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Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems
《环境科学与工程前沿(英文)》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1476-5
• MES was constructed for simultaneous ammonia removal and acetate production.
关键词: Biocathode Carbon dioxide Electrochemical oxidation Graphite anode Boron-doped diamond
《化学科学与工程前沿(英文)》 2023年 第17卷 第11期 页码 1765-1775 doi: 10.1007/s11705-023-2323-y
关键词: BiOBr nanosheet cellulose acetate silk fibroin photocatalytic degradation dye wastewater
Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects
Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl
《化学科学与工程前沿(英文)》 2018年 第12卷 第4期 页码 670-682 doi: 10.1007/s11705-018-1769-9
Methyl acetate is considered low toxicity volatile solvent produced either as a by-product during methanol carbonylation or via acetic acid esterification with methanol. In both cases, pure methyl acetate has to be isolated from the reaction mixture. Simulation of methyl acetate separation from its mixture with methanol by extraction distillation was carried out in ASPEN+ software. In total three case studies were assumed using two different extraction solvents and two solvent regeneration strategies. In case A, novel extraction solvent 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid, was considered. Raw material separation was achieved in an extraction distillation column while the solvent regeneration was accomplished in a second distillation column in this case. In case study B, the same extraction solvent was used; however, its regeneration was carried out in a single-effect evaporator. Dimethyl sulfoxide was the second extraction solvent selected. Its use in methyl acetate-methanol separation is presented in case study C. As high purity of dimethyl sulfoxide was required for the methyl acetate-methanol azeotrope breaking, its regeneration was carried out in the second distillation column only. To simulate the ternary methyl acetate–methanol–extraction solvent mixtures separation, vapor–liquid equilibrium was predicted based on the NRTL equation. Further, unknown properties of the considered ionic liquid and variation of these properties with temperature were predicted and introduced into the ASPEN+ components properties database. Based on these data, optimum operation parameters of the respective separation equipment were established. In all case studies, the same condition had to be fulfilled, namely minimum methyl acetate content in the distillate from the extraction distillation column of 99.5mol-%. Results of simulations using the respective optimum operation parameters were employed in the economic evaluation of the three separation unit designs studied. It was found that the least energy-demanding design corresponds to the case study B in terms of both capital as well as operation expenses.
关键词: methyl acetate 1-ethyl-3-methylimidazolium trifluoromethanesulfonate extraction distillation dimethyl sulfoxide economic evaluation
Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the
Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai
《化学科学与工程前沿(英文)》 2017年 第11卷 第2期 页码 185-196 doi: 10.1007/s11705-017-1631-5
关键词: cryptomelane-type manganese oxide octahedral molecular sieve oxygen mobility reducibility carbon monoxide oxidation volatile organic compound combustion
Ao Yang, Yang Su, Tao Shi, Jingzheng Ren, Weifeng Shen, Teng Zhou
《化学科学与工程前沿(英文)》 2022年 第16卷 第2期 页码 303-315 doi: 10.1007/s11705-021-2044-z
关键词: extractive distillation solvent selection conceptual design process optimization heat integration
The
Prayoga SURYADARMA, Yoshihiro OJIMA, Yuto FUKUDA, Naohiro AKAMATSU, Masahito TAYA
《化学科学与工程前沿(英文)》 2012年 第6卷 第2期 页码 152-157 doi: 10.1007/s11705-012-1287-0
关键词:
A comparison of the biological activities of ethyl acetate fractions from the stems and leaves of
Zhaolei WANG, Kai JIANG, Qinchao DING, Shujun LIU, Xiaobing DOU, Bin DING
《农业科学与工程前沿(英文)》 2020年 第7卷 第4期 页码 505-512 doi: 10.15302/J-FASE-2019271
Pursh (PCP) is a popular traditional medicinal plant in China, widely used for the treatment of a variety of liver diseases. Although it has been long recognized that the main active elements of PCP are contained in ethyl acetate fraction (EAF), little is known so far in terms of the relative effectiveness of EAF derived from the stems versus leaves of this plant. In the current study, we prepared EAF by reflux extraction and sequential extraction from the stems (SEAF) and leaves (LEAF) of PCP and tested their hepatoprotective efficacies. The extract rates and flavonoid contents of LEAF were higher than those of SEAF. EAFs (>50 μg·mL ) prevented lipid accumulation in cells and protected against lipotoxicity injury when the concentration exceeded 25 μg·mL . More than 95% free radicals released by 2,2-diphenyl-1-picrylhydrazyl (DPPH) were eliminated by 25 μg·mL SEAF and 50 μg·mL LEAF, respectively. Further, EAFs (25 μg·mL ) also showed protective antioxidant effects, with the activity of LEAF being significantly higher than that of SEAF. EAFs (10 mg·mL ) also showed similar unspecific bacteriostatic activity. In comparison with SEAF, LEAF contained more flavonoids and had a higher anti-oxidation capability and for these reasons we suggest it should be better for clinical use.
关键词: antibacterial anti-oxidation lipid accumulation lipotoxicity Penthorum chinense Pursh
Influence of accelerated curing on the compressive strength of polymer-modified concrete
Izhar AHMAD; Kashif Ali KHAN; Tahir AHMAD; Muhammad ALAM; Muhammad Tariq BASHIR
《结构与土木工程前沿(英文)》 2022年 第16卷 第5期 页码 589-599 doi: 10.1007/s11709-022-0789-1
关键词: compressive strength prediction polymer-modified concrete linear regression fit early age strength ethylene vinyl acetate
Benzenesulfonic acid-grafted UIO-66 with improved hydrophobicity as a stable Brønsted acid catalyst
《化学科学与工程前沿(英文)》 2023年 第17卷 第10期 页码 1389-1398 doi: 10.1007/s11705-022-2285-5
关键词: metal−organic frameworks (MOFs) UIO-66 hydrolysis of cyclohexyl acetate hydrophobicity Brønsted acidity
Halide-free carbonylation of methanol with H-MOR supported CuCeO
Chaoli Tong, Jiachang Zuo, Danlu Wen, Weikun Chen, Linmin Ye, Youzhu Yuan
《化学科学与工程前沿(英文)》 2021年 第15卷 第5期 页码 1075-1087 doi: 10.1007/s11705-020-2019-5
关键词: methanol carbonylation halide-free methyl acetate H-mordenite copper and cerium oxide
Mary Beth LEIGH,Wei-Min WU,Erick CARDENAS,Ondrej UHLIK,Sue CARROLL,Terry GENTRY,Terence L. MARSH,Jizhong ZHOU,Philip JARDINE,Craig S. CRIDDLE,James M. TIEDJE
《环境科学与工程前沿(英文)》 2015年 第9卷 第3期 页码 453-464 doi: 10.1007/s11783-014-0721-6
关键词: Stable isotope probing (SIP) ethanol acetate uranium reduction sediment bioremediation
标题 作者 时间 类型 操作
Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems
期刊论文
Durable and recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation
期刊论文
Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects
Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl
期刊论文
Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the
Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai
期刊论文
Energy-efficient recovery of tetrahydrofuran and ethyl acetate by triple-column extractive distillation
Ao Yang, Yang Su, Tao Shi, Jingzheng Ren, Weifeng Shen, Teng Zhou
期刊论文
The
Prayoga SURYADARMA, Yoshihiro OJIMA, Yuto FUKUDA, Naohiro AKAMATSU, Masahito TAYA
期刊论文
A comparison of the biological activities of ethyl acetate fractions from the stems and leaves of
Zhaolei WANG, Kai JIANG, Qinchao DING, Shujun LIU, Xiaobing DOU, Bin DING
期刊论文
Influence of accelerated curing on the compressive strength of polymer-modified concrete
Izhar AHMAD; Kashif Ali KHAN; Tahir AHMAD; Muhammad ALAM; Muhammad Tariq BASHIR
期刊论文
Benzenesulfonic acid-grafted UIO-66 with improved hydrophobicity as a stable Brønsted acid catalyst
期刊论文
Halide-free carbonylation of methanol with H-MOR supported CuCeO
Chaoli Tong, Jiachang Zuo, Danlu Wen, Weikun Chen, Linmin Ye, Youzhu Yuan
期刊论文
Microbial communities biostimulated by ethanol during uranium (VI) bioremediation in contaminated sediment as shown by stable isotope probing
Mary Beth LEIGH,Wei-Min WU,Erick CARDENAS,Ondrej UHLIK,Sue CARROLL,Terry GENTRY,Terence L. MARSH,Jizhong ZHOU,Philip JARDINE,Craig S. CRIDDLE,James M. TIEDJE
期刊论文