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Brazing of ceramic-to-ceramic and ceramic-to-metal joints in air

Kirsten BOBZIN, Thomas SCHLAEFER, Lidong ZHAO, Nils KOPP, Arne SCHLEGEL

《机械工程前沿(英文)》 2010年 第5卷 第2期   页码 125-129 doi: 10.1007/s11465-010-0007-z

摘要: Reactive air brazing (RAB) is an emerging technology for the production of ceramic-to-ceramic and ceramic-to-metal joints. In this study, RAB was investigated with respect to the potential applications for solid oxide fuel cells (SOFCs) as one example of use. It was found that alumina could be well brazed by RAB with AgCu and AgCuTi brazes. Both braze composition and brazing temperature influenced significantly the wetting behavior and their mechanism of wetting. AgCu and AgCuTi braze alloys could also be used to produce brazed joints with the SOFC materials ceramic yttria stabilized zirconia and steel X1CrTiLa22. However, CuO reacts with the steel, forming a brittle oxide layer on the steel surface, which is undesirable for SOFC applications. The first trials with Ag0.5Al showed a promising solution.

关键词: reactive air brazing (RAB)     X1CrTiLa22     Al2O3     yttria stabilized zirconia (YSZ)     solid oxide fuel cell (SOFC)    

用高光谱发光法研究Cu(Inx,Ga1x)Se2 (CIGS)模块中由P1引起的功率损耗的成因 Article

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

《工程(英文)》 2020年 第6卷 第12期   页码 1395-1402 doi: 10.1016/j.eng.2019.12.019

摘要:

在本文中,我们利用了高光谱高分辨率光致发光映射技术,这是一个强大的工具,可用于选择和优化在Cu(Inx,Ga1-x)Se2(CIGS)模块上对子电池进行图案化互连的激光烧蚀工艺。具体而言,通过分析在CIGS沉积之前烧蚀的标准P1图案线,我们发现了沿着下部的钼槽边缘的异常发射猝灭效应。通过扫描电子显微镜(SEM)比较了P1边缘的横截面的形貌,我们进一步合理化产生这种效应的起因,但无法用厚度变化解释光发射的减少。我们还研究了激光诱导对CIGS沉积后的P1图案线带来的损伤。我们的发现能更好地理解P1引起的功率损耗,并为改进与行业相关的模块互连方案提供了新的见解。

关键词: Cu(Inx     Ga1x)Se2     电池到模块的效率差距     由P1引起的功率损耗     高光谱光致发光     激光烧蚀短程热效应    

磁控溅射法生长的带隙可调谐(GaxIn1x)2O3 Research Articles

张法碧1,孙巾寓1,李海鸥1,周娟1,王荣1,孙堂友1,傅涛1,肖功利1,李琦1,刘兴鹏1,张秀云1,郭道友2,王相虎3,秦祖军1

《信息与电子工程前沿(英文)》 2021年 第22卷 第10期   页码 1370-1378 doi: 10.1631/FITEE.2000330

摘要: 采用磁控溅射技术和热退火技术在(0001)蓝宝石衬底上制备了多组分氧化物(GaxIn1x)2O3薄膜,实现可调带隙。详细研究了三元化合物(GaxIn1x)2O3在整个组成范围内的光学性质和能带结构演化。X射线衍射谱表明,Ga含量在0.11至0.55之间的(GaxIn1x)2O3薄膜既有立方结构,也有单斜结构,而Ga含量高于0.74的(GaxIn1x)2O3薄膜只有单斜结构。实验结果为透明导电化合物半导体(GaxIn1x)2O3薄膜在光电和光伏行业的应用,特别是在显示器、发光二极管和太阳能电池的应用奠定了基础。

关键词: (GaxIn1x)2O3薄膜;带隙可调谐;磁控溅射    

吴飞:人工智能+X的思考与实践(2021年1月29日)

吴飞(高级职称)

2021年10月14日

关键词: 人工智能    

Lamellar thickness transition of melt-crystallized polybuten-1 tetragonal phase: configurational change

Motoi YAMASHITA

《化学科学与工程前沿(英文)》 2009年 第3卷 第1期   页码 26-32 doi: 10.1007/s11705-009-0002-2

摘要: Lamellar crystal thickness of isotactic polybutene-1 ( -PB1) have been investigated for crystallization in the melt over a wide range of crystallization temperature from 40°C to 90°C by small angle X-ray scattering experiments and density measurements. The crystal thickness demonstrates two linear dependences on inverse supercooling and a transition from one dependence to the other has been observed around = 65°C. Each of the two dependences obeys the nucleation theory in the high and low supercooling ranges, respectively. Chain folding free energy determined from the low supercooling range is larger than that determined from the high supercooling range. Possible mechanisms for the transition are discussed taking account of entropy of chain folding directions.

关键词: isotactic polybutene-1     tetragonal phase     crystal thickness     melt growth     chain folding     small angle X-ray scattering     nucleation theory     end surface free energy    

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

《化学科学与工程前沿(英文)》 2021年 第15卷 第6期   页码 1561-1571 doi: 10.1007/s11705-021-2089-z

摘要: It is of broad interest to develop emerging photocatalysts with excellent light-harvesting capacity and high charge carrier separation efficiency for visible light photocatalytic hydrogen evolution reaction. However, achieving satisfying hydrogen evolution efficiency under noble metal-free conditions remains challenging. In this study, we demonstrate the fabrication of three-dimensionally ordered macroporous SrTiO3 decorated with ZnxCd1−xS nanoparticles for hydrogen production under visible light irradiation (λ>420 nm). Synergetic enhancement of photocatalytic activity is achieved by the slow photon effect and improved separation efficiency of photogenerated charge carriers. The obtained composites could afford very high hydrogen production efficiencies up to 19.67 mmol·g−1·h−1, with an apparent quantum efficiency of 35.9% at 420 nm, which is 4.2 and 23.9 times higher than those of pure Zn0.5Cd0.5S (4.67 mmol·g−1·h−1) and CdS (0.82 mmol·g−1·h−1), respectively. In particular, under Pt-free conditions, an attractive hydrogen production rate (3.23 mmol·g−1·h−1) was achieved, providing a low-cost and high-efficiency strategy to produce hydrogen from water splitting. Moreover, the composites showed excellent stability, and no obvious loss in activity was observed after five cycling tests.

关键词: three-dimensionally ordered macroporous SrTiO3     ZnxCd1–xS     visible light     hydrogen production     promotion mechanism    

Self-sustained catalytic combustion of CO enhanced by micro fluidized bed: stability operation, fluidization state and CFD simulation

《环境科学与工程前沿(英文)》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1709-x

摘要:

● Catalytic combustion in fluidized bed realizes efficient heat and mass transfer.

关键词: Self-sustained catalytic combustion     Carbon monoxide     Cu1–xCexOy     Fluidized bed     Computational fluid dynamics    

Cloning of human XAF1 gene promoter and assay of its transcription activity in a variety of cell lines

Qiong CHEN, Qing YU, Yuhu SONG, Peiyuan Li, Ying CHANG, Zhijun WANG, Lifeng LIU, Wei WU, Jusheng LIN

《医学前沿(英文)》 2009年 第3卷 第2期   页码 148-152 doi: 10.1007/s11684-009-0032-7

摘要: To investigate the regulation of tumor suppressor XAF1 gene expression in digestive system cancers, we studied XAF1 gene promoter transcription activity and mRNA level in digestive system cancer cell lines (human hepatoma cell line HepG2, human colon cancer cell line LoVo, and human gastric cancer cell line AGS) and nontumor cell lines (human embryonic liver cell line L02 (L02 cells) and human embryonic kidney 293 cells [HEK293 cells]) as controls. 1395-bp-promoter fragment of XAF1 gene was amplified by polymerase chain reaction (PCR) and cloned into pGL3-basic vector and pEGFP-1 vector to assay its promoter transcription activity. The plasmids were transfected into a variety of cell lines by lipofectamine 2000. The promoter transcription activity was determined by dual-luciferase report assay, and enhanced green fluorescent protein (EGFP)-positive cells were detected by fluorescence microscope. The expression of XAF1 mRNA in HEK293 and L02 were significantly higher than that in any of the three digestive system cancer cell lines. The dual-luciferase reporter assay showed that the promoter transcription activity in digestive system tumor cell lines transfected with pGL3-XAF1p promoter was apparently lower than that of both HEK293 and L02 cells. Expression of green fluorescent protein (GFP) under the control of XAF1 promoter in the three digestive system cancer cell lines was lower than that of both HEK293 and L02 cells. The activities of pGL3-XAF1p in the three digestive system cancer cell lines after treatment with heat stress were significantly lower than those in the unstressed cells. The results suggested that remarkably down-regulated XAF1 mRNA expression in digestive system cancer cell lines may be due to loss of transcription activity of XAF1 promoter.

关键词: gene     X-linked inhibitor of apoptosis protein associated factor-1 (XAF1)     promoter     transcription regulation    

采用白光X射线源和模拟阵列能量色散阵列探测器的高通量粉末衍射技术 Article

汪晓平, 董伟伟, 张鹏, 唐浩琪, 张澜庭, 杨铁莹, 刘鹏, 汪洪, 项晓东

《工程(英文)》 2022年 第10卷 第3期   页码 81-88 doi: 10.1016/j.eng.2021.05.023

摘要: text-align: justify;">在上海同步辐射光源(SSRF)的弯铁光束线上,利用由空间扫描硅漂移探测器(SDD)模拟获得的能量色散阵列探测器,对CeO2样品进行高通量白光X射线粉末衍射校正后的衍射图谱表明,由能量色散X 射线衍射(EDXRD)获得的不同衍射峰之间的相对强度与来自角度分辨X射线衍射(ARXRD)的相对强度一致,说明EDXRD结果可用于分析未知样品的晶体结构。实验同时采集了X射线荧光(XRF)信号。来自所有像素的XRF计数可直接在能量坐标下叠加,而衍射信号则需在d 空间下叠加,从而大大改善了阵列探测器的峰值强度和信噪比(S/N)。与ARXRD相比,白光X射线衍射信号强度是单色光衍射信号强度的104倍左右。

关键词: 高通量实验     白光X射线衍射     能量色散阵列探测器     能量色散X射线衍射     角分辨X射线衍射    

生成锁P<G,X,X'>和它的中央加密系统

史开泉,陈泽雄

《中国工程科学》 2000年 第2卷 第2期   页码 41-46

摘要:

利用数据生成技术,提出生成锁P <G ,X, X´>x,x´>的概念和由P <G ,X, X´>这些系统是:生成锁P <G ,X, X´>x,x´>与单齿中央加密系统,生成锁P <G ,X, X´>研究指出:任意两个秘密通讯的双方A和B,它们各自选择无规则分布的正整数集合XA={x1x2,…,xn},XB={x1xx,x´>x,x´>x,x´>x,x´>

关键词: 生成锁     中央加密系统     多齿加密-解密算法     P    X     X'>存在定理     数位签章唯一性定理    

A mini review: Shape memory polymers for biomedical applications

Kaojin Wang, Satu Strandman, X. X. Zhu

《化学科学与工程前沿(英文)》 2017年 第11卷 第2期   页码 143-153 doi: 10.1007/s11705-017-1632-4

摘要: Shape memory polymers (SMPs) are smart materials that can change their shape in a pre-defined manner under a stimulus. The shape memory functionality has gained considerable interest for biomedical applications, which require materials that are biocompatible and sometimes biodegradable. There is a need for SMPs that are prepared from renewable sources to be used as substitutes for conventional SMPs. In this paper, advances in SMPs based on synthetic monomers and bio-compounds are discussed. Materials designed for biomedical applications are highlighted.

关键词: shape memory polymer     biodegradability     biocompatibility     biomedical application     bile acids    

A study on quality evaluation for bituminous mixture using X-ray CT

Satoshi TANIGUCHI, Keiichiro OGAWA, Jun OTANI, Itaru NISHIZAKI

《结构与土木工程前沿(英文)》 2013年 第7卷 第2期   页码 89-101 doi: 10.1007/s11709-013-0197-7

摘要: The objective of this paper is to propose a new quality evaluation method for asphalt concrete mixture using X-ray CT scanner. To achieve this aim, asphalt mixtures should be subjected to the X-ray CT scanning and its characteristics should be clarified. The approach employed in this study was as follows: 1) Coarse aggregate, fine aggregate, filler and bitumen were prepared; 2) dense-graded, coarse-graded and porous asphalt mixtures were made; 3) materials and mixtures were subjected to the X-ray CT scanning; 4) frequency of CT-value, threshold value, average slice CT-value, average segment CT-value were computed. In the material examination, CT-value of aggregate becomes smaller in the order of coarse aggregate, fine aggregate and filler and CT image of bitumen was nearly homogeneous. In the mixture examination, histograms of CT-value and four segmentation images made from CT images expressed the material and mixture characterization such as particle size and the difference in bitumen content and mixture type visibly and the bitumen content varies with the threshold values. In addition, the average segment CT-value without threshold value by dividing the fine aggregate from the coarse aggregate and average CT-value of the coarse aggregate, especially is highly correlated with average CT-value of the bitumen.

关键词: asphalt concrete mixture     aggregate     bitumen     bitumen content     quality evaluation     X-ray CT    

Adsorption of fluoride on clay minerals and their mechanisms using X-ray photoelectron spectroscopy

Junyi DU, Daishe WU, Huayun XIAO, Ping LI

《环境科学与工程前沿(英文)》 2011年 第5卷 第2期   页码 212-226 doi: 10.1007/s11783-010-0255-5

摘要: This research investigates the adsorption mechanisms of fluoride (F) on four clay minerals (kaolinite, montmorillonite, chlorite, and illite) under different F concentrations and reaction times by probing their fluoride superficial layer binding energies and element compositions using X-ray photoelectron spectroscopy (XPS). At high F concentrations ( = 5–1000 mg·L ), the amount of F adsorbed ( ), amount of hydroxide released by clay minerals, solution F concentration, and the pH increase with increasing . The increases are remarkable at >50 mg·L . The increases significantly by continuously modifying the pH level. At <5–100 mg·L , clay minerals adsorb H to protonate aluminum-bound surface-active hydroxyl sites in the superficial layers and induce F binding. As the increases, F , along with other cations, is adsorbed to form a quasi-cryolite structure. At >100 mg·L , new minerals precipitate and the product depends on the critical Al concentration. At [Al ]>10 mol·L , cryolite forms, while at [Al ]<10 mol·L , AlF is formed. At low (0.3–1.5 mg·L ), proton transfer occurs, and the F adsorption capabilities of the clay minerals increase with time.

关键词: clay mineral     fluoride (F)     adsorption mechanism     X-ray photoelectron spectroscopy (XPS)    

Purification of ice structuring protein complexes from winter wheat using Triton X-114 phase partitioning

Huaneng XU, Haiying CHEN, Weining HUANG,

《化学科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 383-385 doi: 10.1007/s11705-009-0249-7

摘要: Ice structuring proteins (ISPs) isolated from the cold-acclimated plants have a great potential in improving the quality of frozen foods. The purification of ISP complexes from winter wheat was achieved using an aqueous two-phase system of Triton X-114. The highly reactive phenols were removed, and the ISP complexes remained in the aqueous phase after phase separation. The ISP complexes treated by this procedure retained higher thermal hysteresis activity than those treated by ammonium sulfate method. The phase separation technique provides a simple and mild way for removing phenols from ISP complexes.

关键词: separation technique     thermal hysteresis     cold-acclimated     purification     X-114    

脉冲X射线模拟技术的发展

邱爱慈

《中国工程科学》 2000年 第2卷 第9期   页码 24-28

摘要:

文章简要介绍了利用强流脉冲电子束加速器模拟脉冲X射线的发展概况及国内脉冲X射线模拟源的发展现状,指出作为主要技术途径,高功率Z箍缩技术在实现超强脉冲X射线源和ICF驱动源上都有很重要的 发展应用前景

关键词: 脉冲X射线     高功率脉冲技术     脉冲电子束加速器     Z箍缩     ICF    

标题 作者 时间 类型 操作

Brazing of ceramic-to-ceramic and ceramic-to-metal joints in air

Kirsten BOBZIN, Thomas SCHLAEFER, Lidong ZHAO, Nils KOPP, Arne SCHLEGEL

期刊论文

用高光谱发光法研究Cu(Inx,Ga1x)Se2 (CIGS)模块中由P1引起的功率损耗的成因

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

期刊论文

磁控溅射法生长的带隙可调谐(GaxIn1x)2O3

张法碧1,孙巾寓1,李海鸥1,周娟1,王荣1,孙堂友1,傅涛1,肖功利1,李琦1,刘兴鹏1,张秀云1,郭道友2,王相虎3,秦祖军1

期刊论文

吴飞:人工智能+X的思考与实践(2021年1月29日)

吴飞(高级职称)

2021年10月14日

会议视频

Lamellar thickness transition of melt-crystallized polybuten-1 tetragonal phase: configurational change

Motoi YAMASHITA

期刊论文

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

期刊论文

Self-sustained catalytic combustion of CO enhanced by micro fluidized bed: stability operation, fluidization state and CFD simulation

期刊论文

Cloning of human XAF1 gene promoter and assay of its transcription activity in a variety of cell lines

Qiong CHEN, Qing YU, Yuhu SONG, Peiyuan Li, Ying CHANG, Zhijun WANG, Lifeng LIU, Wei WU, Jusheng LIN

期刊论文

采用白光X射线源和模拟阵列能量色散阵列探测器的高通量粉末衍射技术

汪晓平, 董伟伟, 张鹏, 唐浩琪, 张澜庭, 杨铁莹, 刘鹏, 汪洪, 项晓东

期刊论文

生成锁P<G,X,X'>和它的中央加密系统

史开泉,陈泽雄

期刊论文

A mini review: Shape memory polymers for biomedical applications

Kaojin Wang, Satu Strandman, X. X. Zhu

期刊论文

A study on quality evaluation for bituminous mixture using X-ray CT

Satoshi TANIGUCHI, Keiichiro OGAWA, Jun OTANI, Itaru NISHIZAKI

期刊论文

Adsorption of fluoride on clay minerals and their mechanisms using X-ray photoelectron spectroscopy

Junyi DU, Daishe WU, Huayun XIAO, Ping LI

期刊论文

Purification of ice structuring protein complexes from winter wheat using Triton X-114 phase partitioning

Huaneng XU, Haiying CHEN, Weining HUANG,

期刊论文

脉冲X射线模拟技术的发展

邱爱慈

期刊论文