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2008 1

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Tripotassium citrate monohydrate derived carbon nanosheets as a competent assistant to manganese dioxide with remarkable

《化学科学与工程前沿（英文）》 2022年第16卷第3期页码 420-432 doi: 10.1007/s11705-021-2065-7

摘要： Production cost, capacitance, and electrode materials safety are the key factors to be concerned about for supercapacitors. In this work, a type of carbon nanosheets was produced through the carbonization of tripotassium citrate monohydrate and nitric acidification. Subsequently, a well-designed manganese dioxide/carbon nanosheets composite was synthesized through hydrothermal treating. The carbon nanosheets served as the substrate for growing the manganese dioxide, regulating its distribution, and preventing it from inhomogeneous dimensions and severe agglomeration. Many manganese dioxide nanosheets grew vertically on the numerous functional groups generated on the surface of the carbon nanosheets during acidification. The synergistic combination of carbon nanosheets and manganese dioxide tailors the electrochemical performance of the composite, which benefits from the excellent conductivity and stability of carbon nanosheets. The carbon nanosheets derived from tripotassium citrate monohydrate are conducive to the remarkable performance of manganese dioxide/carbon nanosheets electrode. Finally, an asymmetric supercapacitor with active carbon as the cathode and manganese dioxide/carbon nanosheets as the anode was assembled, achieving an outstanding energy density of 54.68 Wh·kg^–1 and remarkable power density of 6399.2 W·kg^–1 superior to conventional lead-acid batteries. After 10000 charge-discharge cycles, the device retained 75.3% of the initial capacitance, showing good cycle stability. Two assembled asymmetric supercapacitors in series charged for 3 min could power a yellow light emitting diode with an operating voltage of 2 V for 2 min. This study may provide valuable insights for applying carbon materials and manganese dioxide in the energy storage field.

关键词： carbon nanosheets manganese dioxide asymmetric supercapacitors energy density power density

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Flow characteristics of single-phase flow in narrow annular channels

ZENG Heyi, SU Guanghui, JIA Dounan

《能源前沿（英文）》 2008年第2卷第4期页码 466-470 doi: 10.1007/s11708-008-0101-7

摘要： The characteristics of single-phase flow in narrow annular channels were analyzed and theoretical model was proposed. Based on the present model, the theoretical calculation was performed to predict the flow characteristics for the developed flow in narrow annuli with the gap sizes of 1.0, 1.5 and 2.0 mm, respectively. The results were in good agreement with the experimental data. In addition, the gap size of narrow annuli has great impact upon the flow characteristics. The decrease of gap size reduces friction factor. The higher the Reynolds number, the more remarkable the effect of gap size upon friction coefficient during single-phase flowing through narrow annular channels. The effect of gap size upon friction coefficient is dependent on the Reynolds number, and will decrease with the decrease of the Reynolds number.

关键词： narrow annuli remarkable mm developed friction