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Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

《化学科学与工程前沿(英文)》 2009年 第3卷 第1期   页码 65-67 doi: 10.1007/s11705-009-0105-9

摘要: Lithium is one of the most important light metals, which is widely used as raw materials for large-capacity rechargeable batteries, light aircraft alloys and nuclear fusion fuel. Seawater, which contains 250 billion tons of lithium in total, has thus recently been noticed as a possible resource of lithium. While, since the average concentration of lithium in seawater is quite low (0.17 mg·L ), enriching it to an adequate high density becomes the primary step for industrial applications. The adsorption method is the most prospective technology for increasing the concentration of lithium in liquid. Among the adsorbents for lithium, the ion-sieve is a kind of special absorbent which has high selectivity for Li , especially the spinel manganese oxides (SMO), which among the series of ion-sieves, has become the most promising adsorption material for lithium. In this study, the SMO ion-sieve was prepared by a coprecipitation method. The preparation conditions were discussed and the sample characters were analyzed. Recovery of Li from seawater were studied in batch experiments using prepared ion-sieve, and the effect of solution pH and the uptake rates were also investigated in different Li solutions.

关键词: lithium     ion-sieve     seawater     spinel manganese oxide    

Preparation and characterization of lithium

Chang WANG,Yanlong ZHAI,Xi WANG,Ming ZENG

《化学科学与工程前沿(英文)》 2014年 第8卷 第4期   页码 471-477 doi: 10.1007/s11705-014-1449-3

摘要: Lithium -MnO ion-sieves were prepared from spinel LiMn O via treatment with nitric acid. The LiMn O was synthesized by a solid state reaction between LiOH·H O and MnO . The effects of the calcination time and temperature on the preparation of the LiMn O precursor and the lithium ion-sieve were investigated. In addition, the Li extraction ratio, the Mn dissolving ratio and the adsorption properties of the lithium ion-sieve were all measured. The lithium ion-sieve had a high exchange capacity and was selective for Li . Specifically, at pH= 13, the ion exchange capacity of Li was 30.9 mg/g in 10 mmol/L LiCl solution and the lithium extraction ratio and manganese dissolving ratio were 95% and 25%, respectively.

关键词: lithium ion-sieve     solid state reaction     adsorption     LiMn2O4    

Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis

Ying Yan, Peng Huang, Huiping Zhang

《化学科学与工程前沿(英文)》 2019年 第13卷 第4期   页码 772-783 doi: 10.1007/s11705-019-1827-y

摘要: Carbon molecular sieve membrane (CMSM)/paper-like stainless steel fibers (PSSF) has been manufactured by pyrolyzing poly (furfuryl alcohol) (PFA) coated on the metal fibers. PFA was synthesized using oxalic acid dihydrate as a catalyst and coated on microfibers by dip coating method. For the purpose of investigating the effects of final carbonization temperature, the composites were carbonized between 400°C and 800°C under flowing nitrogen. The morphology and microstructure were examined by X-ray diffraction, Fourier transforms infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, N adsorption and desorption, Raman spectra and X-ray photoelectron spectra. The consequences of characterization showed that the CMSM containing mesopores of 3.9 nm were manufactured. The specific surface area of the CMSM/PSSF fabricated in different pyrolysis temperature varies from 26.5 to 169.1 m ∙g and pore volume varies from 0.06 to 0.23 cm ∙g . When pyrolysis temperature exceeds 600°C, the specific surface, pore diameter and pore volume decreased as carbonization temperature increased. Besides, the degree of graphitization in carbon matrix increased with rising pyrolysis temperature. Toluene adsorption experiments on different structured fixed bed that was padded by CMSM/PSSF and granular activated carbon (GAC) were conducted. For the sake of comparison, adsorption test was also performed on fixed bed packed with GAC. The experimental results indicated that the rate constant ′ was dramatically increased as the proportion of CMCM/PSSF composites increased on the basis of Yoon-Nelson model, which suggested that structured fixed bed padded with CMSM/PSSF composite offered higher adsorption rate and mass transfer efficiency.

关键词: carbon molecular sieve membrane     stainless steel fibers     pyrolysis     structured fixed bed     toluene    

Thermal decomposition of poly(ethylene terephthalate)/mesoporous molecular sieve composites

RUN Mingtao, ZHANG Dayu, WU Sizhu, WU Gang

《化学科学与工程前沿(英文)》 2007年 第1卷 第1期   页码 50-54 doi: 10.1007/s11705-007-0010-z

摘要: The nonisothermal and isothermal degradation processes of poly (ethylene terephthalate)/mesoporous molecular sieve (PET/MMS) composites synthesized by in-situ polymerization were studied by using thermogravimetric analysis in nitrogen. The nonisothermal degradation of the composite is found to be the first-order reaction. An iso-conversional procedure developed by Ozawa is used to calculate the apparent activation energy (), which is an average value of about 260 kJ/mol with the weight conversion from 0% to 30%, and is higher than that of neat PET. Isothermal degradation results are confirmed with the nonisothermal process, in which PET/MMS showed higher thermal stability than neat PET. The polymer in mesoporous channels has more stability due to the protection of the inorganic pore-wall. These results indicate that mesoporous MMS in PET/MMS composites improve the stability of the polymer.

关键词: polymerization     isothermal degradation     conversion     nonisothermal degradation     activation    

Advancing ion-exchange membranes to ion-selective membranes: principles, status, and opportunities

《环境科学与工程前沿(英文)》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1625-0

摘要:

● IEM ion/ion selectivities of charge, valence, & specific ion are critically assessed.

关键词: Ion-exchange membranes     Selectivity     Separations    

Alumina modified sodium vanadate cathode for aqueous zinc-ion batteries

《能源前沿(英文)》   页码 775-781 doi: 10.1007/s11708-023-0902-8

摘要: Aqueous zinc-ion batteries (ZIBs) have great prospects for widespread application in massive scale energy storage. By virtue of the multivalent state, open frame structure and high theoretical specific capacity, vanadium (V)-based compounds are a kind of the most developmental potential cathode materials for ZIBs. However, the slow kinetics caused by low conductivity and the capacity degradation caused by material dissolution still need to be addressed for large-scale applications. Therefore, sodium vanadate Na2V6O16·3H2O (NVO) was chosen as a model material, and was modified with alumina coating through simple mixing and stirring methods. After Al2O3 coating modification, the rate capability and long-cycle stability of Zn//NVO@Al2O3 battery have been significantly improved. The discharge specific capacity of NVO@Al2O3 reach up to 228 mAh/g (at 4 A/g), with a capacity reservation rate of approximately 68% after 1000 cycles, and the Coulombic efficiency (CE) is close to 100%. As a comparison, the capacity reservation rate of Zn//NVO battery is only 27.7%. Its superior electrochemical performance is mainly attributed to the Al2O3 coating layer, which can increase zinc-ion conductivity of the material surface, and to some extent inhibit the dissolution of NVO, making the structure stable and improving the cyclic stability of the material. This paper offers new prospects for the development of cathode coating materials for ZIBs.

关键词: cathodes     aqueous zinc-ion batteries     sodium vanadate     alumina     coating    

Vanadium oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coatingfor high performance zinc-ion batteries

《化学科学与工程前沿(英文)》 2023年 第17卷 第9期   页码 1244-1253 doi: 10.1007/s11705-022-2293-5

摘要: Vanadium oxides as cathode for zinc-ion batteries have attracted much attention because of their high theoretical capacity, flexible layered structure and abundant resources. However, cathodes are susceptible to the collapse of their layered structure and the dissolution of vanadium after repeated long cycles, which worsen their capacities and cycling stabilities. Herein, a synergistic engineering of calcium-ion intercalation and polyaniline coating was developed to achieve the superior electrochemical performance of vanadium pentoxide for zinc-ion batteries. The pre-intercalation of calcium-ion between vanadium pentoxide layers as pillars increase the crystal structure’s stability, while the polyaniline coating on the cathodes improves the conductivity and inhibits the dissolution of vanadium. This synergistic engineering enables that the battery system based-on the polyaniline coated calcium vanadate cathode to deliver a high capacity of 406.4 mAh·g−1 at 1 A·g−1, an ultralong cycle life over 6000 cycles at 10 A·g−1 with 93% capacity retention and high-rate capability. The vanadium oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coating was verified to effectively improve the electrochemical performance of zinc-ion batteries.

关键词: zinc-ion battery     CaV8O20     polyaniline coating     synergistic engineering     high capacity     long durability    

Ion-imprinted silica gel and its dynamic membrane for nickel ion removal from wastewaters

Jiehui Zeng, Jianxian Zeng, Hu Zhou, Guoqing Liu, Zhengqiu Yuan, Jian Jian

《化学科学与工程前沿(英文)》 2020年 第14卷 第6期   页码 1018-1028 doi: 10.1007/s11705-020-1915-z

摘要: An ion-imprinted sorbent (IIP) was prepared by using Ni as template, 3-[2-(2-aminoethylamino) ethylamino] propyl-trimethoxysilane as functional monomer, and silica gel as carrier. The adsorption performance of IIP towards Ni was investigated. IIP showed a higher adsorption capacity than that of non-imprinted sorbent, and it also exhibited high selectivity for Ni in the presence of Cu and Zn ions. Then, IIP was used to form a dynamic membrane onto the surface of ceramic membrane for treatment of electroplating wastewater containing Ni . Compared with ceramic membrane, IIP dynamic membrane had much higher steady membrane flux, and also rejected Ni to obtain a lower concentration of Ni in the permeate fluid. Perhaps it is suitable for future practice applications.

关键词: ion-imprinted     nickel ion     dynamic membrane     adsorption    

Highly selective metal recovery from spent lithium-ion batteries through stoichiometric hydrogen ion

Weiguang Lv, Xiaohong Zheng, Li Li, Hongbin Cao, Yi Zhang, Renjie Chen, Hancheng Ou, Fei Kang, Zhi Sun

《化学科学与工程前沿(英文)》 2021年 第15卷 第5期   页码 1243-1256 doi: 10.1007/s11705-020-2029-3

摘要: Spent lithium-ion battery recycling has attracted significant attention because of its importance in regard to the environment and resource importance. Traditional hydrometallurgical methods usually leach all valuable metals and subsequently extract target meals to prepare corresponding materials. However, Li recovery in these processes requires lengthy operational procedures, and the recovery efficiency is low. In this research, we demonstrate a method to selectively recover lithium before the leaching of other elements by introducing a hydrothermal treatment. Approximately 90% of Li is leached from high-Ni layered oxide cathode powders, while consuming a nearly stoichiometric amount of hydrogen ions. With this selective recovery of Li, the transition metals remain as solid residue hydroxides or oxides. Furthermore, the extraction of Li is found to be highly dependent on the content of transition metals in the cathode materials. A high leaching selectivity of Li (>98%) and nearly 95% leaching efficiency of Li can be reached with LiNi Co Mn O . In this case, both the energy and material consumption during the proposed Li recovery is significantly decreased compared to traditional methods; furthermore, the proposed method makes full use of H to leach Li . This research is expected to provide new understanding for selectively recovering metal from secondary resources.

关键词: recycling     spent LIBs     selective recovery     hydrothermal treatment    

Migration of ammonium nitrogen in ion-absorbed rare earth soils during and post mining: a column study

《环境科学与工程前沿(英文)》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1702-4

摘要:

● Column experiments with an inclined slope were applied to simulate NH4–N transport.

关键词: Ion-absorbed rare earth     Ammonium nitrogen transport     HYDRUS-2D     Numerical simulation    

Control strategies for disinfection byproducts by ion exchange resin, nanofiltration and their sequential

《环境科学与工程前沿(英文)》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1725-x

摘要:

● Effects of AER adsorption and NF on DBP precursors, DBPs, and TOX were examined.

关键词: Disinfection byproducts     Control     Anion exchange resin     Nanofiltration     Cytotoxicity    

Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery

Tong Zhang, Elie Paillard

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 577-591 doi: 10.1007/s11705-018-1758-z

摘要:

Lithium-ion batteries are a key technology in today’s world and improving their performances requires, in many cases, the use of cathodes operating above the anodic stability of state-of-the-art electrolytes based on ethylene carbonate (EC) mixtures. EC, however, is a crucial component of electrolytes, due to its excellent ability to allow graphite anode operation–also required for high energy density batteries–by stabilizing the electrode/electrolyte interface. In the last years, many alternative electrolytes, aiming at allowing high voltage battery operation, have been proposed. However, often, graphite electrode operation is not well demonstrated in these electrolytes. Thus, we review here the high voltage, EC-free alternative electrolytes, focusing on those allowing the steady operation of graphite anodes. This review covers electrolyte compositions, with the widespread use of additives, the change in main lithium salt, the effect of anion (or Li salt) concentration, but also reports on graphite protection strategies, by coatings or artificial solid electrolyte interphase (SEI) or by use of water-soluble binder for electrode processing as these can also enable the use of graphite in electrolytes with suboptimal intrinsic SEI formation ability.

关键词: lithium-ion     electrolyte     solid electrolyte interphase     additives     high voltage     graphite    

g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

《化学科学与工程前沿(英文)》 2023年 第17卷 第2期   页码 217-225 doi: 10.1007/s11705-022-2214-7

摘要: Aqueous zinc-ion batteries are attracting considerable attention because of their high safety compared with conventional lithium-ion batteries. Manganese-based materials have been widely developed for zinc-ion batteries cathode owning to their low cost, high security and simple preparation. However, the severe volume expansion and poor stability during charging and discharging limit the further development of manganese-based cathodes. Herein, superior α-MnO2@g-C3N4 was successfully prepared for stable zinc-ion batteries (ZIBs) cathode by introducing g-C3N4 nanosheets. Compared with pure α-MnO2, α-MnO2@g-C3N4 has a specific capacity of 298 mAh·g–1 at 0.1 A·g–1. Even at 1 A·g–1, the α-MnO2@g-C3N4 still retains 100 mAh·g–1 (83.4% retention after 5000 cycles), implying its excellent cycling stability. The α-MnO2@g-C3N4-based cathode has the highest energy density (563 Wh·kg–1) and power energy density (2170 W·kg–1). This work provides new avenues for the development of a wider range of cathode materials for ZIBs.

关键词: α-MnO2 hollow nanorods     g-C3N4     heterojunction     aqueous Zn-ion batteries    

Two-phase early prediction method for remaining useful life of lithium-ion batteries based on a neural

《能源前沿(英文)》 doi: 10.1007/s11708-023-0906-4

摘要: Lithium-ion batteries (LIBs) are widely used in transportation, energy storage, and other fields. The prediction of the remaining useful life (RUL) of lithium batteries not only provides a reference for health management but also serves as a basis for assessing the residual value of the battery. In order to improve the prediction accuracy of the RUL of LIBs, a two-phase RUL early prediction method combining neural network and Gaussian process regression (GPR) is proposed. In the initial phase, the features related to the capacity degradation of LIBs are utilized to train the neural network model, which is used to predict the initial cycle lifetime of 124 LIBs. The Pearson coefficient’s two most significant characteristic factors and the predicted normalized lifetime form a 3D space. The Euclidean distance between the test dataset and each cell in the training dataset and validation dataset is calculated, and the shortest distance is considered to have a similar degradation pattern, which is used to determine the initial Dual Exponential Model (DEM). In the second phase, GPR uses the DEM as the initial parameter to predict each test set’s early RUL (ERUL). By testing four batteries under different working conditions, the RMSE of all capacity estimation is less than 1.2%, and the accuracy percentage (AP) of remaining life prediction is more than 98%. Experiments show that the method does not need human intervention and has high prediction accuracy.

关键词: lithium-ion batteries     RUL prediction     double exponential model     neural network     Gaussian process regression (GPR)    

Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

《化学科学与工程前沿(英文)》 2023年 第17卷 第2期   页码 226-235 doi: 10.1007/s11705-022-2198-3

摘要: Prussian blue and its analogs are extensively investigated as a cathode for ammonium-ion batteries. However, they often suffer from poor electronic conductivity. Here, we report a Ni2Fe(CN)6/multiwalled carbon nanotube composite electrode material, which is prepared using a simple coprecipitation approach. The obtained material consists of nanoparticles with sizes 30–50 nm and the multiwalled carbon nanotube embedded in it. The existence of multiwalled carbon nanotube ensures that the Ni2Fe(CN)6/multiwalled carbon nanotube composite shows excellent electrochemical performance, achieving a discharge capacity of 55.1 mAh·g–1 at 1 C and 43.2 mAh·g–1 even at 15 C. An increase in the ammonium-ion diffusion coefficient and ionic/electron conductivity based on kinetic investigations accounts for their high performance. Furthermore, detailed ex situ characterizations demonstrate that Ni2Fe(CN)6/multiwalled carbon nanotube composite offers three advantages: negligible lattice expansion during cycling, stable structure, and the reversible redox couple. Therefore, the Ni2Fe(CN)6/multiwalled carbon nanotube composite presents a long cycling life and high rate capacity. Finally, our study reports a desirable material for ammonium-ion batteries and provides a practical approach for improving the electrochemical performance of Prussian blue and its analogs.

关键词: nickel ferrocyanides     NH4+     electrochemistry     Prussian blue     aqueous ammonium ion batteries    

标题 作者 时间 类型 操作

Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

期刊论文

Preparation and characterization of lithium

Chang WANG,Yanlong ZHAI,Xi WANG,Ming ZENG

期刊论文

Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis

Ying Yan, Peng Huang, Huiping Zhang

期刊论文

Thermal decomposition of poly(ethylene terephthalate)/mesoporous molecular sieve composites

RUN Mingtao, ZHANG Dayu, WU Sizhu, WU Gang

期刊论文

Advancing ion-exchange membranes to ion-selective membranes: principles, status, and opportunities

期刊论文

Alumina modified sodium vanadate cathode for aqueous zinc-ion batteries

期刊论文

Vanadium oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coatingfor high performance zinc-ion batteries

期刊论文

Ion-imprinted silica gel and its dynamic membrane for nickel ion removal from wastewaters

Jiehui Zeng, Jianxian Zeng, Hu Zhou, Guoqing Liu, Zhengqiu Yuan, Jian Jian

期刊论文

Highly selective metal recovery from spent lithium-ion batteries through stoichiometric hydrogen ion

Weiguang Lv, Xiaohong Zheng, Li Li, Hongbin Cao, Yi Zhang, Renjie Chen, Hancheng Ou, Fei Kang, Zhi Sun

期刊论文

Migration of ammonium nitrogen in ion-absorbed rare earth soils during and post mining: a column study

期刊论文

Control strategies for disinfection byproducts by ion exchange resin, nanofiltration and their sequential

期刊论文

Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery

Tong Zhang, Elie Paillard

期刊论文

g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

期刊论文

Two-phase early prediction method for remaining useful life of lithium-ion batteries based on a neural

期刊论文

Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

期刊论文