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Generation of enhanced stability of SnO/In(OH)/InP for photocatalytic water splitting by SnO protection

《能源前沿（英文）》 2021年 第15卷 第3期   页码 710-720 doi: 10.1007/s11708-021-0764-x

摘要： InP shows a very high efficiency for solar light to electricity conversion in solar cell and may present an expectation property in photocatalytic hydrogen evolution. However, it suffers serious corrosion in water dispersion. In this paper, it is demonstrated that the stability and activity of the InP-based catalyst are effectively enhanced by applying an anti-corrosion SnO layer and In(OH)3 transition layer, which reduces the crystal mismatch between SnO and InP and increases charge transfer. The obtained Pt/SnO/In(OH)3/InP exhibits a hydrogen production rate of 144.42 µmol/g in 3 h under visible light illumination in multi-cycle tests without remarkable decay, 123 times higher than that of naked In(OH)3/InP without any electron donor under visible irradiation.

关键词： SnO/In(OH)3/InP photocatalyst     enhanced activity and stability for water splitting     corrosion inhibition     enhancing charge transfer and decreasing crystal mismatch    

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Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH

Hong SUN,Min SUN,Yaobin ZHANG,Xie QUAN

《环境科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 591-595 doi: 10.1007/s11783-014-0694-5

摘要： Catalytic ozonation of Reactive Red X-3B in aqueous solution had been carried out in an ozone oxidation reactor where Mn-Fe-ceramic honeycomb was used as the catalysts. The presence of Mn-Fe-ceramic honeycomb catalyst could obviously improve the decoloration efficiency of Reactive Red X-3B and the utilization efficiency of ozone compared to the results from non-catalytic ozonation. Adsorption of Reactive Red X-3B had no obviously influence on the degradation efficiency. Addition of tert-butanol significantly decreased the degradation efficiency, indicating that the degradation of Reactive Red X-3B followed the mechanism of hydroxyl radical (OH·) oxidation. The operating variables such as reaction pressure and ozone supply had a positive influence on the degradation efficiency, mainly attributing to facilitate the ozone decomposition and OH· formation.

关键词： catalytic ozonation     reactive red X-3B     ceramic honeycomb     hydroxyl radical (OH·)    

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Complete oxidation of methane on CoO-SnO catalysts

Xingfu TANG , Jiming HAO , Junhua LI ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 265-270 doi: 10.1007/s11783-009-0019-2

摘要： CoO-SnO hybrid oxides were prepared by the coprecipitation method and were used to oxidate methane (CH) in presence of oxygen. The CoO-SnO with a molar ratio of Co/(Co+Sn) at 0.75 exhibited the highest catalytic activity among all the CoO-SnO hybrid oxides. Experimental results showed that the catalysts were considerably stable in the CH combustion reaction, and were verified by X-ray photoelectron spectra (XPS). It was found that CoO was the active species, and SnO acted as a support or a promoting component in the CoO-SnO hybrid oxides. The surface area was not a major factor that affected catalytic activity. The hydrogen temperature-programmed reduction (H-TPR) results demonstrated that the interaction between cobalt and tin oxides accelerated the mobility of oxygen species of CoO-SnO, leading to higher catalytic activity.

关键词： Co3O4-SnO2     complete oxidation     methane (CH4)    

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Formation of CaCO hollow microspheres in carbonated distiller waste from Solvay soda ash plants

《化学科学与工程前沿（英文）》   页码 1659-1671 doi: 10.1007/s11705-022-2173-z

摘要： For decades, distiller waste and CO2 were not the first choice for production of high valued products. Here, CaCO3 hollow microspheres, a high-value product was synthesized from such a reaction system. The synthetic methods, the formation mechanism and operational cost were discussed. When 2.5 L·min–1·L–1 CO2 was flowed into distiller waste (pH = 11.4), spheres with 4–13 μm diameters and about 2 μm shell thickness were obtained. It is found that there is a transformation of CaCO3 particles from solid-cubic nuclei to hollow spheres. Firstly, the Ca(OH)2 in the distiller waste stimulated the nucleation of calcite with a non-template effect and further maintained the calcite form and prevented the formation of vaterite. Therefore, in absence of auxiliaries, the formation of hollow structures mainly depended on the growth and aging of CaCO3. Studies on the crystal morphology and its changes during the growth process point to the inside–out Ostwald effect in the formation of hollow spheres. Change in chemical properties of the bulk solution caused changes in interfacial tension and interfacial energy, which promoted the morphological transformation of CaCO3 particles from cubic calcite to spherical clusters. Finally, the flow process for absorption of CO2 by distiller waste was designed and found profitable.

关键词： distiller waste     CO2     hollow microsphere     CaCO3     Ca(OH)2     inside−out Ostwald effect    

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A mini-review of ferrites-based photocatalyst on application of hydrogen production

《能源前沿（英文）》 2021年 第15卷 第3期   页码 621-630 doi: 10.1007/s11708-021-0761-0

摘要： Photocatalytic water splitting for hydrogen production is a promising strategy to produce renewable energy and decrease production cost. Spinel-ferrites are potential photocatalysts in photocatalytic reaction system due to their room temperature magnetization, the high thermal and chemical stability, narrow bandgap with broader visible light absorption, and proper conduction band energy level with strong oxidation activity for water or organic compounds. However, the fast recombination of the photoexcited electrons and holes is a critical drawback of ferrites. Therefore, the features of crystallinity, particle size, specific surface area, morphology, and band energy structure have been summarized and investigated to solve this issue. Moreover, composites construction with ferrites and the popular support of TiO2 or g-C3N4 are also summarized to illustrate the advanced improvement in photocatalytic hydrogen production. It has been shown that ferrites could induce the formation of metal ions impurity energy levels in TiO2, and the strong oxidation activity of ferrites could accelerate the oxidation reaction kinetics in both TiO2/ferrites and g-C3N4/ferrites systems. Furthermore, two representative reports of CaFe2O4/MgFe2O4 composite and ZnFe2O4/CdS composite are used to show the efficient heterojunction in a ferrite/ferrite composite and the ability of resistance to photo-corrosion, respectively.

关键词： photocatalyst     spinel-ferrite     composite     photocatalytic hydrogen production    

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An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 950-962 doi: 10.1007/s11705-022-2162-2

摘要： A series of Cu–Ce–Zr catalysts with different Ce contents are applied to the hydrogenation of CO2 to CO/CH3OH products. The Cu–Ce–Zr catalyst with 2 wt% Ce loading shows higher CO selectivity (SCO = 0.0%–87.8%) from 200–300 °C, while the Cu–Ce–Zr catalyst with 8 wt% Ce loading presents higher CO2 conversion ( XCO2 = 5.4%–15.6%) and CH3OH selectivity ( SCH3OH = 97.8%–40.6%). The number of hydroxyl groups and solid solution nature play a significant role in changing the reaction pathway. The solid solution enhances the CO2 adsorption ability. At the CO2 adsorption step, a larger number of hydroxyl groups over the Cu–Ce–Zr catalyst with 8 wt% Ce loading leads to the production of H-containing adsorption species. At the CO2 hydrogenation step, a larger number of hydroxyl groups assists in encouraging the further hydrogenation of intermediate species to CH3OH and improving the hydrogenation rate. Hence, the Cu–Ce–Zr catalyst with 8 wt% Ce loading favors CH3OH selectivity and CO2 activation, while CO is preferred on the Cu–Ce–Zr catalyst with 2 wt% Ce loading, a smaller number of hydroxyl groups and a solid solution nature. Additionally, high-pressure in situ diffuse reflectance infrared Fourier transform spectroscopy shows that CO is produced from formate decomposition and that both monodentate formate and bidentate formate are active intermediate species of CO2 hydrogenation to CH3OH.

关键词： CO2 hydrogenation     Cu–Ce–Zr     hydroxyls     CO/CH3OH selectivity    

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Antioxidative potential of metformin: Possible protective mechanism against generating OH radicals

Huibin Guo, Ning Wang, Xiang Li

《环境科学与工程前沿（英文）》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1313-2

摘要： Abstract • Metformin consumes O2−• and OH• induced by PM are proposed. • OH• dominated the oxidation of metformin compared with O2−• • Metformin can prevent the harm of ROS induced by PM to human health. • Antioxidative potential of metformin was first proposed to provide measures. Exposure to particulate matter (PM) can lead to the excessive accumulation of reactive oxygen species (ROS), which causes oxidative stress and endangers human health. In this study, the effects of metformin on PM-induced radicals were investigated, and the antioxidation reaction mechanism of metformin was analyzed by the density functional theory (DFT) method. The corresponding results revealed that the consumption rate of dithiothreitol (DTT) increased as the metformin concentration (0–40 mmol/L) increased under exposure to PM active components. Moreover, the OH radical content decreased as the metformin concentration increased. This result may be related to the consumption of PM-induced OH radicals by metformin, which promotes the DTT consumption rate. Additionally, because the initiation reaction has a high barrier, the oxidation reaction rate between metformin and •O2− is not very fast, although various catalysts may be present in the human environment. Importantly, we found that the barrier of metformin induced by OH radicals is only 9.6 kcal/mol while the barrier of metformin induced by oxygen is 57.9 kcal/mol, which shows that the rate of the •OH-initiated oxidative reaction of metformin is much faster and that this reaction path occurs more easily. By sample analysis, the mean OH radical generation was 55 nmol/min/g (ranging from 5 to 105 nmol/min/g) on haze days and 30 nmol/min/g (ranging from 10 to 50 nmol/min/g) on non-haze days. Moreover, OH radical generation was higher on haze days than on neighboring non-haze days. Taken together, all data suggest that metformin could consume the PM-induced radicals, such as OH radicals and •O2−, thereby providing health protection.

关键词： Antioxidative potential     Metformin     Mechanism     OH radical     Health protection.    

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Recent advances in special morphologic photocatalysts for NO removal

《环境科学与工程前沿（英文）》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1573-0

摘要：

● Systematic information of recent progress in photocatalytic NO x removal is provided.

关键词： NOx removal     Photocatalyst     Graphene     C3N4     Bi-based compounds.    

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One-pot hydrothermal fabrication of BiVO/FeO/rGO composite photocatalyst for the simulated solar light-driven

《环境科学与工程前沿（英文）》 2022年 第16卷 第3期 doi: 10.1007/s11783-021-1470-y

摘要：

• BiVO4/Fe3O4/rGO has excellent photocatalytic activity under solar light radiation.

关键词： Photocatalysis     Ternary magnetic photocatalyst     Visible-light-driven     Free radicals trapping     Reusability     Recycling    

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Multi-effect anthraquinone-based polyimide enclosed SnO/reduced graphene oxide composite as high-performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1231-1243 doi: 10.1007/s11705-023-2306-z

摘要： The cycling stability of SnO2 anode as lithium-ion battery is poor due to volume expansion. Polyimide coatings can effectively confine the expansion of SnO2. However, linear polyimides are easily dissolved in ester electrolytes and their carbonyls is not fully utilized during charging/discharging process. Herein, the SnO2 enclosed with anthraquinone-based polyimide/reduced graphene oxide composite was prepared by self-assembly. Carbonyls from the anthraquinone unit provide fully available active sites to react with Li+, improving the utilization of carbonyl in the polyimide. More exposed carbonyl active sites promote the conversion of Sn to SnO2 with electrode gradual activation, leading to an increase in reversible capacity during the charge/discharge cycle. In addition, the introduction of reduced graphene oxide cannot only improve the stability of polyimide in the electrolyte, but also build fast ion and electron transport channels for composite electrodes. Due to the multiple effects of anthraquinone-based polyimide and the synergistic effect of reducing graphene oxide, the composite anode exhibits a maximum reversible capacity of 1266 mAh·g−1 at 0.25 A·g−1, and maintains an excellent specific capacity of 983 mAh·g−1 after 200 cycles. This work provides a new strategy for the synergistic modification of SnO2.

关键词： anthraquinone-based polyimide     multi-effect     tin dioxide     reduced graphene oxide     lithium-ion battery    

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ADT-OH improves intestinal barrier function and remodels the gut microbiota in DSS-induced colitis

《医学前沿（英文）》 2023年 第17卷 第5期   页码 972-992 doi: 10.1007/s11684-023-0990-1

摘要： Owing to the increasing incidence and prevalence of inflammatory bowel disease (IBD) worldwide, effective and safe treatments for IBD are urgently needed. Hydrogen sulfide (H2S) is an endogenous gasotransmitter and plays an important role in inflammation. To date, H2S-releasing agents are viewed as potential anti-inflammatory drugs. The slow-releasing H2S donor 5-(4-hydroxyphenyl)-3H-1,2-dithiole-3-thione (ADT-OH), known as a potent therapeutic with chemopreventive and cytoprotective properties, has received attention recently. Here, we reported its anti-inflammatory effects on dextran sodium sulfate (DSS)-induced acute (7 days) and chronic (30 days) colitis. We found that ADT-OH effectively reduced the DSS-colitis clinical score and reversed the inflammation-induced shortening of colon length. Moreover, ADT-OH reduced intestinal inflammation by suppressing the nuclear factor kappa-B pathway. In vivo and in vitro results showed that ADT-OH decreased intestinal permeability by increasing the expression of zonula occludens-1 and occludin and blocking increases in myosin II regulatory light chain phosphorylation and epithelial myosin light chain kinase protein expression levels. In addition, ADT-OH restored intestinal microbiota dysbiosis characterized by the significantly increased abundance of Muribaculaceae and Alistipes and markedly decreased abundance of Helicobacter, Mucispirillum, Parasutterella, and Desulfovibrio. Transplanting ADT-OH-modulated microbiota can alleviate DSS-induced colitis and negatively regulate the expression of local and systemic proinflammatory cytokines. Collectively, ADT-OH is safe without any short-term (5 days) or long-term (30 days) toxicological adverse effects and can be used as an alternative therapeutic agent for IBD treatment.

关键词： inflammatory bowel disease     ADT-OH     intestinal permeability     gut microbiota    

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Efficient photoelectrochemical oxidation of rhodamine B on metal electrodes without photocatalyst or

Xuejiao Wang, Xiang Feng, Jing Shang

《环境科学与工程前沿（英文）》 2018年 第12卷 第6期 doi: 10.1007/s11783-018-1061-8

摘要：

•The efficient PEC degradation of RhB is realized using no photocatalyst.

•The efficient PEC degradation of RhB features the low salinity.

•The PEC degradation of RhB takes place on the anode and cathode simultaneously.

关键词： Energy relay structure     Energy saving     Photocatalyst-free and low-salinity degradation     Photoelectrochemical cell    

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Identification of differentially expressed miRNAs associated with chronic kidney disease–mineral bone disorder

null

《医学前沿（英文）》 2017年 第11卷 第3期   页码 378-385 doi: 10.1007/s11684-017-0541-8

摘要：

The purpose of this study is to characterize a meta-signature of differentially expressed mRNA in chronic kidney disease (CKD) to predict putative microRNA (miRNA) in CKD–mineral bone disorder (CKD–MBD) and confirm the changes in these genes and miRNA expression under uremic conditions by using a cell culture system. PubMed searches using MeSH terms and keywords related to CKD, uremia, and mRNA arrays were conducted. Through a computational analysis, a meta-signature that characterizes the significant intersection of differentially expressed mRNA and expected miRNAs associated with CKD–MBD was determined. Additionally, changes in gene and miRNA expressions under uremic conditions were confirmed with human Saos-2 osteoblast-like cells. A statistically significant mRNA meta-signature of upregulated and downregulated mRNA levels was identified. Furthermore, miRNA expression profiles were inferred, and computational analyses were performed with the imputed microRNA regulation based on weighted ranked expression and putative microRNA targets (IMRE) method to identify miRNAs associated with CKD occurrence. TLR4 and miR-146b levels were significantly associated with CKD–MBD. TLR4 levels were significantly downregulated, whereas pri-miR-146b and miR-146b were upregulated in the presence of uremic toxins in human Saos-2 osteoblast-like cells. Differentially expressed miRNAs associated with CKD-MBD were identified through a computational analysis, and changes in gene and miRNA expressions were confirmed with an in vitro cell culture system.

关键词： chronic kidney disease     microRNA     mineral bone disorder     uremia    

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Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH)

Giovanni Cagnetta, Kunlun Zhang, Qiwu Zhang, Jun Huang, Gang Yu

《环境科学与工程前沿（英文）》 2019年 第13卷 第1期 doi: 10.1007/s11783-019-1096-5

摘要：

PE ball milling pretreatment induces higher H2 production and purity by gasification.

Ca(OH)2 reacts at solid state with PE boosting H2 and capturing CO2.

Ca(OH)2 significantly reduces methanation side-reaction.

关键词： Hydrogen production     Gasification     Plastic waste     High energy ball milling    

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Efficient flower-like ZnSe/CuZnS photocatalyst for hydrogen production application

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1301-1310 doi: 10.1007/s11705-022-2295-3

摘要： Photocatalytic hydrogen production utilizing abundant solar energy to produce high-calorie, clean, and pollution-free hydrogen is an important approach to solving environmental and resource problems. In this work, a high-efficiency flower-like ZnSe/Cu0.08Zn0.92S photocatalyst was constructed through element doping and the formation of a Z-scheme heterojunction. The synergistic effect of Cu doping and the built-in electric field in the heterojunction enhanced light absorption and utilization by the ZnSe/Cu0.08Zn0.92S microflowers, accelerated the separation and transfer of photogenerated electrons and effectively inhibited electron–hole recombination. Thus the photocatalytic hydrogen production ability of the ZnSe/Cu0.08Zn0.92S microflowers was increased significantly. The highly stable ZnSe/Cu0.08Zn0.92S microflowers could provide excellent catalysis of photocatalytic hydrogen production.

关键词： photocatalysis     Cu0.08Zn0.92S     ZnSe     hydrogen production    

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标题 作者 时间 类型 操作

Generation of enhanced stability of SnO/In(OH)/InP for photocatalytic water splitting by SnO protection

期刊论文

Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH

Hong SUN,Min SUN,Yaobin ZHANG,Xie QUAN

期刊论文

Complete oxidation of methane on CoO-SnO catalysts

Xingfu TANG , Jiming HAO , Junhua LI ,

期刊论文

Formation of CaCO hollow microspheres in carbonated distiller waste from Solvay soda ash plants

期刊论文

A mini-review of ferrites-based photocatalyst on application of hydrogen production

期刊论文

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

期刊论文

Antioxidative potential of metformin: Possible protective mechanism against generating OH radicals

Huibin Guo, Ning Wang, Xiang Li

期刊论文

Recent advances in special morphologic photocatalysts for NO removal

期刊论文

One-pot hydrothermal fabrication of BiVO/FeO/rGO composite photocatalyst for the simulated solar light-driven

期刊论文

Multi-effect anthraquinone-based polyimide enclosed SnO/reduced graphene oxide composite as high-performance

期刊论文

ADT-OH improves intestinal barrier function and remodels the gut microbiota in DSS-induced colitis

期刊论文

Efficient photoelectrochemical oxidation of rhodamine B on metal electrodes without photocatalyst or

Xuejiao Wang, Xiang Feng, Jing Shang

期刊论文

Identification of differentially expressed miRNAs associated with chronic kidney disease–mineral bone disorder

null

期刊论文

Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH)

Giovanni Cagnetta, Kunlun Zhang, Qiwu Zhang, Jun Huang, Gang Yu

期刊论文

Efficient flower-like ZnSe/CuZnS photocatalyst for hydrogen production application

期刊论文