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期刊论文 10

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2017 6

2015 1

2012 1

2009 1

2008 1

关键词

LED灯具;加速老化测试;中位寿命;滑动平均误差 1

双光子 1

图案化 1

宏量 1

碳点 1

荧光寿命成像 1

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Thermal degradation kinetics and lifetime estimation for polycarbonate/polymethylphenylsilsesquioxane

Jiangbo WANG, Zhong XIN

《化学科学与工程前沿(英文)》 2009年 第3卷 第2期   页码 167-171 doi: 10.1007/s11705-009-0006-y

摘要: The thermal degradation behaviors of polycarbonate/polymethylphenylsilsesquioxane (FRPC) composites were investigated by thermogravimetric analysis (TGA) under isothermal conditions in nitrogen atmosphere. The isothermal kinetics equation was used to describe the thermal degradation process. The results showed that activation energy ( ), in the case of isothermal degradation, was a quick increasing function of conversion (α) for polycarbonate (PC) but was a strong and decreasing function of conversion for FRPC. Under the isothermal condition, the addition of polymethylphenylsilsesquioxane (PMPSQ) retardanted the thermal degradation and enhanced the thermal stability of PC during the early and middle stages of thermal degradation. It also indicated a possible existence of a difference in nucleation, nuclei growth, and gas diffusion mechanism in the thermal degradation process between PC and FRPC. Meanwhile, the addition of PMPSQ influenced the lifetime of PC, but the composite still met the demand in manufacturing and application.

关键词: polycarbonate     polymethylphenylsilsesquioxane     thermal degradation kinetics     activation energy     lifetime    

Full lifetime cost analysis of battery, plug-in hybrid and FCEVs in China in the near future

Zhihua CAI, Xunmin OU, Qian ZHANG, Xiliang ZHANG

《能源前沿(英文)》 2012年 第6卷 第2期   页码 107-111 doi: 10.1007/s11708-012-0182-1

摘要: This paper analyzes the full lifetime cost of battery electric vehicles (BEVs), plug-in hybrid electric vehicles (PHEVs), and fuel cell electric vehicles (FCEVs) in China in the near future. The full lifetime cost comprises the initial and periodic cost of owning and operating the vehicle. Compared with the conventional gasoline vehicles, the full lifetime cost of the BEVs, PHEVs and FCEVs are approximately 1.5, 0.5 and 2.3 times more in the short term, respectively, due to the higher initial costs and higher non-energy-related costs though the fuel costs are lower. The results also suggest that with reasonably anticipatable technological progress in the long term, the lifetime cost of advanced electric vehicles (EVs) can be close to that of gasoline vehicles. It is found that two aspects of action are most important to make BEVs cost-effective: to support technology improvement to decrease the high cost of BEV and to formulate high energy cost of operating the conventional gasoline car. Moreover, it is important to decrease the non-energy operating costs including registration fee, tax rate and etc., of BEVs at the same time.

关键词: electric vehicle (EV)     life time cost     China    

Novel methods by using non-vacuum insulated tubing to extend the lifetime of the tubing

Chenglong ZHOU,Guojin ZHU,Yongxiang XU,Jifei YU,Xiaoliang ZHANG,Hongzhi SHENG

《能源前沿(英文)》 2015年 第9卷 第2期   页码 142-147 doi: 10.1007/s11708-015-0357-7

摘要: The analysis of the failure mechanics, namely hydrogen permeation of vacuum insulated tubing (VIT), indicated that the failure of VIT could be decreased but could not be avoided. To solve this problem, some measures by using non-vacuum materials were proposed and analyzed in this paper. The results show that to fill the tubing with foam-glass beads or high pressure argon may lead to a good performance.

关键词: vacuum insulated tubing     cyclic steam stimulation     insulation material     thermal conductivity     foam-glass     hydrogen permeation    

Multi-functional 3D N-doped TiO

Zijian Cui, Kaiyue Zhang, Guangyu Xing, Yaqing Feng, Shuxian Meng

《化学科学与工程前沿(英文)》 2017年 第11卷 第3期   页码 395-404 doi: 10.1007/s11705-017-1643-1

摘要: Three-dimensional TiO microspheres doped with N were synthesized by a simple single-step solvothermal method and the sample treated for 15 h (hereafter called TMF) was then used as scattering layers in the photoanodes of dye-sensitized solar cells (DSSCs). The TMF was characterized using scanning electron microscopy, high resolution transmission electron microscopy, Brunauer-Emmett-Teller measurements, X-ray diffraction, and X-ray photoelectron spectroscopy. The TMF had a high surface area of 93.2 m ·g which was beneficial for more dye-loading. Five photoanode films with different internal structures were fabricated by printing different numbers of TMF scattering layers on fluorine-doped tin oxide glass. UV-vis diffuse reflection spectra, incident photon-to-current efficiencies, photocurrent-voltage curves and electrochemical impedance spectroscopy were used to investigate the optical and electrochemical properties of these photoanodes in DSSCs. The presence of nitrogen in the TMF changed the TMF microstructure, which led to a higher open circuit voltage and a longer electron lifetime. In addition, the presence of the nitrogen significantly improved the light utilization and photocurrent. The highest photoelectric conversion efficiency achieved was 8.08%, which is much higher than that derived from typical P25 nanoparticles (6.52%).

关键词: DSSCs     N doping     scattering layer     electron lifetime    

SiO2 passivation layer grown by liquid phase deposition for silicon solar cell application

Yanlin CHEN,Sihua ZHONG,Miao TAN,Wenzhong SHEN

《能源前沿(英文)》 2017年 第11卷 第1期   页码 52-59 doi: 10.1007/s11708-016-0429-3

摘要: Surface passivation is one of the primary requirements for high efficient silicon solar cells. Though the current existed passivation techniques are effective, expensive equipments are required. In this paper, a comprehensive understanding of the SiO passivation layer grown by liquid phase deposition (LPD) was presented, which was cost-effective and very simple. It was found that the post-annealing process could significantly enhance the passivation effect of the LPD SiO film. Besides, it was revealed that both chemical passivation and field-effect passivation mechanisms played important roles in outstanding passivation effect of the LPD SiO film through analyzing the minority carrier lifetime and the surface recombination velocity of n-type and p-type silicon wafers. Although the deposition parameters had little influence on the passivation effect, they affected the deposition rate. Therefore, appropriate deposition parameters should be carefully chosen based on the compromise of the deposition rate and fabrication cost. By utilizing the LPD SiO film as surface passivation layer, a 19.5%-efficient silicon solar cell on a large-scale wafer (156 mm × 156 mm) was fabricated.

关键词: Si solar cell     passivation     SiO2     liquid phase deposition     carrier lifetime    

Solid-state-reaction fabrication and properties of a high-doping Nd:YAG transparent laser ceramic

WU Yusong, LI Jiang, PAN Yubai, LIU Wenbin, AN Liqiong, WANG Shiwei, GUO Jingkun

《化学科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 248-252 doi: 10.1007/s11705-008-0048-6

摘要: High-quality neodymium-doped yttrium aluminum garnet (Nd:YAG) transparent ceramic (4.0 mole percent) was fabricated by a solid-state reaction method and vacuum sintering. The microstructure, optical transmittance, spectral properties and laser performance were investigated. The average grain size of the sample is about 10 ?m. The transmittance of a 2.8-mm thick sample reaches 79.5% at the laser wavelength of 1064 nm. The highest absorption peak is centered at 807 nm and the absorption coefficient is 13.9 cm. The absorption coefficient at the laser wavelength is 0.2 cm. The main emission peak is at 1064 nm and the fluorescence lifetime is 102 ?s. A laser diode (808 nm) whose maximum output is about 1000 mW was used as a pump source and an end-pumped laser experiment was performed. The 1064 nm-CW-laser output was obtained and the threshold is 733 mW. With 998 mW of maximum absorbed pump power, a laser output of 17 mW is obtained with a slope efficiency of 6.1%.

关键词: neodymium-doped yttrium     maximum absorbed     microstructure     fluorescence lifetime     threshold    

Statistical analysis of recombination properties of the boron-oxygen defect in p-type Czochralski silicon

Nitin NAMPALLI,Tsun Hang FUNG,Stuart WENHAM,Brett HALLAM,Malcolm ABBOTT

《能源前沿(英文)》 2017年 第11卷 第1期   页码 4-22 doi: 10.1007/s11708-016-0442-6

摘要: This paper presents the application of lifetime spectroscopy to the study of carrier-induced degradation ascribed to the boron-oxygen (BO) defect. Specifically, a large data set of p-type silicon samples is used to investigate two important aspects of carrier lifetime analysis: ① the methods used to extract the recombination lifetime associated with the defect and ② the underlying assumption that carrier injection does not affect lifetime components unrelated to the defect. The results demonstrate that the capture cross section ratio associated with the donor level of the BO defect ( ) vary widely depending on the specific method used to extract the defect-specific recombination lifetime. For the data set studied here, it was also found that illumination used to form the defect caused minor, but statistically significant changes in the surface passivation used. This violation of the fundamental assumption could be accounted for by applying appropriate curve fitting methods, resulting in an improved estimate of (11.90±0.45) for the fully formed BO defect when modeled using the donor level alone. Illumination also appeared to cause a minor, apparently injection-independent change in lifetime that could not be attributed to the donor level of the BO defect alone and is likely related to the acceptor level of the BO defect. While specific to the BO defect, this study has implications for the use of lifetime spectroscopy to study other carrier induced defects. Finally, we demonstrate the use of a unit-less regression goodness-of-fit metric for lifetime data that is easy to interpret and accounts for repeatability error.

关键词: Czochralski silicon     boron-oxygen defect     injection dependent lifetime spectroscopy     goodness-of-fit     repeatability error    

荧光碳点的快速宏量制备及多功能应用 Article

王丹,王志勇,詹求强,蒲源,王洁欣,Neil R. Foster,戴黎明

《工程(英文)》 2017年 第3卷 第3期   页码 402-408 doi: 10.1016/J.ENG.2017.03.014

摘要:

荧光纳米材料在化学传感、生物成像及光电器件等领域具有重要应用前景,其合成方法的研究得到广泛关注。我们采用柠檬酸和乙二胺作为原料,在150 ℃、常压的相对温和条件下,通过“一锅法”反应制备了氮掺杂荧光碳点。所得荧光碳点光学带隙为3.4 eV,在单光子或双光子激发下呈现出明亮的荧光,且荧光发射波长稳定(λ = 450 nm)。基于荧光碳点低细胞毒性和长荧光寿命的优势,实现了荧光碳点作为离体肿瘤细胞(HeLa 细胞) 标记和荧光寿命成像探针的应用,获得了高对比度的荧光寿命成像结果。通过将所得荧光碳点与普通油墨混合制备均匀分散的荧光墨水,可用于普通纸张及其他基材( 如柔性塑料薄膜、纺织品、衣服) 的荧光图案化,为固态荧光传感、荧光防伪标记和可穿戴光电子设备应用研究提供了基础。

关键词: 宏量     碳点     双光子     荧光寿命成像     图案化    

LED灯具温度应力加速老化截止时间的确定 Article

Jian HAO, Lei JING, Hong-liang KE, Yao WANG, Qun GAO, Xiao-xun WANG, Qiang SUN, Zhi-jun XU

《信息与电子工程前沿(英文)》 2017年 第18卷 第10期   页码 1678-1678 doi: 10.1631/FITEE.1500483

摘要: 在LED灯具加速老化过程中,为获得最小截止时间,对其寿命进行快速预估,本文采用5阶滑动平均误差方法分析数据。选用同批次的16个样本,分别进行80℃和85℃应力条件下的加速老化。首先,采用e指数对光通维持率进行拟合,获得每个灯具的加速寿命,进而采用威布尔分布对加速寿命进行拟合,获得中位寿命。其次,采用平均滑动误差方法,可获取不同截止时间下中位寿命预估误差。结果表明:加速老化过程中,存在最小截止时间,该时间可通过滑动平均误差和截止时间的关系确定;当截止时间小于该值时,寿命预估不合理;寿命预估误差随截止时间增加而逐渐减小。对于该类LED灯具,80℃时最小截止时间为1104小时,寿命预估误差为1.15%;85℃时最小截止时间为936小时,寿命预估误差为1.24%。当寿命估计误差约为0.46%时,80 ℃和85 ℃对应的中位寿命分别为7310小时和4598小时。

关键词: LED灯具;加速老化测试;中位寿命;滑动平均误差    

Erratum to: Determination of cut-off time of accelerated aging test under temperature stress for LED lamps

Jian Hao, Lei Jing, Hong-liang Ke, Yao Wang, Qun Gao, Xiao-xun Wang, Qiang Sun, Zhi-jun Xu,sunq@ciomp.ac.cn

《信息与电子工程前沿(英文)》 2017年 第18卷 第10期   页码 1678-1678 doi: 10.1631/FITEE.15e0483

摘要: Erratum to: , 2017 18(8):1197-1204. doi:

关键词: LED lamp     Accelerated aging test     Medium lifetime     Moving average error    

标题 作者 时间 类型 操作

Thermal degradation kinetics and lifetime estimation for polycarbonate/polymethylphenylsilsesquioxane

Jiangbo WANG, Zhong XIN

期刊论文

Full lifetime cost analysis of battery, plug-in hybrid and FCEVs in China in the near future

Zhihua CAI, Xunmin OU, Qian ZHANG, Xiliang ZHANG

期刊论文

Novel methods by using non-vacuum insulated tubing to extend the lifetime of the tubing

Chenglong ZHOU,Guojin ZHU,Yongxiang XU,Jifei YU,Xiaoliang ZHANG,Hongzhi SHENG

期刊论文

Multi-functional 3D N-doped TiO

Zijian Cui, Kaiyue Zhang, Guangyu Xing, Yaqing Feng, Shuxian Meng

期刊论文

SiO2 passivation layer grown by liquid phase deposition for silicon solar cell application

Yanlin CHEN,Sihua ZHONG,Miao TAN,Wenzhong SHEN

期刊论文

Solid-state-reaction fabrication and properties of a high-doping Nd:YAG transparent laser ceramic

WU Yusong, LI Jiang, PAN Yubai, LIU Wenbin, AN Liqiong, WANG Shiwei, GUO Jingkun

期刊论文

Statistical analysis of recombination properties of the boron-oxygen defect in p-type Czochralski silicon

Nitin NAMPALLI,Tsun Hang FUNG,Stuart WENHAM,Brett HALLAM,Malcolm ABBOTT

期刊论文

荧光碳点的快速宏量制备及多功能应用

王丹,王志勇,詹求强,蒲源,王洁欣,Neil R. Foster,戴黎明

期刊论文

LED灯具温度应力加速老化截止时间的确定

Jian HAO, Lei JING, Hong-liang KE, Yao WANG, Qun GAO, Xiao-xun WANG, Qiang SUN, Zhi-jun XU

期刊论文

Erratum to: Determination of cut-off time of accelerated aging test under temperature stress for LED lamps

Jian Hao, Lei Jing, Hong-liang Ke, Yao Wang, Qun Gao, Xiao-xun Wang, Qiang Sun, Zhi-jun Xu,sunq@ciomp.ac.cn

期刊论文