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过硫酸盐诱导的缺陷氮化碳中三配位氮(N3C)空位增强光催化产过氧化氢 Article

缪蔚, 王奕杰, 刘莹, 秦贺贺, 褚成成, 毛舜

《工程(英文)》 2023年 第25卷 第6期   页码 214-221 doi: 10.1016/j.eng.2021.12.016

摘要: 其中石墨氮化碳(g-C3N4)被认为是最有前途的合成过氧化氢的光催化剂之一;并且,在g-C3N4中引入氮空位已被证明是提高其光催化活性的有效策略在此,本文提出了一种简便的过硫酸钠共晶聚合方法,制备了具有丰富三配位氮空位(N3C)的g-C3N4。本研究的结果表明,在g-C3N4中引入N3C空位可以成功地拓宽光吸收范围,抑制光激发电荷的重组,增强O2的吸附和活化富含N3C空位的g-C3N4的光催化过氧化氢产量是原始g-C3N4的4.5倍。本研究提出了在g-C3N4中引入N3C空位的新策略,为开发光催化产过氧化氢的活性催化剂提供了一种新方法。

关键词: 氮化碳     N3C空位     过氧化氢     光催化     过硫酸盐    

Multi-functional 3D N-doped TiO

Zijian Cui, Kaiyue Zhang, Guangyu Xing, Yaqing Feng, Shuxian Meng

《化学科学与工程前沿(英文)》 2017年 第11卷 第3期   页码 395-404 doi: 10.1007/s11705-017-1643-1

摘要: Three-dimensional TiO microspheres doped with N were synthesized by a simple single-step solvothermal method and the sample treated for 15 h (hereafter called TMF) was then used as scattering layers in the photoanodes of dye-sensitized solar cells (DSSCs). The TMF was characterized using scanning electron microscopy, high resolution transmission electron microscopy, Brunauer-Emmett-Teller measurements, X-ray diffraction, and X-ray photoelectron spectroscopy. The TMF had a high surface area of 93.2 m ·g which was beneficial for more dye-loading. Five photoanode films with different internal structures were fabricated by printing different numbers of TMF scattering layers on fluorine-doped tin oxide glass. UV-vis diffuse reflection spectra, incident photon-to-current efficiencies, photocurrent-voltage curves and electrochemical impedance spectroscopy were used to investigate the optical and electrochemical properties of these photoanodes in DSSCs. The presence of nitrogen in the TMF changed the TMF microstructure, which led to a higher open circuit voltage and a longer electron lifetime. In addition, the presence of the nitrogen significantly improved the light utilization and photocurrent. The highest photoelectric conversion efficiency achieved was 8.08%, which is much higher than that derived from typical P25 nanoparticles (6.52%).

关键词: DSSCs     N doping     scattering layer     electron lifetime    

Rh2O3/hexagonal CePO4 nanocatalysts for N2O decomposition

Huan Liu, Zhen Ma

《化学科学与工程前沿(英文)》 2017年 第11卷 第4期   页码 586-593 doi: 10.1007/s11705-017-1659-6

摘要: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

关键词: Rh2O3     CePO4     N2O decomposition    

Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study

《化学科学与工程前沿(英文)》 2023年 第17卷 第12期   页码 1986-2000 doi: 10.1007/s11705-023-2337-5

摘要: Breakage of the C–N bond is a structure sensitive process, and the catalyst size significantly affects its activity. On the active metal nanoparticle scale, the role of catalyst size in C–N bond cleavage has not been clearly elucidated. So, Ru catalysts with variable nanoparticle sizes were obtained by modulating the reduction temperature, and the catalytic activity was evaluated using 1,2,3,4-tetrahydroquinoline and o-propylaniline with different C–N bond hybridization patterns as reactants. Results showed a 13 times higher reaction rate for sp3-hybridized C–N bond cleavage than sp2-hybridized C–N bond cleavage, while the reaction rate tended to increase first and then decrease as the catalyst nanoparticle size increased. Different concentrations of terrace, step, and corner sites were found in different sizes of Ru nanoparticles. The relationship between catalytic site variation and C–N bond cleavage activity was further investigated by calculating the turnover frequency values for each site. This analysis indicates that the variation of different sites on the catalyst is the intrinsic factor of the size dependence of C–N bond cleavage activity, and the step atoms are the active sites for the C–N bond cleavage. When Ru nanoparticles are smaller than 1.9 nm, they have a strong adsorption effect on the reactants, which will affect the catalytic performance of the Ru catalyst. Furthermore, these findings were also confirmed on other metallic Pd/Pt catalysts. The role of step sites in C–N bond cleavage was proposed using the density function theory calculations. The reactants have stronger adsorption energies on the step atoms, and step atoms have d-band center nearer to the Fermi level. In this case, the interaction with the reactant is stronger, which is beneficial for activating the C–N bond of the reactant.

关键词: sp3/sp2-hybridized C–N bond     noble metal nanoparticle     catalytic active site     turnover frequency     DFT    

3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 417-424 doi: 10.1007/s11705-018-1711-1

摘要:

A highly active bi-functional electrocatalyst towards both hydrogen and oxygen evolution reactions is critical for the water splitting. Herein, a self-supported electrode composed of 3D network nanostructured NiCoP nanosheets grown on N-doped carbon coated Ni foam (NiCoP/NF@NC) has been synthesized by a hydrothermal route and a subsequent phosphorization process. As a bifunctional electrocatalyst, the NiCoP/NF@NC electrode needs overpotentials of 31.8 mV for hydrogen evolution reaction and 308.2 mV for oxygen evolution reaction to achieve the current density of 10 mA·cm2 in 1 mol·L1 KOH electrolyte. This is much better than the corresponding monometal catalysts of CoP/NF@NC and NiP/NF@NC owing to the synergistic effect. NiCoP/NF@NC also exhibits low Tafel slope, and excellent long-term stability, which are comparable to the commercial noble catalysts of Pt/C and RuO2.

关键词: bimetallic phosphides     N-doped carbon     self-support     hydrogen evolution     oxygen evolution    

Enhanced biohydrogen generation from organic wastewater containing N H 4 + by phototrophic bacteria Rhodobactergeneration from organic wastewater containing N H 4 + by phototrophic bacteria Rhodobacter sphaeroides AR-3

Guanghong ZHENG, Zhuhui KANG, Yifan QIAN, Lei WANG,

《环境科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 387-392 doi: 10.1007/s11783-009-0154-9

摘要: Haifa RAJHI,Daniel PUYOL,Mirna C. MARTÍNEZ,Emiliano E. DÍAZ,José L. SANZ. [J]. Front. Environ. Sci. Eng., 2016, 10(3): 513-521.Yongtao LV,Xuan CHEN,Lei WANG,Kai JU,Xiaoqiang CHEN,Rui MIAO,Xudong WANG. [J]. Front. Environ. Sci. Eng., 2016, 10(2): 390-398.Zulkifly JEMAAT,Josep Anton TORA,Albert BARTROLI,Julián CARRERA,Julio PEREZ. [J]. Front. Environ. Sci. Eng., 2015, 9(3): 528-533.Wei LI, Xiaowen DING, Min LIU, Yuewen GUO, Lei LIU. [J]. Front Envir Sci Eng, 2012, 6(6): 892-900.Guochen ZHENG, Jianzheng LI, Feng ZHAO, Liguo ZHANG, Li WEI, Qiaoying BAN, Yongsheng ZHAO. [J]. Front Envir Sci Eng, 2012, 6(1): 125-130.Hailong LIN, Weiguang LI, Changhong GUO, Sihang QU, Nanqi REN. [J]. Front Envir Sci Eng Chin, 2011, 5(4): 519-525.Daijun ZHANG, Cui BAI, Ting TANG, Qing YANG. [J]. Front Envir Sci Eng Chin, 2011, 5(2): 291-297.Yanhui ZHAN, Jianwei LIN, Yanling QIU, Naiyun GAO, Zhiliang ZHU. [J]. Front Envir Sci Eng Chin, 2011, 5(1): 65-75.Rongchang WANG, Xinmin ZHAN, Yalei ZHANG, Jianfu ZHAO. [J]. Front Envir Sci Eng Chin, 2011, 5(1): 48-56.Bo WANG, Wei WAN, Jianlong WANG, . [J]. Front.Environ.Sci.Eng., 2009, 3(4): 380-386.GUO Jinsong, YANG Guohong, FANG Fang, QIN Yu. [J]. Front.Environ.Sci.Eng., 2008, 2(4): 439-445.GENG Bing, ZHU Yanfang, JIN Zhaohui, LI Tielong, KANG Haiyan, WANG Shuaima. [J]. Front.Environ.Sci.Eng., 2007, 1(3): 357-361.WU Deyi, HU Zhanbo, WANG Xinze, HE Shengbing, KONG Hainan. [J]. Front.Environ.Sci.Eng., 2007, 1(2): 213-220.XU Zhengyong, YANG Zhaohui, ZENG Guangming, XIAO Yong, DENG Jiuhua. [J]. Front.Environ.Sci.Eng., 2007, 1(1): 43-48.

关键词: ammonium     anoxygenic phototrophic bacterium     biohydrogen     glutamine auxotrophic     tofu wastewater    

结构功能一体化的高性能陶瓷材料的研究与开发

江东亮

《中国工程科学》 2003年 第5卷 第2期   页码 35-39

摘要: 低成本制备等要求出发, 并就现有高性能陶瓷材料的基本性能和材料制备工艺上的优缺点进行了分析;简要介绍了碳化硅(SiC)陶瓷、 添加Nd的钇铝石榴子石(Nd-YAG)陶瓷、掺有稀土的氮化硅(RE-Si3N4)陶瓷等几种具有结构和功能一体化高性能陶瓷材料的优良性能,可能的应用以及目前存在的问题,特别是在基础研究和制备科学上今后应予以关注的方面。

关键词: 结构和功能一体化     高性能陶瓷     碳化硅     Nd-YAG     RE-Si3N4    

FMO3--TMAO axis modulates the clinical outcome in chronic heart-failure patients with reduced ejection

《医学前沿(英文)》 2022年 第16卷 第2期   页码 295-305 doi: 10.1007/s11684-021-0857-2

摘要: The association among plasma trimethylamine-N-oxide (TMAO), FMO3 polymorphisms, and chronic heart failure (CHF) remains to be elucidated. TMAO is a microbiota-dependent metabolite from dietary choline and carnitine. A prospective study was performed including 955 consecutively diagnosed CHF patients with reduced ejection fraction, with the longest follow-up of 7 years. The concentrations of plasma TMAO and its precursors, namely, choline and carnitine, were determined by liquid chromatography-mass spectrometry, and the FMO3 E158K polymorphisms (rs2266782) were genotyped. The top tertile of plasma TMAO was associated with a significant increment in hazard ratio (HR) for the composite outcome of cardiovascular death or heart transplantation (HR=1.47, 95% CI=1.13–1.91, P=0.004) compared with the lowest tertile. After adjustments of the potential confounders, higher TMAO could still be used to predict the risk of the primary endpoint (adjusted HR=1.33, 95% CI=1.01–1.74, P=0.039). This result was also obtained after further adjustment for carnitine (adjusted HR=1.33, 95% CI=1.01–1.74, P=0.039). The FMO3 rs2266782 polymorphism was associated with the plasma TMAO concentrations in our cohort, and lower TMAO levels were found in the AA-genotype. Thus, higher plasma TMAO levels indicated increased risk of the composite outcome of cardiovascular death or heart transplantation independent of potential confounders, and the FMO3 AA-genotype in rs2266782 was related to lower plasma TMAO levels.

关键词: chronic heart failure     trimethylamine-N-oxide     flavin monooxygenase 3     single nucleotide polymorphism    

Strategy for robot motion and path planning in robot taping

Qilong YUAN,I-Ming CHEN,Teguh Santoso LEMBONO,Simon Nelson LANDÉN,Victor MALMGREN

《机械工程前沿(英文)》 2016年 第11卷 第2期   页码 195-203 doi: 10.1007/s11465-016-0390-1

摘要:

Covering objects with masking tapes is a common process for surface protection in processes like spray painting, plasma spraying, shot peening, etc. Manual taping is tedious and takes a lot of effort of the workers. The taping process is a special process which requires correct surface covering strategy and proper attachment of the masking tape for an efficient surface protection. We have introduced an automatic robot taping system consisting of a robot manipulator, a rotating platform, a 3D scanner and specially designed taping end-effectors. This paper mainly talks about the surface covering strategies for different classes of geometries. The methods and corresponding taping tools are introduced for taping of following classes of surfaces: Cylindrical/extended surfaces, freeform surfaces with no grooves, surfaces with grooves, and rotational symmetrical surfaces. A collision avoidance algorithm is introduced for the robot taping manipulation. With further improvements on segmenting surfaces of taping parts and tape cutting mechanisms, such taping solution with the taping tool and the taping methodology can be combined as a very useful and practical taping package to assist humans in this tedious and time costly work.

关键词: robot taping     path planning     robot manipulation     3D scanning    

Assessment of an alternative to deep foundations in compressible clays: the structural cell foundation

MARTÍNEZ-GALVÁN, Miguel P. ROMO

《结构与土木工程前沿(英文)》 2018年 第12卷 第1期   页码 67-80 doi: 10.1007/s11709-017-0399-5

摘要: The new type of deep foundation for buildings on saturated, compressible-low strength clayey soil deposits, branded structural cell essentially consists of a rigid concrete top slab, structurally connected to reinforced concrete peripheral walls (diaphragms) that enclose the natural soil. Accordingly, as the initial volume of the confined soft clays within the lateral stiff diaphragms will remain constant upon loading, the hollowed structural cell will be “transformed” into a very large cross-section pillar of unit weight slightly higher than that of the natural soft clayey soil. This type of foundation seems to be a highly competitive alternative to the friction pile-box foundations (widely used in Mexico City clays), due to its economic and environmental advantages. Economies result, for example, from the absence of huge excavations hence sparing the need of earth retaining structures. Further savings result from appreciably smaller concrete volumes required for building the structural cell than the friction pile-box foundation; moreover, the construction time of the former is much shorter than that of the latter. Regarding the impact to the environment, less air contamination follows from the fact that both traffic jams and soil excavation lessen appreciably. Considering these facts and others regarding scheduling, it was decided to replace 48-friction pile-box foundations specified in the master plan project by this new type of foundation. The overall behavior of these cell foundations over a five-year period is fared from close visual observations and their leveling during the first three years after their construction.

关键词: deep foundations     bearing capacity     resistant moment     structural cell     3D numerical modeling    

Recent advances in special morphologic photocatalysts for NO removal

《环境科学与工程前沿(英文)》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1573-0

摘要:

● Systematic information of recent progress in photocatalytic NO x removal is provided.

关键词: NOx removal     Photocatalyst     Graphene     C3N4     Bi-based compounds.    

Comparison of the morphology and structure of WO

Diah Susanti, Stefanus Haryo N, Hasnan Nisfu, Eko Prasetio Nugroho, Hariyati Purwaningsih, George Endri

《化学科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 371-380 doi: 10.1007/s11705-012-1215-3

摘要: Tungsten (VI) oxide (WO ) nanomaterials were synthesized by a sol-gel method using WCl and C H OH as precursors followed by calcination or hydrothermal treatment. X-Ray diffraction (XRD), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM) equipped with energy dispersive X-ray spectroscopy (EDX) were used to characterize the structure and morphology of the materials. There were significant differences between the WO materials that were calcinated and those that were subjected to a hydrothermal process. The XRD results revealed that calcination temperatures of 300°C and 400°C gave hexagonal structures and temperatures of 500°C and 600°C gave monoclinic structures. The SEM images showed that an increase in calcination temperature led to a decrease in the WO powder particle size. The TEM analysis showed that several nanoparticles agglomerated to form bigger clusters. The hydrothermal process produced hexagonal structures for holding times of 12, 16, and 20 h and monoclinic structures for a holding time of 24 h. The SEM results showed transparent rectangular particles which according to the TEM results originated from the aggregation of several nanotubes.

关键词: WO3 nanomaterial     sol-gel method     calcination     hydrothermal    

黄淮海平原浅层地下水中NO3-N含量的空间变异与分布特征

李保国,白由路,胡克林,黄元仿,陈德立

《中国工程科学》 2001年 第3卷 第4期   页码 42-45

摘要:

通过GPS定位取样分析和GIS处理,研究了黄淮海平原浅层地下水中NO3-N含量的空间变异和分布特征。结果表明,黄淮海平原浅层地下水中NO3-N含量在35~50km的取样密度下,没有半方差结构,各取样点之间变异性较大;黄淮海平原有10%的面积浅层地下水中NO3徐州至连云港一带的苏北地区及山东的潍坊地区,浅层地下水中的NO3-N含量一般在10~20 mg·L-1之间,约占黄淮海平原总面积的11.5%。浅层地下水中NO3-N 的含量与地下水埋深密切相关,NO3-N含量超过20 mg·L-1的地下水埋深一般在3 m以上,地下水埋深在这表明,目前通过土壤NO3-N的淋失对该区地下水中 NO3-N含量影响深度一般不超过10 m。

关键词: 黄淮海平原     地下水     NO3-N     空间分布    

面向5G n260应用的低成本基片集成空腔波导高次模背腔缝隙天线阵

齐紫航1,2,3,李秀萍1,2,3,朱华1,2,3

《信息与电子工程前沿(英文)》 2021年 第22卷 第4期   页码 609-614 doi: 10.1631/FITEE.2000503

摘要: 本文面向5G n260频段应用,提出一款采用低成本FR-4 PCB板材设计的缝隙天线阵。天线底部由2.4 mm同轴馈电,通过ESIW功分馈电网络,缝隙耦合激励4×4个腔体中的TE340模式,每个TE340模式的腔体通过顶层的3×4个缝隙辐射,形成12×16的缝隙阵列。S参数−8 dB带宽可覆盖n260的37–40 GHz频率范围。测试的最大实际增益为27 dBi,通过与仿真的方向性系数对比,可估计得到天线辐射效率约为72.4%。

Tuning nitrogen defects and doping sulfur in carbon nitride for enhanced visible light photocatalytic activity

《化学科学与工程前沿(英文)》 2023年 第17卷 第1期   页码 93-101 doi: 10.1007/s11705-022-2175-x

摘要: Defect construction and heteroatom doping are effective strategies for improving photocatalytic activity of carbon nitride (g-C3N4). In this work, N defects were successfully prepared via cold plasma. High-energy electrons generated by plasma can produce N defects and embed sulfur atoms into g-C3N4. The N defects obviously promoted photocatalytic degradation performance that was 7.5 times higher than that of pure g-C3N4. The concentration of N defects can be tuned by different power and time of plasma. With the increase in N defects, the photocatalytic activity showed a volcanic trend. The g-C3N4 with moderate concentration of N defects exhibited the highest photocatalytic activity. S-doped g-C3N4 exhibited 11.25 times higher photocatalytic activity than pure g-C3N4. It provided extra active sites for photocatalytic reaction and improved stability of N defects. The N vacancy-enriched and S-doped g-C3N4 are beneficial for widening absorption edge and improving the separation efficiency of electron and holes.

关键词: g-C3N4     nitrogen defect     sulfur doping     photodegradation     plasma    

标题 作者 时间 类型 操作

过硫酸盐诱导的缺陷氮化碳中三配位氮(N3C)空位增强光催化产过氧化氢

缪蔚, 王奕杰, 刘莹, 秦贺贺, 褚成成, 毛舜

期刊论文

Multi-functional 3D N-doped TiO

Zijian Cui, Kaiyue Zhang, Guangyu Xing, Yaqing Feng, Shuxian Meng

期刊论文

Rh2O3/hexagonal CePO4 nanocatalysts for N2O decomposition

Huan Liu, Zhen Ma

期刊论文

Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study

期刊论文

3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

期刊论文

Enhanced biohydrogen generation from organic wastewater containing N H 4 + by phototrophic bacteria Rhodobactergeneration from organic wastewater containing N H 4 + by phototrophic bacteria Rhodobacter sphaeroides AR-3

Guanghong ZHENG, Zhuhui KANG, Yifan QIAN, Lei WANG,

期刊论文

结构功能一体化的高性能陶瓷材料的研究与开发

江东亮

期刊论文

FMO3--TMAO axis modulates the clinical outcome in chronic heart-failure patients with reduced ejection

期刊论文

Strategy for robot motion and path planning in robot taping

Qilong YUAN,I-Ming CHEN,Teguh Santoso LEMBONO,Simon Nelson LANDÉN,Victor MALMGREN

期刊论文

Assessment of an alternative to deep foundations in compressible clays: the structural cell foundation

MARTÍNEZ-GALVÁN, Miguel P. ROMO

期刊论文

Recent advances in special morphologic photocatalysts for NO removal

期刊论文

Comparison of the morphology and structure of WO

Diah Susanti, Stefanus Haryo N, Hasnan Nisfu, Eko Prasetio Nugroho, Hariyati Purwaningsih, George Endri

期刊论文

黄淮海平原浅层地下水中NO3-N含量的空间变异与分布特征

李保国,白由路,胡克林,黄元仿,陈德立

期刊论文

面向5G n260应用的低成本基片集成空腔波导高次模背腔缝隙天线阵

齐紫航1,2,3,李秀萍1,2,3,朱华1,2,3

期刊论文

Tuning nitrogen defects and doping sulfur in carbon nitride for enhanced visible light photocatalytic activity

期刊论文