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期刊论文 1

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2020 1

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Effects of solvents and temperature on spherulites of self-assembled phloroglucinol tristearate

Yawen Yao, Sabine Rosenfeldt, Kai Zhang

《化学科学与工程前沿(英文)》 2020年 第14卷 第3期   页码 389-396 doi: 10.1007/s11705-019-1911-3

摘要: Herein, phloroglucinol tristearate (PhgTS) was used to study the crystallization process due to its unique symmetric structure containing a benzene ring and three aliphatic chains. Spherulites of crystallized PhgTS from four solvents under diverse conditions were analyzed in detail and their formation process was studied. Maltese cross is shown by PhgTS spherulites obtained from aprotic solvents via polarized optical microscopy. In comparison, no Maltese cross can be observed from branch-like crystals formed from protic solvents. Independent on the microscaled morphology, lamellae were found to be the basic blocks constructing both PhgTS spherulites and branch-like crystals, which were formed predominantly by stacked PhgTS molecules. Although differential characters of the solvents did not affect the formation of lamellas, the solvents played a crucial role in the formation of self-assembled microscaled morphologies. In particular, the morphologies of spherulites were strongly affected by the concentration of PhgTS solutions, surrounding temperature and evaporation rate of solvents. Generally, a higher concentration of PhgTS led to more homogeneous spherulites, a lower evaporation rate resulted in more compact spherulites, and a higher surrounding temperature generated preferentially more ring-banded spherulites of PhgTS.

关键词: phloroglucinol     tristearate     aprotic and protic solvent     self-assembly     spherulites    

标题 作者 时间 类型 操作

Effects of solvents and temperature on spherulites of self-assembled phloroglucinol tristearate

Yawen Yao, Sabine Rosenfeldt, Kai Zhang

期刊论文