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Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 313-319 doi: 10.1007/s11783-009-0025-4

摘要： This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact of leachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (), the reaction rate constant in the first stage (), and the reaction rate constant in the second stage () of 64.746 L, 0.202 d, and 0.338 d, respectively, were comparable to the old ones of 42.069 L, 0.231 d, and 0.231 d. The new model is better able to explain the mechanisms involved in LFG generation.

关键词： landfill gas (LFG)     generation rate model     first-order kinetics     two-stage reaction     outflow function    

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Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

《化学科学与工程前沿（英文）》 2010年 第4卷 第3期   页码 322-327 doi: 10.1007/s11705-009-0261-y

摘要： In the present work, bimetallic silver/zinc was applied into the degradation of trihalomethanes, THMs: CHCl, CHBrCl, CHBrCl, and CHBr. The kinetics reaction rates and removal efficiencies of the THM compound mixtures, in the aqueous solutions, were investigated. Batch experiments were conducted under mild conditions, ambient temperature, and pressure. The primary degradation reaction followed a pseudo-first-order kinetic law. The first-order rate constants and the degradation efficiencies followed the decreasing order of CHBr>CHBrCl>CHBrCl>CHCl. The bond dissociation energy and hydrophilic/hydrophobic characteristics of the THM compounds may become the most important parameters affecting the degradation kinetics and efficiency by bimetallic Ag/Zn.

关键词： reaction     first-order     dissociation     degradation reaction     aqueous    

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Flow behavior of liquid-solid coupled system of piezoelectric micropump

LU Lijun, WU Jiankang

《机械工程前沿（英文）》 2008年 第3卷 第1期   页码 50-54 doi: 10.1007/s11465-008-0003-8

摘要： This paper employs a shallow water model and the finite element method to approximate periodical flows of a micropump to a two-dimensional thickness-averaged flow. A liquid-solid coupled system equation of the micropump is presented. Through the mode analysis of the liquid-solid coupled system, the first-order natural frequency, diaphragm vibration shape and amplitude-frequency relationship are obtained. The vibration response of the diaphragm is calculated when an external electric field is applied. Based on the thickness-averaged flow equation, the periodical flow of the micropump is studied using the finite volume method to investigate the flow behavior and flow rate-frequency characteristics. Numerical results indicate that an optimal working frequency can be obtained, at which the flow rate of the micropump achieves the maximum when the external electric voltage is fixed.

关键词： amplitude-frequency relationship     first-order     micropump     diaphragm vibration     electric    

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Comparison between linear and non-linear forms of pseudo-first-order and pseudo-second-order adsorption

Junxiong LIN , Lan WANG ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 320-324 doi: 10.1007/s11783-009-0030-7

摘要： The best-fit equations of linear and non-linear forms of the two widely used kinetic models, namely pseudo-first-order and pseudo-second-order equations, were compared in this study. The experimental kinetics of methylene blue adsorption on activated carbon was used for this research. Both the correlation coefficient () and the normalized standard deviation Δ(%) were employed as error analysis methods to determine the best-fitting equations. The results show that the non-linear forms of pseudo-first-order and pseudo-second-order models were more suitable than the linear forms for fitting the experimental data. The experimental kinetics may have been distorted by linearization of the linear kinetic equations, and thus, the non-linear forms of kinetic equations should be primarily used to obtain the adsorption parameters. In addition, the Δ(%) method for error analysis may be better to determine the best-fitting model in this case.

关键词： adsorption     pseudo-first order     pseudo-second order     kinetic model     linear method     non-linear method    

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Free vibration analysis of laminated FG-CNT reinforced composite beams using finite element method

T. VO-DUY, V. HO-HUU, T. NGUYEN-THOI

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 324-336 doi: 10.1007/s11709-018-0466-6

摘要： In the present study, the free vibration of laminated functionally graded carbon nanotube reinforced composite beams is analyzed. The laminated beam is made of perfectly bonded carbon nanotubes reinforced composite (CNTRC) layers. In each layer, single-walled carbon nanotubes are assumed to be uniformly distributed (UD) or functionally graded (FG) distributed along the thickness direction. Effective material properties of the two-phase composites, a mixture of carbon nanotubes (CNTs) and an isotropic polymer, are calculated using the extended rule of mixture. The first-order shear deformation theory is used to formulate a governing equation for predicting free vibration of laminated functionally graded carbon nanotubes reinforced composite (FG-CNTRC) beams. The governing equation is solved by the finite element method with various boundary conditions. Several numerical tests are performed to investigate the influence of the CNTs volume fractions, CNTs distributions, CNTs orientation angles, boundary conditions, length-to-thickness ratios and the numbers of layers on the frequencies of the laminated FG-CNTRC beams. Moreover, a laminated composite beam combined by various distribution types of CNTs is also studied.

关键词： free vibration analysis     laminated FG-CNTRC beam     finite element method     first-order shear deformation theory     composite material    

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具有区域约束的一阶多智能体系统的有限时间编队控制 Research Articles

杨正全1,潘小芳1,张青1,陈增强2

《信息与电子工程前沿（英文）》 2021年 第22卷 第1期   页码 1-140 doi: 10.1631/FITEE.2000177

摘要： 研究具有区域约束的多智能体系统的有限时间编队控制问题。多智能体具有一阶动力学和一个共同目标区域。提出一种利用局部信息和交互作用的控制算法。如果通信图是无向连通的以及所设计框架是刚性的，证明该控制器可用于解决具有目标区域的编队问题。该控制算法可控制所有智能体在有限时间内进入所需区域，同时达到并保持所需队形。最后，给出一个数值例子说明算法的有效性。

关键词： 有限时间编队；多智能体系统；渐进收敛；约束集；李雅普诺夫定理    

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Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy consumption

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

《环境科学与工程前沿（英文）》 2019年 第13卷 第5期 doi: 10.1007/s11783-019-1152-1

摘要： The wastewater from industrial area was treated by EC via Fe and Al electrodes. Cu, Ni, Cr and Zn were highly removed at the first minutes, simultaneously. Pseudo-2nd-order was found to be more suitable for kinetics. Adsorption capacities based on kinetic modeling were observed as Cr>Cu>Ni>Zn. The chemical cost in the case of pH adjustment after EC was less as 3.83 $/m3. It is known that wastewater produced by the metal-plating industry contains several heavy metals, which are acidic in nature and therefore toxic for the environment and for living creatures. In particular, heavy metals enter the food chain and accumulate in vital organs and cause serious illness. The precipitation of these metals is mostly achieved by pH adjustment, but as an alternative to this method, the electrocoagulation process has investigated in this study using iron and aluminum electrodes. The effects of the pH adjustment on removal before and after the electrocoagulation process were investigated, and cost analyses were also compared. It was observed that a high proportion of removal was obtained during the first minutes of the electrocoagulation process; thus, the current density did not have a great effect. In addition, the pH adjustment after the electrocoagulation process using iron electrodes, which are 10% more effective than aluminum electrodes, was found to be much more efficient than before the electrocoagulation process. In the process where kinetic modeling was applied, it was observed that the heavy metal removal mechanism was not solely due to the collapse of heavy metals at high pH values, and with this modeling, it was seen that this mechanism involved adsorption by iron and aluminum hydroxides formed during the electrocoagulation process. When comparing the ability of heavy metals to be adsorbed, the sequence was observed to be Cr>Cu>Ni>Zn, respectively.

关键词： Electrochemical treatment     Heavy metals     Kinetic modeling     Pseudo first order kinetic     Pseudo second order kinetic    

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Shallow foundation response variability due to soil and model parameter uncertainty

Prishati RAYCHOWDHURY,Sumit JINDAL

《结构与土木工程前沿（英文）》 2014年 第8卷 第3期   页码 237-251 doi: 10.1007/s11709-014-0242-1

摘要： Geotechnical uncertainties may play crucial role in response prediction of a structure with substantial soil-foundation-structure-interaction (SFSI) effects. Since the behavior of a soil-foundation system may significantly alter the response of the structure supported by it, and consequently several design decisions, it is extremely important to identify and characterize the relevant parameters. Moreover, the modeling approach and the parameters required for the modeling are also critically important for the response prediction. The present work intends to investigate the effect of soil and model parameter uncertainty on the response of shallow foundation-structure systems resting on dry dense sand. The SFSI is modeled using a beam-on-nonlinear-winkler-foundation (BNWF) concept, where soil beneath the foundation is assumed to be an assembly of discrete, nonlinear elements composed of springs, dashpots and gap elements. The sensitivity of both soil and model input parameters on shallow foundation responses are investigated using first-order second-moment (FOSM) analysis and Monte Carlo simulation through Latin hypercube sampling technique. It has been observed that the degree of accuracy in predicting the responses of the shallow foundation is highly sensitive soil parameters, such as friction angle, Poisson’s ratio and shear modulus, rather than model parameters, such as stiffness intensity ratio and spring spacing; indicating the importance of proper characterization of soil parameters for reliable soil-foundation response analysis.

关键词： shallow foun dation     sensitivity analysis     centrifuge data     first-order-second-moment (FOSM) method     parameter uncertainty    

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Effect of metal ion-doping on characteristics and photocatalytic activity of TiO

Rongfang YUAN,Beihai ZHOU,Duo HUA,Chunhong SHI

《环境科学与工程前沿（英文）》 2015年 第9卷 第5期   页码 850-860 doi: 10.1007/s11783-014-0737-y

摘要： The effect of ion-doping on TiO nanotubes were investigated to obtain the optimal TiO nanotubes for the effective decomposition of humic acids (HA) through O /UV/ion-doped TiO process. The experimental results show that changing the calcination temperature, which changed the weight fractions of the anatase phase, the average crystallite sizes, the Brunauer-Emmett-Teller surface area, and the energy band gap of the catalyst, affected the photocatalytic activity of the catalyst. The ionic radius, valence state, and configuration of the dopant also affected the photocatalytic activity. The photocatalytic activities of the catalysts on HA removal increased when Ag , Al , Cu , Fe , V , and Zn were doped into the TiO nanotubes, whereas such activities decreased as a result of Mn - and Ni -doping. In the presence of 1.0 at.% Fe -doped TiO nanotubes calcined at 550°C, the removal efficiency of HA was 80% with a pseudo-first-order rate constant of 0.158 min . Fe in TiO could increase the generation of ·OH, which could remove HA. However, Fe in water cannot function as a shallow trapping site for electrons or holes.

关键词： TiO2 nanotubes     ion-doping     humic acids     pseudo-first-order     mechanism    

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Biodegradation of 2-methylisoborneol by bacteria enriched from biological activated carbon

Rongfang YUAN, Beihai ZHOU, Chunhong SHI, Liying YU, Chunlei ZHANG, Junnong GU

《环境科学与工程前沿（英文）》 2012年 第6卷 第5期   页码 701-710 doi: 10.1007/s11783-011-0367-6

摘要： One of the most common taste and odour compounds (TOCs) in drinking water is 2-methylisoborneol (2-MIB) which cannot be readily removed by conventional water treatments. Four bacterial strains for degrading 2-MIB were isolated from the surface of a biological activated carbon filter, and were characterized as spp., spp., spp. and spp. based on 16S rRNA analysis. The removal efficiencies of 2-MIB with initial concentrations of 515 ng·L were 98.4%, 96.3%, 95.0%, and 92.8% for spp., spp., spp. and spp., respectively. These removal efficiencies were slightly higher than those with initial concentration at 4.2 mg·L (86.1%, 84.4%, 86.7% and 86.0%, respectively). The kinetic model showed that biodegradation of 2-MIB at an initial dose of 4.2 mg·L was a pseudo-first-order reaction, with rate constants of 0.287, 0.277, 0.281, and 0.294 d , respectively. These degraders decomposed 2-MIB to form 2-methylenebornane and 2-methyl-2-bornane as the products.

关键词： 2-methylisoborneol (2-MIB)     biodegradation     2-methylenebornane     2-methyl-2-bornane     pseudo-first-order reaction    

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预应力混凝土斜拉桥施工过程中的力学行为研究

张建民,肖汝诚

《中国工程科学》 2007年 第9卷 第5期   页码 36-41

摘要：

斜拉桥施工过程中的力学行为研究是一项涉及斜拉桥质量和安全的关键技术问题。采用空间非线性 有限元模拟了某大跨度预应力混凝土斜拉桥主梁的悬臂浇筑过程，引入一阶最优化计算方法来确定斜拉桥的合 理施工状态，求出各施工阶段的斜拉索张拉索力和主梁的预抛高值，并讨论了物理非线性和几何非线性等因素 对桥梁施工的影响，提出了减小非线性影响的措施。。

关键词： 斜拉桥     一阶分析法     合理施工状态     非线性    

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High-order phase-field model with the local and second-order max-entropy approximants

Fatemeh AMIRI

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 406-416 doi: 10.1007/s11709-018-0475-5

摘要： We approximate the fracture surface energy functional based on phase-field method with smooth local maximum entropy (LME) and second-order maximum entropy (SME) approximants. The higher-order continuity of the meshfree methods such as LME and SME approximants allows to directly solve the fourth-order phase-field equations without splitting the fourth-order differential equation into two second-order differential equations. We will first show that the crack surface functional can be captured more accurately in the fourth-order model with smooth approximants such as LME, SME and B-spline. Furthermore, smaller length scale parameter is needed for the fourth-order model to approximate the energy functional. We also study SME approximants and drive the formulations. The proposed meshfree fourth-order phase-field formulation show more stable results for SME compared to LME meshfree methods.

关键词： second-order maximum entropy     local maximum entropy     second- and fourth-order phase-field models     B-spline    

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An assemble-to-order production planning with the integration of order scheduling and mixed-model sequencing

Baoxi WANG, Zailin GUAN, Yarong CHEN, Xinyu SHAO, Ming JIN, Chaoyong ZHANG

《机械工程前沿（英文）》 2013年 第8卷 第2期   页码 137-145 doi: 10.1007/s11465-013-0251-0

摘要：

For assemble-to-order enterprises, both order scheduling and mixed-model sequencing need to be taken into consideration in the formulation of order-oriented assembly plan. First, determining production priority for the received orders, and then conducting assembly sequence to the mixed-model products in each order. Order scheduling is aimed to ensure order delivery with the optimization goal of minimal total overdue time, while product sequencing is aimed to minimize the makespan so as to meet the requirement on completion time of the order. In the end, the paper establishes a mixed integer programming model based on an industrial case, and makes programming calculation with Xpress-MP to accomplish an order-oriented assembly plan conforming to actual production.

关键词： mixed-model assembly line     assemble-to-order     order scheduling     sequencing    

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Sustainable intensification of agriculture in sub-Saharan Africa: first things first!

Bernard VANLAUWE, Achim DOBERMANN

《农业科学与工程前沿（英文）》 2020年 第7卷 第4期   页码 376-382 doi: 10.15302/J-FASE-2020351

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千米级斜拉桥空间非线性合理恒载索力分析

张建民,肖汝诚

《中国工程科学》 2004年 第6卷 第12期   页码 37-42

摘要：

建立了斜拉桥索力调整的空间非线性有限元分析模型，以斜拉桥主梁和索塔的弯曲应变能为目标函数、结构应力及索力为约束条件，采用一阶最优化计算方法进行求解，用以确定成桥合理状态的索力。应用该法分析了某千米级斜拉桥的合理成桥状态，计算结果表明，该方法简单、有效。

关键词： 斜拉桥     一阶分析法     合理成桥状态    

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标题 作者 时间 类型 操作

Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

期刊论文

Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

期刊论文

Flow behavior of liquid-solid coupled system of piezoelectric micropump

LU Lijun, WU Jiankang

期刊论文

Comparison between linear and non-linear forms of pseudo-first-order and pseudo-second-order adsorption

Junxiong LIN , Lan WANG ,

期刊论文

Free vibration analysis of laminated FG-CNT reinforced composite beams using finite element method

T. VO-DUY, V. HO-HUU, T. NGUYEN-THOI

期刊论文

具有区域约束的一阶多智能体系统的有限时间编队控制

杨正全1,潘小芳1,张青1,陈增强2

期刊论文

Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy consumption

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

期刊论文

Shallow foundation response variability due to soil and model parameter uncertainty

Prishati RAYCHOWDHURY,Sumit JINDAL

期刊论文

Effect of metal ion-doping on characteristics and photocatalytic activity of TiO

Rongfang YUAN,Beihai ZHOU,Duo HUA,Chunhong SHI

期刊论文

Biodegradation of 2-methylisoborneol by bacteria enriched from biological activated carbon

Rongfang YUAN, Beihai ZHOU, Chunhong SHI, Liying YU, Chunlei ZHANG, Junnong GU

期刊论文

预应力混凝土斜拉桥施工过程中的力学行为研究

张建民,肖汝诚

期刊论文

High-order phase-field model with the local and second-order max-entropy approximants

Fatemeh AMIRI

期刊论文

An assemble-to-order production planning with the integration of order scheduling and mixed-model sequencing

Baoxi WANG, Zailin GUAN, Yarong CHEN, Xinyu SHAO, Ming JIN, Chaoyong ZHANG

期刊论文

Sustainable intensification of agriculture in sub-Saharan Africa: first things first!

Bernard VANLAUWE, Achim DOBERMANN

期刊论文

千米级斜拉桥空间非线性合理恒载索力分析

张建民,肖汝诚

期刊论文