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Tailoring electrical conductivity of two dimensional nanomaterials using plasma for edge electronics:

Aswathy Vasudevan, Vasyl Shvalya, Aleksander Zidanšek, Uroš Cvelbar

《化学科学与工程前沿（英文）》 2019年 第13卷 第3期   页码 427-443 doi: 10.1007/s11705-019-1805-4

摘要： Since graphene has been discovered, two-dimensional nanomaterials have attracted attention due to their promising tunable electronic properties. The possibility of tailoring electrical conductivity at the atomic level allows creating new prospective 2D structures for energy harvesting and sensing-related applications. In this respect, one of the most successful way to manipulate the physical properties of the aforementioned materials is related to the surface modification techniques employing plasma. Moreover, plasma-gaseous chemical treatment can provide a controlled change in the bandgap, increase sensitivity and significantly improve the structural stability of material to the environment as well. This review deals with recent advances in the modification of 2D carbon nanostructures for novel ‘edge’ electronics using plasma technology and processes.

关键词： graphene     edge electronics     2D nanomaterials     plasma     electrical conductivity    

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composite with phosphorus-nitrogen based flame retardant and multi-walled carbon nanotubes for enhanced electricalconductivity and acceptable flame retardancy

Yong Luo, Yuhui Xie, Renjie Chen, Ruizhi Zheng, Hua Wu, Xinxin Sheng, Delong Xie, Yi Mei

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1332-1345 doi: 10.1007/s11705-021-2035-0

摘要： Design and exploitation of flame retardant polymers with high electrical conductivity are desired for polymer applications in electronics. Herein, a novel phosphorus-nitrogen intumescent flame retardant was synthesized from pentaerythritol octahydrogen tetraphosphate, phenylphosphonyl dichloride, and aniline. Low-density polyethylene was combined with the flame retardant and multi-walled carbon nanotubes to form a nanocomposite material via a ball-milling and hot-pressing method. The electrical conductivity, mechanical properties, thermal performance, and flame retardancy of the composites were investigated using a four-point probe instrument, universal tensile machine, thermogravimetric analysis, and cone calorimeter tests, respectively. It was found that the addition of multi-walled carbon nanotubes can significantly improve the electrical conductivity and mechanical properties of the low-density polyethylene composites. Furthermore, the combination of multi-walled carbon nanotubes and phosphorus–nitrogen flame retardant remarkably enhances the flame retardancy of matrixes with an observed decrease of the peak heat release rate and total heat release of 49.8% and 51.9%, respectively. This study provides a new and effective methodology to substantially enhance the electrical conductivity and flame retardancy of polymers with an attractive prospect for polymer applications in electrical equipment.

关键词： MWCNTs     PEPA     electrical conductivity     flame retardant     low density polyethylene    

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Fracture model for the prediction of the electrical percolation threshold in CNTs/Polymer composites

Yang SHEN, Pengfei HE, Xiaoying ZHUANG

《结构与土木工程前沿（英文）》 2018年 第12卷 第1期   页码 125-136 doi: 10.1007/s11709-017-0396-8

摘要： In this paper, we propose a 3D stochastic model to predict the percolation threshold and the effective electric conductivity of CNTs/Polymer composites. We consider the tunneling effect in our model so that the unrealistic interpenetration can be avoided in the identification of the conductive paths between the CNTs inside the polymer. The results are shown to be in good agreement with reported experimental data.

关键词： electrical percolation     CNTs/Polymer composites     fracture model     electric conductivity     tunnelling effects    

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Experimental research on thermal transport properties of crystallized palladium-based alloys

Siyuan CHENG, Xuguo SHI, Weigang MA, Xing ZHANG, Guanglai LIU, Mingxiang PAN, Weihua WANG

《能源前沿（英文）》 2018年 第12卷 第1期   页码 121-126 doi: 10.1007/s11708-018-0531-9

摘要： Palladium-based alloy is a kind of material with a high glass forming ability and can be easily formed into an amorphous state. After an annealing process, it can also be maintained at a crystallized state. To study the thermal and electrical transport properties of crystallized palladium-based alloys, the steady-state T-type method, standard four-probe method, and AC heating-DC detecting T-type method were used to measure the thermal conductivity, electrical conductivity, and Seebeck coefficient of crystallized Pd Ni Cu P and Pd Ni Cu P alloys respectively. The results show that compared to amorphous samples, the thermal conductivity and electrical conductivity of crystallized palladium-based alloys are significantly higher, while the Seebeck coefficient is lower. The ratio of crystallized and amorphous thermal conductivity is higher for Pd Ni Cu P alloy fiber which has a higher glass forming ability, while the ratio of electronic thermal conductivity almost remains constant for both alloy fibers. The results also show that the slope of electrical resistivity to temperature is a function of elemental composition for crystallized quaternary palladium-based alloy fibers. The sensitivity of thermal conductivity and electrical conductivity to the composition is high, while the correlation between Seebeck coefficient and composition is relatively weak.

关键词： palladium-based alloy     T-type method     thermal conductivity     electrical conductivity     Seebeck coefficient    

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Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1278-1

摘要： Abstract • Graphite bipolar electrodes act as an appropriate bed for the CDI process. • Activated carbon Coating improves the application of the electrodes. • CDI is an environmentally friendly method to apply for brackish water. • Initial concentration is the most important parameter in the CDI method. • CDI process in a batch-mode setup needs more development. This research investigates a capacitive deionization method for salinity reduction in a batch reactor as a new approach for desalination. Reductions of cost and energy compared with conventional desalination methods are the significant advantages of this approach. In this research, experiments were performed with a pair of graphite bipolar electrodes that were coated with a one-gram activated carbon solution. After completing preliminary tests, the impacts of four parameters on electrical conductivity reduction, including (1) the initial concentration of feed solution, (2) the duration of the tests, (3) the applied voltage, and (4) the pH of the solution, were examined. The results show that the maximum efficiency of electrical conductivity reduction in this laboratory-scale reactor is about 55%. Furthermore, the effects of the initial concentration of feed solution are more significant than the other parameters. Thus, using the capacitive deionization method for water desalination with low and moderate salt concentrations (i.e., brackish water) is proposed as an affordable method. Compared with conventional desalination methods, capacitive deionization is not only more efficient but also potentially more environmentally friendly.

关键词： Capacitive deionization (CDI)     Desalination     Electrical conductivity (EC)     Graphite bipolar electrode     Activated carbon coated (ACC)    

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Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2088-2100 doi: 10.1007/s11705-023-2352-6

摘要： Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor application

关键词： nickel ferrite conductivity     carbon oxygen vacancies    

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Electromagnetic induction mapping at varied soil moisture reveals field-scale soil textural patterns and gravel lenses

Hiruy ABDU, David A. ROBINSON, Janis BOETTINGER, Scott B. JONES

《农业科学与工程前沿（英文）》 2017年 第4卷 第2期   页码 135-145 doi: 10.15302/J-FASE-2017143

摘要： Knowledge of the spatial distribution of soil textural properties is important for determining soil moisture storage and soil hydraulic transport properties. Capturing field heterogeneity without exhaustive sampling and costly sample analysis is difficult. Our objective was to employ electromagnetic induction (EMI) mapping in low apparent electrical conductivity (EC ) soils at varying soil water contents to capture time invariant properties such as soil texture. Georeferenced EC measurements were taken using a ground conductivity meter on six different days where volumetric water content ( ) varied from 0.11 to 0.23. The 50 m × 50 m field included a subsurface gravelly patch in an otherwise homogeneous silt-loam alluvial soil. Ordinary block kriging predicted EC at unsampled areas to produce 1-m resolution maps. Temporal stability analysis was used to divide the field into three distinct EC regions. Subsequent ground-truthing confirmed the lowest conductivity region correlated with coarse textured soil parent materials associated with a former high-energy alluvial depositional area. Combining maps using temporal stability analysis gives the clearest image of the textural difference. These maps could be informative for modeling, experimental design, sensor placement and targeted zone management strategies in soil science, ecology, hydrology, and agricultural applications.

关键词： soil electrical conductivity     soil texture mapping     temporal stability analysis    

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Permeability and thermal conductivity of host compressed natural graphite for consolidated activated

Bo TIAN, Liwei WANG, Zhequan JIN, Ruzhu WANG

《能源前沿（英文）》 2011年 第5卷 第2期   页码 159-165 doi: 10.1007/s11708-011-0145-y

摘要： Permeability and thermal conductivity test units were set up to study the heat and mass transfer performance of the host material, i.e. expanded natural graphite (ENG), for consolidated activated carbon (AC) adsorbent. The permeability was tested with nitrogen as the gas source, and the thermal conductivity was studied using steady-state heat source method. The results showed that the values of permeability and thermal conductivity were 10 to 10 m and 1.7 to 3.2 W/(m·K), respectively, while the density compressed expanded natural graphite (CENG) varied from 100 to 500 kg/m . The permeability decreased with the increasing density of CENG, whereas the thermal conductivity increased with the increasing density of CENG. Then the thermal conductivity and permeability of granular AC were researched. It was discovered that the thermal conductivity of samples with different grain size almost kept constant at 0.36 W/(m·K) while the density was approximately 600 kg/m . This means that the thermal conductivity was not related to the grain size of AC. The thermal conductivity of CENG was improved by 5 to 10 times compared with that of granular AC. Such a result showed that CENG was a promising host material for AC to improve the heat transfer performance, while the mass transfer performance should be considered in different conditions for utilization of adsorbent.

关键词： permeability     thermal conductivity     expanded nature graphite     activated carbon    

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Equivalent thermal conductivity of heat pipes

LU Zesheng, MA Binghui

《机械工程前沿（英文）》 2008年 第3卷 第4期   页码 462-466 doi: 10.1007/s11465-008-0087-1

摘要： In precision machining, the machining error from thermal distortion carries a high proportion of the total errors. If a precision machining tool can transfer heat fast, the thermal distortion will be reduced and the machining precision will be improved. A heat pipe working based on phase transitions of the inner working liquid transfers heat with high efficiency and is widely applied in spaceflight and chemical industries. In mechanics, applications of heat pipes are correspondingly less. When a heat pipe is applied to a hydrostatic motorized spindle, the thermal distortion cannot be solved during the heat transfer process because thermal conductivity or equivalent thermal conductivity should be provided first for special application in mechanics. An equivalent thermal conductivity model based on equivalent thermal resistances is established. Performance tests for a screen wick pipe, gravity pipe, and rotation heat pipe are done to validate the efficiency of the equivalent thermal conductivity model. The proposed model provides a calculation method for the thermal distortion analysis of heat pipes applied in the motorized spindle.

关键词： proposed     distortion analysis     hydrostatic motorized     motorized spindle     Performance    

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Preparation, with graphene, of novel biomimetic self-healing microcapsules with high thermal stability and conductivity

《结构与土木工程前沿（英文）》 2023年 第17卷 第8期   页码 1188-1198 doi: 10.1007/s11709-023-0027-5

摘要： This paper reports a comparative study of microcapsules with enhanced thermal stability and electrical conductivity inspired by the bionic thermal insulation of birds’ feathers for self-healing aged asphalt. The work is based on an in situ polymerization with composite shell components of graphene and hexamethoxymethylmelamine resin. By using graphene, microcapsules with rough surfaces are achieved, improving the interface between microcapsules and asphalt. In addition, the microcapsules’ initial thermal decomposition temperature is appropriately high, so that the stability of the microcapsule in the asphalt highway system is protected. The proportion of graphene in the microcapsule shell can regulate the microcapsule’s heat resistance because graphene modifies the shell’s structural makeup. Additionally, the microcapsules’ electrical conductivity is relatively high. The self-healing capability of bitumen sharply increases, providing benefit to the effect of microcapsules on the properties of aged asphalt.

关键词： graphene     microcapsule     bitumen     heat insulation     conductivity    

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Recycling Materials from Waste Electrical and Electronic Equipment

Jinhui Li

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-1001-z

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CHARACTERISTICS OF HERBIVORY/WOUND-ELICITED ELECTRICAL SIGNAL TRANSDUCTION IN TOMATO

《农业科学与工程前沿（英文）》 2021年 第8卷 第2期

摘要：

Electrical signals commonly occur in plants in response to various environmental changes and have a dominant function in plant acclimation. The transduction of wound-elicited electrical signals in the model plant species Arabidopsis has been characterized but the characteristics of electrical signal transduction in response to herbivory or wounding in crop species remain unknown. Here, the features of electrical signals elicited by insect herbivory and wounding in tomato were investigated. Unlike those in Arabidopsis, wounding tomato leaves did not cause leaf-to-leaf electrical signal transduction. In contrast, electrical signals elicited in response to petiole wounding were stronger and more strongly transduced. Leaflet wounding also activated electrical signal transduction and jasmonic acid (JA) signaling within the whole compound leaf. It was also demonstrated that tomato glutamate receptor-like 3.3 (GLR3.3) and GLR3.5 mediated leaflet-to-leaflet electrical signal transduction. Herbivory-induced JA accumulation and Helicoverpa armigera resistance were reduced in glr3.3/3.5 plants. This work reveals the nature of electrical signal transduction in tomato and emphasizes the key roles of GLR3.3 and GLR3.5 in electrical signal transduction and JA signaling activation.

 

关键词： electrical signal / glutamate receptor-like / herbivory / jasmonic acid / tomato    

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Modeling of ion conductivity in Nafion membranes

YANG Zhen, PENG Xiaofeng, WANG Buxuan, DUAN Yuanyuan, LEE Duujong

《能源前沿（英文）》 2007年 第1卷 第1期   页码 58-66 doi: 10.1007/s11708-007-0005-y

摘要： A theoretical investigation was conducted to describe the ion transport behavior in a Nafion Membrane of proton exchange membrane fuel cells (PEMFC). By analyzing the surface energy configuration of the ionic clusters in a Nafion membrane, an equivalent field intensity, , was introduced to facilitate the analysis of surface resistance against ion conduction in the central region of clusters. An expression was derived for ionic conductivity incorporating the influence of surface resistance. A face-centered cubic (FCC) lattice model for a spatial cluster distribution was used to modify the effect of water content on ionic conductivity in the polymeric matrix, i.e., the regions between clusters. Compared with the available empirical correlations, the new expression showed much better agreement with the available experimental results, which indicates the rationality to consider the structural influence on ion conduction in water-swollen Nafion membranes.

关键词： face-centered     polymeric     theoretical investigation     conduction     equivalent    

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Exploration on electrical resistance tomography in characterizing the slurry spatial distribution in

《结构与土木工程前沿（英文）》 2024年 第18卷 第3期   页码 365-379 doi: 10.1007/s11709-024-1049-3

摘要： This study investigated the application of electrical resistance tomography (ERT) in characterizing the slurry spatial distribution in cemented granular materials (CGMs). For CGM formed by self-flow grouting, the voids in the accumulation are only partially filled and the bond strength is often limited, which results in difficulty in obtaining in situ samples for quality evaluation. Therefore, it is usually infeasible to evaluate the grouting effect or monitor the slurry spatial distribution by a mechanical method. In this research, the process of grouting cement paste into high alumina ceramic beads (HACB) accumulation is reliably monitored with ERT. It shows that ERT results can be used to calculate the cement paste volume in the HACB accumulation, based on calibrating the saturation exponent n in Archie’s law. The results support the feasibility of ERT as an imaging tool in CGM characterization and may provide guidance for engineering applications in the future.

关键词： electrical resistance tomography     cemented granular material     grouting     spatial distribution     Archie’s law    

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Engineering Fronts in fields of Energy and Electrical Science and Technologies in the report of

《能源前沿（英文）》 2023年 第17卷 第1期   页码 5-8 doi: 10.1007/s11708-023-0868-6

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标题 作者 时间 类型 操作

Tailoring electrical conductivity of two dimensional nanomaterials using plasma for edge electronics:

Aswathy Vasudevan, Vasyl Shvalya, Aleksander Zidanšek, Uroš Cvelbar

期刊论文

composite with phosphorus-nitrogen based flame retardant and multi-walled carbon nanotubes for enhanced electricalconductivity and acceptable flame retardancy

Yong Luo, Yuhui Xie, Renjie Chen, Ruizhi Zheng, Hua Wu, Xinxin Sheng, Delong Xie, Yi Mei

期刊论文

Fracture model for the prediction of the electrical percolation threshold in CNTs/Polymer composites

Yang SHEN, Pengfei HE, Xiaoying ZHUANG

期刊论文

Experimental research on thermal transport properties of crystallized palladium-based alloys

Siyuan CHENG, Xuguo SHI, Weigang MA, Xing ZHANG, Guanglai LIU, Mingxiang PAN, Weihua WANG

期刊论文

Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

期刊论文

Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor

期刊论文

Electromagnetic induction mapping at varied soil moisture reveals field-scale soil textural patterns and gravel lenses

Hiruy ABDU, David A. ROBINSON, Janis BOETTINGER, Scott B. JONES

期刊论文

Permeability and thermal conductivity of host compressed natural graphite for consolidated activated

Bo TIAN, Liwei WANG, Zhequan JIN, Ruzhu WANG

期刊论文

Equivalent thermal conductivity of heat pipes

LU Zesheng, MA Binghui

期刊论文

Preparation, with graphene, of novel biomimetic self-healing microcapsules with high thermal stability and conductivity

期刊论文

Recycling Materials from Waste Electrical and Electronic Equipment

Jinhui Li

期刊论文

CHARACTERISTICS OF HERBIVORY/WOUND-ELICITED ELECTRICAL SIGNAL TRANSDUCTION IN TOMATO

期刊论文

Modeling of ion conductivity in Nafion membranes

YANG Zhen, PENG Xiaofeng, WANG Buxuan, DUAN Yuanyuan, LEE Duujong

期刊论文

Exploration on electrical resistance tomography in characterizing the slurry spatial distribution in

期刊论文

Engineering Fronts in fields of Energy and Electrical Science and Technologies in the report of

期刊论文