     Lanthanum     Catalyst     Fenton-like process    

NO oxidation over Co-La catalysts and NO

Tiejun Zhang,Jian Li,Hong He,Qianqian Song,Quanming Liang

《环境科学与工程前沿(英文)》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0906-x

摘要: The Co-La catalyst (pH= 1) exhibited maximum NO conversion of 43% at 180°C. Acid modified catalyst enhanced the resistance to SO . The formed sulfates may block the pore structure of the catalyst. The NO conversion of compact SCR was 91% at 180°C at the highest space velocity. A series of Co-La catalysts were prepared using the wet impregnation method and the synthesis of catalysts were modified by controlling pH with the addition of ammonium hydroxide or oxalic solution. All the catalysts were systematically investigated for NO oxidation and SO resistance in a fixed bed reactor and were characterized by Brunanuer–Emmett–Teller (BET) method, Fourier Transform infrared spectroscopy (FTIR), X–ray diffraction (XRD), Thermogravimetric (TG) and Ion Chromatography (IC). Among the catalysts, the one synthesized at pH= 1 exhibited the maximum NO conversion of 43% at 180°C. The activity of the catalyst was significantly suppressed by the existence of SO (300 ppm) at 220°C. Deactivation may have been associated with the generation of cobalt sulfate, and the SO adsorption quantity of the catalyst might also have effected sulfur resistance. In the case of the compact selective catalytic reduction (SCR), the activity increased from 74% to 91% at the highest gas hourly space velocity (GHSV) of 300000 h when the NO catalyst maintained the highest activity, in excess of 50% more than that of the standard SCR.

关键词: NO catalytic oxidation     pH effect     Low temperature     Sulfur dioxide     High space velocity     SCR    

室内导航系统视觉标记性能分析 Article

LA DELFA,Salvatore MONTELEONE,Vincenzo CATANIA,Juan F. DE PAZ,Javier BAJO

《信息与电子工程前沿(英文)》 2016年 第17卷 第8期   页码 730-740 doi: 10.1631/FITEE.1500324

摘要: 在本文中,我们对3种可服务于实时应用的2D视觉标记(Vuforia,ArUco标记和AprilTag)进行了定性的性能评估。本文重点研究了附于地表瓷砖的3种视觉标记在特定情况下的表现,提出了最优视觉标记的甄选原则,为我们提出的室内定位导航技术提供技术支撑。

关键词: 室内定位;视觉标记;计算机视觉    

LAND-USE INTENSIFICATION TRENDS IN THE RIO DE LA PLATA REGION OF SOUTH AMERICA: TOWARD SPECIALIZATION

Paulo César DE FACCIO CARVALHO, Jean Víctor SAVIAN, Tomas DELLA CHIESA, William DE SOUZA FILHO, José Alfredo TERRA, Priscila PINTO, Amanda POSSELT MARTINS, Sebastian VILLARINO, Júlio Kuhn DA TRINDADE, Pedro Arthur DE ALBUQUERQUE NUNES, Gervasio PIÑEIRO

《农业科学与工程前沿(英文)》 2021年 第8卷 第1期   页码 97-110 doi: 10.15302/J-FASE-2020380

摘要: The Rio de la Plata region comprises central Argentina, Uruguay, and southern Brazil. Modern agriculture developed around 1900 with recent decades being characterized by the advance of cropping areas over native grasslands. Highly specialized agriculture has decoupled crop and livestock production but has succeeded in intensifying yields. However, significant losses of ecosystem services have been reported. Thus, questions have been raised on the sustainability of this pathway. A glance at world regions that have experienced similar trends suggests that an urgent course correction is needed. A major concern has been the lack of diversity in regions with highly specialized agriculture, promoting renewed interest in integrated crop-livestock systems (ICLS), not only because ICLS are more diverse than specialized systems, but also because they are rare examples of reconciliation between agroecosystem intensification and environmental quality. Consequently, this paper discusses alternatives to redesign multifunctional landscapes based on ICLS. Recent data provide evidence that recoupling crop and animal production increases the resilience of nutrient cycling functions and economic indicators to external stressors, enabling these systems to face climate-market uncertainty and reconcile food production with the provision of diverse ecosystem services. Finally, these concepts are exemplified in case studies where this perspective has been successfully applied.

关键词: grazing     integrated crop-livestock systems     mixed crops-livestock     Pampa    

Synthesis of copolymers of 3-acryloyloxymethyl-3′-methyloxetane and 3-(2-(2-(2-Methoxyethylenoxy)ethylenoxy)ethylenoxy)-3′-methyloxetane and their ionic conductivity properties

YE Lin, ZHAO Yumei, FENG Zengguo, BAI Ying, WU Feng

《化学科学与工程前沿(英文)》 2007年 第1卷 第4期   页码 343-348 doi: 10.1007/s11705-007-0062-0

摘要: An oxetane-derived monomer, 3-acryloyloxymethyl-3′-methyloxetane (AMO) was prepared from the reaction of 3-hydromethyl-3-methyloxetane with acryloyl chloride. The cationic ring-opening copolymerization of AMO with another oxetane-derived monomer, 3-(2-(2-(2-methoxyethylenoxy)ethylenoxy)ethylenoxy)-3′-methyloxetane (MEMO) was conducted in CHCl solution using BF3 ·OEt/1, 4-butanediol as a co-initiator. The resulting copolymers were characterized by FTIR, H NMR and Gel Permeation Chromatography (GPC) analyses, and it was found that the enchained ratio of AMO in the copolymers is far lower than its feed ratio. They were crosslinked via the radical polymerization of the vinyl group initiated by BPO after doping with lithium trifluoromethanesulfonimide (LiTFSI) to give rise to tough polymeric electrolyte films. The ionic conductivity was measured at varying content of AMO and different concentration of lithium salt LiTFSI by AC impedance, and a maximum ion conductivity of 1.44×10 S/cm at 30°C or 1.25×10 S/cm at 80°C was attained in the sample PAM 33 at the mole ratio of O : Li = 20. The DSC results indicated that decreases with the increase of the proportion of AMO in the copolymer, well consistent with the ion conductivity trend. The TGA (thermogravimetric analysis) measurement revealed that this kind of copolymer electrolytes is more thermostable than their liquid counterparts.

关键词: 4-butanediol     2-methoxyethylenoxy     consistent     oxetane-derived     copolymer    

Heterologous expression of signal protein 14-3-3 in and the subsequent immune response in mice

ZHENG Meijuan, SHEN Jilong, LUO Qingli, XU Yuanhong

《医学前沿(英文)》 2008年 第2卷 第1期   页码 95-99 doi: 10.1007/s11684-008-0017-y

摘要: Schistosomiasis japonica, a zoonosis caused by , is endemic to the Philippines and China. Several vaccine candidates have been identified and tested in different animal models, but it is still unclear which will be optimal for testing in the field. Therefore, new antigens and strategies are necessary for vaccine development against schistosomiasis japonica. The Sj14-3-3 gene was amplified and subcloned into the expression vector pPICZ?-B and transformed into X-33 by electroporation. Three transformants were induced with methanol. The cultural supernatant was collected and tested by SDS-PAGE and Western blotting. The protein of rSj14-3-3 was prepared and purified and BALB/c mice were immunized which was followed by a challenging infection. The immuno-protection was then evaluated. The Sj14-3-3 gene was expressed and secreted into the medium and its molecular weight was about 35000 as determined by SDS-PAGE. Western blotting showed that the protein had a high specificity against mouse-anti-Sj14-3-3 monoclonal antibody and rSj14-3-3 had a promising immune reactivity. The results of the immuno-protective experiments revealed that the worm reduction was 26.0%, 32.2%, and 36.8%, respectively. The number of eggs in liver tissue was reduced by 36.8%, 43.2%, and 46.1%, respectively. The recombinant Sj14-3-3 of eukaryotic expression in was successfully harvested. The molecular vaccine of Sj14-3-3 could partially induce resistance to the infection with in BALB/c mice. The recombinant protein Sj14-3-3 has promising immunological potentials for further approach to the diagnosis and development of molecular vaccine.

关键词: development     challenging     rSj14-3-3     resistance     cultural supernatant    

第四届高性能编译、计算和通信国际会议(HP3C 2020)

会议日期: 2020年03月12日

会议地点: 广东广州

主办单位: HP3C 2020

作为免疫疗法靶点的FOXP3及其辅因子 Review

Yasuhiro Nagai,Lian Lam,Mark I. Greene,Hongtao Zhang

《工程(英文)》 2019年 第5卷 第1期   页码 115-121 doi: 10.1016/j.eng.2019.01.001

摘要:

叉头框蛋白P3(FOXP3)是调节性T细胞(Tregs)的一个主要调节因子,调节性T细胞是能抑制抗原特异性免疫反应的T 细胞亚群,在增强宿主耐受性和维持免疫平衡方面发挥着重要作用。众所周知,FOXP3 与多种蛋白质形成复合物,并能通过乙酰化、磷酸化、泛素化和甲基化等各种翻译后修饰(PTM)进行调节。因此,翻译后修饰可改变FOXP3 的稳定性及其调节基因表达的能力,并最终影响调节性T细胞活性。虽然FOXP3 自身并非理想的药物靶点,但脱乙酰酶、乙酰转移酶、激酶和其他可调节FOXP3 的翻译后修饰的酶均为调控FOXP3 和调节性T细胞活性的潜在靶点。但FOXP3 并非这些酶的唯一底物;因此,当使用相关抑制剂时,必须考虑是否存在有害的“FOXP3脱靶”副作用。

关键词: 调节性T细胞     叉头框蛋白P3(FOXP3    翻译后修饰     自体免疫     癌症    

标题 作者 时间 类型 操作

Effects of La, Ce on nitrogen removal in sequencing batch reactor

Qing XIA , Rui LIANG , Yuning HONG , Lili DING , Hongqiang REN , Yuxiang MAO , Mingyu ZHAO ,

期刊论文

Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

期刊论文

Preparation and catalytic performance of La0.8Sr0.2CoO3 supported on the mullite fiber ceramic

ZENG Lingke, LIU Yanchun, LIU Ping′an, WANG Hui, SHUI Anze, DUAN Bilin

期刊论文

Properties of La1-xCexCoO3 system perovskite-type catalysts for diesel engine exhaust removal

GONG Cairong, FAN Guoliang, HOU Yanfeng, ZHANG Zhongrong, SONG Chonglin, HUANG Qifei

期刊论文

PM-support interfacial effect and oxygen mobility in Pt, Pd or Rh-loaded (Ce,Zr,La)O catalysts

期刊论文

LAND-USE INTENSIFICATION TRENDS IN THE RIO DE LA PLATA REGION OF SOUTH AMERICA: TOWARD SPECIALIZATION

期刊论文

Degradation of antipyrine in the Fenton-like process with a La-doped heterogeneous catalyst

Shicheng Wei, Cuiping Zeng, Yaobin Lu, Guangli Liu, Haiping Luo, Renduo Zhang

期刊论文

NO oxidation over Co-La catalysts and NO

Tiejun Zhang,Jian Li,Hong He,Qianqian Song,Quanming Liang

期刊论文

室内导航系统视觉标记性能分析

LA DELFA,Salvatore MONTELEONE,Vincenzo CATANIA,Juan F. DE PAZ,Javier BAJO

期刊论文

LAND-USE INTENSIFICATION TRENDS IN THE RIO DE LA PLATA REGION OF SOUTH AMERICA: TOWARD SPECIALIZATION

Paulo César DE FACCIO CARVALHO, Jean Víctor SAVIAN, Tomas DELLA CHIESA, William DE SOUZA FILHO, José Alfredo TERRA, Priscila PINTO, Amanda POSSELT MARTINS, Sebastian VILLARINO, Júlio Kuhn DA TRINDADE, Pedro Arthur DE ALBUQUERQUE NUNES, Gervasio PIÑEIRO

期刊论文

虞晓含:中医话健康,食补改善免疫力(2020年3月1日)

2022年04月18日

会议视频

Synthesis of copolymers of 3-acryloyloxymethyl-3′-methyloxetane and 3-(2-(2-(2-Methoxyethylenoxy)ethylenoxy)ethylenoxy)-3′-methyloxetane and their ionic conductivity properties

YE Lin, ZHAO Yumei, FENG Zengguo, BAI Ying, WU Feng

期刊论文

Heterologous expression of signal protein 14-3-3 in and the subsequent immune response in mice

ZHENG Meijuan, SHEN Jilong, LUO Qingli, XU Yuanhong

期刊论文

第四届高性能编译、计算和通信国际会议(HP3C 2020)

2020年03月12日

会议信息

作为免疫疗法靶点的FOXP3及其辅因子

Yasuhiro Nagai,Lian Lam,Mark I. Greene,Hongtao Zhang

期刊论文