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Preparation and gaseous photocatalytic activity of smooth potassium dititanate film

QIAN Qinghua, HU Yuyan, WEN Gaofei, FENG Xin, LU Xiao-hua

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 308-314 doi: 10.1007/s11705-008-0047-7

摘要： A new smooth potassium dititanate film was prepared by sol-gel method and characterized by thermogravimetry (TG) and differential scanning calorimetry (DSC), X-ray diffraction (XRD), atomic force microscopy (AFM), UV-Visible diffuse reflectance and Raman spectroscopy. The gaseous photocatalytic activity of smooth KTiO films was studied using contact angle analysis from the photocatalytic decomposition of octadecyltrichlorosilane (OTS) based self-assembled monolayers (SAMs) formed on KTiO films. The photocurrent response of the film was determined by an electrochemical method. It was shown that the films were smooth, compact, and transparent when formed on glass. Compared with TiO film, the KTiO film showed wide absorption in the ultraviolet and visible region. It was found that the monolayers on KTiO decomposed much faster than those on TiO under UV irradiation of 254 nm in air. The film also exhibited a stronger photoresponse and a more stable anodic photocurrent. The KTiO film efficiently decomposes the alkylsiloxane monolayers under UV irradiation in air and it was found to be a good photocatalyst for gaseous organic pollutant treatment.

关键词： reflectance     UV-Visible     photocurrent     irradiation     scanning calorimetry    

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Removal of virus aerosols by the combination of filtration and UV-C irradiation

《环境科学与工程前沿（英文）》 2023年 第17卷 第3期 doi: 10.1007/s11783-023-1627-y

摘要：

● The removal of virus aerosols by filtration and UV-C irradiation was proposed.

关键词： Filtration system     UV-C irradiation     Virus aerosol     Public health     COVID-19    

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and bacteriophage MS2 disinfection by UV, ozone and the combined UV and ozone processes

Jingyun FANG,Huiling LIU,Chii SHANG,Minzhen ZENG,Mengling NI,Wei LIU

《环境科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 547-552 doi: 10.1007/s11783-013-0620-2

摘要： The combination of low-dose ozone with ultraviolet (UV) irradiation should be an option to give benefit to disinfection and reduce drawbacks of UV and ozone disinfection. However, less is known about the disinfection performance of UV and ozone (UV/ozone) coexposure and sequential UV-followed-by-ozone (UV-ozone) and ozone-followed-by-UV (ozone-UV) exposures. In this study, inactivation of and bacteriophage MS2 by UV, ozone, UV/ozone coexposure, and sequential UV-ozone and ozone-UV exposures was investigated and compared. Synergistic effects of 0.5–0.9 log kill on inactivation, including increases in the rate and efficiency, were observed after the UV/ozone coexposure at ozone concentrations as low as 0.05 mg·L in ultrapure water. The coexposure with 0.02-mg·L ozone did not enhance the inactivation but repressed photoreactivation. Little enhancement on inactivation was found after the sequential UV-ozone or ozone-UV exposures. The synergistic effect on MS2 inactivation was less significant after the UV/ozone coexposure, and more significant after the sequential ozone-UV and UV-ozone exposures, which was 0.2 log kill for the former and 0.8 log kill for the latter two processes, at ozone dose of 0.1 mg·L and UV dose of 8.55 mJ·cm in ultrapure water. The synergistic effects on disinfection were also observed in tap water. These results show that the combination of UV and low-dose ozone is a promising technology for securing microbiological quality of water.

关键词： bacteria inactivation     photoreactivation     water disinfection     UV     ozone    

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Enhanced formation of trihalomethane disinfection byproducts from halobenzoquinones under combined UV

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1510-7

摘要：

• 2,6-DCBQ and TCBQ generated THMs differently in chlorine and UV/chlorine processes.

关键词： Halobenzoquinone     Trihalomethane     Chlorine disinfection     UV irradiation     Disinfection byproducts     Combined UV/chlorine    

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All-inorganic TiO/CsAgBiBr composite as highly efficient photocatalyst under visible light irradiation

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1925-1936 doi: 10.1007/s11705-023-2344-6

摘要： In recent years, limited photocatalysis efficiency and wide band gap have hindered the application of TiO2 in the field of photocatalysis. A leading star in photocatalysis has been revealed as lead-free Cs2AgBiBr6 double halide perovskite nanocrystals, owing to its strong visible light absorption and tunable band gap. In this work, this photocatalytic process was facilitated by a unique TiO2/Cs2AgBiBr6 composite, which was identified as an S-cheme heterojunction. TiO2/Cs2AgBiBr6 composite was investigated for its structure and photocatalytic behavior. The results showed that when the perovskite dosage is 40%, the photocatalytic rate of TiO2 could be boosted to 0.1369 min–1. This paper discusses and proposes the band gap matching, carrier separation, and photocatalytic mechanism of TiO2/Cs2AgBiBr6 composites, which will facilitate the generation of new ideas for improving TiO2’s photocatalytic performance.

关键词： Cs2AgBiBr6 nanocrystals     visible-light photocatalyst     Cs2AgBiBr6/TiO2 heterojunction    

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Decomposition of aqueous chlorinated contaminants by UV irradiation with H

Eunsung KAN,Chang-Il KOH,Kyunghyuk LEE,Joonwun KANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第3期   页码 429-435 doi: 10.1007/s11783-014-0677-6

摘要： In the present study, the decomposition rates of carbon tetrachloride (CCl ) and 2,4-dichlorophenol (2,4-DCP) in water by the ultraviolet (UV) light irradiation alone and H O /UV were experimentally investigated. The detailed experimental studies have been conducted for examining treatment capacities of the two different ultraviolet light sources (low and medium pressure Hg arc) in H O /UV processes. The low or medium UV lamp alone resulted in a 60%–90% decomposition of 2,4-DCP while a slight addition of H O resulted in a drastic enhancement of the 2,4-DCP decomposition rate. The decomposition rate of 2,4-DCP with the medium pressure UV lamp alone was about 3–6 times greater than the low pressure UV lamp alone. In the direct photolysis of aqueous CCl , the medium pressure UV lamp had advantage over the low pressure UV lamp because the molar extinction coefficient of CCl at shorter wavelength (210–220 nm) is about 20 to 50 times higher than that at 254 nm. However, adding H O to the medium pressure UV lamp system rendered a negative oxidation rate because H O acted as a UV absorber being competitive with CCl due to negligible reaction between CCl and OH radicals. The results from the present study indicated significant influence of the photochemical properties of the target contaminants on the photochemical treatment characteristics for designing cost-effective UV-based degradation of toxic contaminants.

关键词： H2O2/ultraviolet (UV) light     advanced oxidation     UV light irradiation     chlorinated contaminants     photochemical treatment characteristics    

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Online recognition of drainage type based on UV-vis spectra and derivative neural network algorithm

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1430-6

摘要：

• UV-vis absorption analyzer was applied in drainage type online recognition.

关键词： Drainage online recognition     UV-vis spectra     Derivative spectrum     Convolutional neural network    

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Novel Ag-AgBr decorated composite membrane for dye rejection and photodegradation under visible light

Yixing Wang, Liheng Dai, Kai Qu, Lu Qin, Linzhou Zhuang, Hu Yang, Zhi Xu

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 892-901 doi: 10.1007/s11705-020-2011-0

摘要： Photocatalytic membranes have received increasing attention due to their excellent separation and photodegradation of organic contaminants in wastewater. Herein, we bound Ag-AgBr nanoparticles onto a synthesized polyacrylonitrile-ethanolamine (PAN-ETA) membrane with the aid of a chitosan (CS)-TiO layer via vacuum filtration and partial reduction. The introduction of the CS-TiO layer improved surface hydrophilicity and provided attachment sites for the Ag-AgBr nanoparticles. The PAN-ETA/CS-TiO /Ag-AgBr photocatalytic membranes showed a relatively high water permeation flux (~ 47 L·m ·h ·bar ) and dyes rejection (methyl orange: 88.22%; congo red: 95%; methyl blue: 97.41%; rose bengal: 99.98%). Additionally, the composite membranes exhibited potential long-term stability for dye/salt separation (dye rejection: ~97%; salt rejection: ~6.5%). Moreover, the methylene blue and rhodamine B solutions (20 mL, 10 mg·L ) were degraded approximately 90.75% and 96.81% in batch mode via the synthesized photocatalytic membranes under visible light irradiation for 30 min. This study provides a feasible method for the combination of polymeric membranes and inorganic catalytic materials.

关键词： Ag-AgBr     dye rejection     photodegradation     visible light    

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Low temperature synthesis of visible light responsive rutile TiO

John TELLAM, Xu ZONG, Lianzhou WANG

《化学科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 53-57 doi: 10.1007/s11705-011-1165-1

摘要： A nano-structured TiO with rutile phase was synthesized by using the hydrothermal method from a titanium carbide (TiC) nano-powder precursor at low temperature to produce a stable visible light responsive photocatalyst. The rutile phase was formed at temperature as low as 100°C, and both synthesis time and temperature affected its formation. The rutile particles showed a faceted nano-rod structure, and were tested for absorption and photo-degradation ability under visible light. Particles with shorter synthesis times showed higher visible light absorption and corresponding photo-degradation ability, while those synthesized at lower temperatures had lower, but still evident, degradation ability under visible light.

关键词： photocatalysis     rutile     TiO2     hydrothermal     visible     titanium carbide    

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Photolysis and photooxidation of typical gaseous VOCs by UV Irradiation: Removal performance and mechanisms

In-Sun Kang, Jinying Xi, Hong-Ying Hu

《环境科学与工程前沿（英文）》 2018年 第12卷 第3期 doi: 10.1007/s11783-018-1032-0

摘要： Photodegradation by ultraviolet irradiation (UV) is increasingly applied in volatile organic compound (VOC) and odor gas treatments. In this study, 27 typical VOCs, including 11 hydrocarbons and 16 hydrocarbon derivatives, at 150–200 ppm in air and nitrogen gas were treated by a laboratory-scale UV reactor with 185/254 nm irradiation to systematically investigate their removal and conversion by UV irradiation. For the tested 27 VOCs, the VOC removal efficiencies in air were within the range of 13%–97% (with an average of 80%) at a retention time of 53 s, which showed a moderate positive correlation with the molecular weight of the VOCs ( = 0.53). The respective contributions of photolysis and photooxidation to VOC removal were identified for each VOC. According to the CO results, the mineralization rate of the tested VOCs was within the range of 9%–90%, with an average of 41% and were negatively correlated to the molecular weight ( = 0.63). Many of the tested VOCs exhibited high concentration particulate matters in the off-gases with a 3–283 mg/m PM range and a 2–40 mg/m PM range. The carbon balance of each VOC during UV irradiation was analyzed based on the VOC, CO and PM concentrations. Certain organic intermediates and 23–218 ppm ozone were also identified in the off-gases. Although the UV technique exhibited a high VOC removal efficiency, its drawbacks, specifically low mineralization, particulate matters production, and ozone emission, must be considered prior to its application in VOC gas treatments.

关键词： VOCs     UV photodegradation     Particulate matters     Ozone    

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Tuning nitrogen defects and doping sulfur in carbon nitride for enhanced visible light photocatalytic

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 93-101 doi: 10.1007/s11705-022-2175-x

摘要： Defect construction and heteroatom doping are effective strategies for improving photocatalytic activity of carbon nitride (g-C3N4). In this work, N defects were successfully prepared via cold plasma. High-energy electrons generated by plasma can produce N defects and embed sulfur atoms into g-C3N4. The N defects obviously promoted photocatalytic degradation performance that was 7.5 times higher than that of pure g-C3N4. The concentration of N defects can be tuned by different power and time of plasma. With the increase in N defects, the photocatalytic activity showed a volcanic trend. The g-C3N4 with moderate concentration of N defects exhibited the highest photocatalytic activity. S-doped g-C3N4 exhibited 11.25 times higher photocatalytic activity than pure g-C3N4. It provided extra active sites for photocatalytic reaction and improved stability of N defects. The N vacancy-enriched and S-doped g-C3N4 are beneficial for widening absorption edge and improving the separation efficiency of electron and holes.

关键词： g-C3N4     nitrogen defect     sulfur doping     photodegradation     plasma    

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Visible-light-driven heterostructured g-CN/Bi-TiO floating photocatalyst with enhanced charge carrier

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1417-3

摘要：

• Bi doping in TiO2 enhanced the separation of photo-generated electron-hole.

关键词： Bi doping     Visible light     Algal removal     Charge carrier separation    

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recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation of dyes under visible

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1765-1775 doi: 10.1007/s11705-023-2323-y

摘要： A stable and recyclable of BiOBr/silk fibroin-cellulose acetate composite film was prepared by blending-wet phase transformation and in situ precipitate technology. The cellulose acetate film modified by silk fibroin formed a finger-shaped porous structure, which provided a large space for the uniform growth of BiOBr nanosheets and facilitated the shuttle flow of dyes in film. The morphology, phase structure, and optical properties of the composite films were characterized using various techniques, and their photocatalytic performance for dye wastewater was evaluated under visible light irradiation. Results showed that the BiOBr/SF-CA composite film exhibited efficient photocatalytic activity with 99.9% of rhodamine B degradation rate. Moreover, the composite film maintained high catalytic stability because Bi as the active species deposited on the film showed almost no loss. Finally, the possible photocatalytic mechanisms in the BiOBr/SF-CA composite film were speculated through radical-trapping experiments and electron spin resonance testing.

关键词： BiOBr nanosheet     cellulose acetate     silk fibroin     photocatalytic degradation     dye wastewater    

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Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 440-449 doi: 10.1007/s11705-018-1700-4

摘要：

In recent years, much effort has been focused on the development of the photocatalysts with high performance under visible light irradiation. In this paper, three-dimensional porous La-doped SrTiO3 (LST) microspheres were prepared by a modified sol–gel method, in which the agarose gel/SrCO3 microsphere and La2O3 were employed as the template and the La resource, respectively. The as-prepared LST microspheres exhibit a porous structure with a diameter of about 10 µm and a surface pore size of about 100 nm. The La element was doped into the crystal lattice of SrTiO3 by the substitution of La3+ for Sr2+. Therefore, the absorption edge of LST samples shifts toward the visible light region, and their photocatalytic activity for the Cr(VI) reduction is enhanced under visible light. Among all LST samples, LST-0.5 (the La3+ doping content is 0.5 wt-%) exhibited the highest visible-light photocatalytic activity, which can reduce 84% Cr(VI) within 100 min. This LST materials may become a promising photocatalyst for the facile treatment of wastewater containing poisonous heavy metal ions.

关键词： SrTiO3     La3+ doping     porous microsphere     visible-light photocatalysis     Cr(VI) reduction    

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Effects of water quality on the coagulation performances of humic acids irradiated with UV light

Wendong WANG,Qinghai FAN,Zixia QIAO,Qin YANG,Yabo WANG,Xiaochang WANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 147-154 doi: 10.1007/s11783-014-0749-7

摘要： The presence of humic acid in drinking water treatment has received significant attention in recent years because of its adverse effects on the removal of many pollutants in coagulation. In this paper, the effects of water quality including pH, turbidity, alkalinity, and hardness on the removal of humic acid were investigated in a UV light hybridized coagulation process. Our results suggested that UV light radiation could effectively improve the removal rate of humic acid in coagulation under both neutral and basic conditions, and the variations of the selected water quality parameters had little adverse effect on the function of UV light. After UV light radiation, the removal rate of the nitro-humic acid (NHA) increased from 20% to 60% in coagulation, and increased further to 75% and 85% for the raw waters with 10.0 NTU kaolin and 100 mg·L hardness, respectively. In addition to NHA, the removal rates of the humic acid extracted from peat coal (PHA) and the humic acid provided by Japan metals and chemicals company (JHA) in coagulation were also improved, both in the range of 80%–90% after undergoing UV light radiation. By changing the radiation location from prior to coagulation to the flocculation process, similar experimental results were obtained. The formation of positive charged sites after UV light radiation was considered to be the primary factor that led to an enhanced removal of the humic acid in coagulation.

关键词： coagulation     drinking water     humic acid     UV light radiation     water quality    

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标题 作者 时间 类型 操作

Preparation and gaseous photocatalytic activity of smooth potassium dititanate film

QIAN Qinghua, HU Yuyan, WEN Gaofei, FENG Xin, LU Xiao-hua

期刊论文

Removal of virus aerosols by the combination of filtration and UV-C irradiation

期刊论文

and bacteriophage MS2 disinfection by UV, ozone and the combined UV and ozone processes

Jingyun FANG,Huiling LIU,Chii SHANG,Minzhen ZENG,Mengling NI,Wei LIU

期刊论文

Enhanced formation of trihalomethane disinfection byproducts from halobenzoquinones under combined UV

期刊论文

All-inorganic TiO/CsAgBiBr composite as highly efficient photocatalyst under visible light irradiation

期刊论文

Decomposition of aqueous chlorinated contaminants by UV irradiation with H

Eunsung KAN,Chang-Il KOH,Kyunghyuk LEE,Joonwun KANG

期刊论文

Online recognition of drainage type based on UV-vis spectra and derivative neural network algorithm

期刊论文

Novel Ag-AgBr decorated composite membrane for dye rejection and photodegradation under visible light

Yixing Wang, Liheng Dai, Kai Qu, Lu Qin, Linzhou Zhuang, Hu Yang, Zhi Xu

期刊论文

Low temperature synthesis of visible light responsive rutile TiO

John TELLAM, Xu ZONG, Lianzhou WANG

期刊论文

Photolysis and photooxidation of typical gaseous VOCs by UV Irradiation: Removal performance and mechanisms

In-Sun Kang, Jinying Xi, Hong-Ying Hu

期刊论文

Tuning nitrogen defects and doping sulfur in carbon nitride for enhanced visible light photocatalytic

期刊论文

Visible-light-driven heterostructured g-CN/Bi-TiO floating photocatalyst with enhanced charge carrier

期刊论文

recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation of dyes under visible

期刊论文

Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

期刊论文

Effects of water quality on the coagulation performances of humic acids irradiated with UV light

Wendong WANG,Qinghai FAN,Zixia QIAO,Qin YANG,Yabo WANG,Xiaochang WANG

期刊论文