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Synthesis of hydroxymethylfurfural and furfural from hardwood and softwood pulp using ferric sulphate

Agneev Mukherjee, Guillermo Portillo-Perez, Marie-Josée Dumont

《化学科学与工程前沿(英文)》 2019年 第13卷 第3期   页码 531-542 doi: 10.1007/s11705-019-1814-3

摘要: Hydroxymethylfurfural (HMF) and furfural are promising chemicals for the creation of a bio-based economy. The development of an inexpensive catalytic system for converting cellulosic biomass into these chemicals is an important step in this regard. Ferric sulphate is a common, cheap and non-toxic Lewis acid that has been used to catalyse reactions such as wood depolymerisation. In this work, ferric sulphate was used to help the production of HMF and furfural from hardwood and softwood pulps. It was found that for hardwood pulp, the use of ferric sulphate alone gave a maximum HMF yield of 31.6 mol-%. The addition of the ionic liquid [BMIM]Cl or HCl as co-catalysts did not lead to an increase in the yields obtained. A prior decationisation step, however, resulted in HMF yields of 50.4 mol-%. Softwood pulp was harder to depolymerise than hardwood, with a yield of 28.7% obtained using ferric sulphate alone. The maximum HMF yield from softwood, 37.9 mol-%, was obtained using a combination of ferric sulphate and dilute HCl. It was thus concluded that ferric sulphate is a promising catalyst for HMF synthesis from cellulosic biomass.

关键词: 5-hydroxymethylfurfural     hardwood     softwood     ferric sulphate     biorefinery    

Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

《化学科学与工程前沿(英文)》 2007年 第1卷 第4期   页码 327-331 doi: 10.1007/s11705-007-0059-8

摘要: In recent years, resins prepared via molecular imprinting technology have received considerable attention owing to their recognition and selective adsorption. This paper deals with the comparative investigation between a uranyl sulphate imprinted ion-exchange based on self-assembling molecular imprinting technology and two kinds of commercial uranium resins (the medium pore resin D263 and strong base resin 201×7). The studies were focused on their kinetics performance, adaptability toward pH, and performance of saturation and elution in laboratory-scale column. The results show that the imprinted ion exchange resin has the fast kinetics, high adaptability toward pH, and good adsorption and elution performance.

关键词: saturation     molecular imprinting     imprinting technology     adaptability     commercial    

硫酸盐岩与碳酸盐岩复合岩溶发育机理与工程效应研究

卢耀如,张凤娥

《中国工程科学》 2008年 第10卷 第4期   页码 4-10

摘要:

硫酸盐岩和碳酸盐岩常共同分布,以往多是分别研究其岩溶发育。文章主要从自然条件上研究两者复合岩溶发育的机理,探讨了化学岩溶作用过程和生物岩溶作用的机理。复合岩溶中,陷落柱是很重要的一个特征。文章也探索了复合岩溶作用中,有关岩溶地下水的水质情况。

关键词: 硫酸盐岩     碳酸盐岩     复合岩溶     陷落柱     地下水水质    

Valorization of agro-industrial fruit peel waste to fluorescent nanocarbon sensor: Ultrasensitive detection of potentially hazardous tropane alkaloid

《环境科学与工程前沿(英文)》 2022年 第16卷 第3期 doi: 10.1007/s11783-021-1461-z

摘要:

• Transformation of agro-industrial waste to value-added material via green chemistry.

关键词: Agro-industrial waste     Orange peel     Valorization     Nanodiamond-like carbon     Atropine sulphate     Fluorescence sensing    

A red water occurrence in drinking water distribution systems caused by changes in water source in Beijing, China: mechanism analysis and control measures

ZHANG Xiaojian,MI Zilong,WANG Yang,LIU Shuming,NIU Zhangbin,LU Pinpin,WANG Jun,GU Junnong,CHEN Chao

《环境科学与工程前沿(英文)》 2014年 第8卷 第3期   页码 417-426 doi: 10.1007/s11783-013-0558-4

摘要: A red water phenomenon occurred in several communities few days after the change of water source in Beijing, China in 2008. In this study, the origin of this problem, the mechanism of iron release and various control measures were investigated. The results indicated that a significant increase in sulphate concentration as a result of the new water source was the cause of the red water phenomenon. The mechanism of iron release was found that the high-concentration sulphate in the new water source disrupted the stable shell of scale on the inner pipe and led to the release of iron compounds. Experiments showed that the iron release rate in the new source water within pipe section was over 11-fold higher than that occurring within the local source water. The recovery of tap water quality lasted several months despite ameliorative measures being implemented, including adding phosphate, reducing the overall proportion of the new water source, elevating the pH and alkalinity, and utilizing free chlorine as a disinfectant instead of chloramine. Adding phosphate was more effective and more practical than the other measures. The iron release rate was decreased after the addition of 1.5 mg·L orthophosphate- P, tripolyphosphate-P and hexametaphosphate-P by 68%, 83% and 87%, respectively. Elevating the pH and alkalinity also reduced the iron release rate by 50%. However, the iron release rate did not decreased after replacing chloramine by 0.5–0.8 mg·L of free chlorine as disinfectant.

关键词: iron release     drinking water distribution system     sulphate     phosphate     red water control     water quality stability    

标题 作者 时间 类型 操作

Synthesis of hydroxymethylfurfural and furfural from hardwood and softwood pulp using ferric sulphate

Agneev Mukherjee, Guillermo Portillo-Perez, Marie-Josée Dumont

期刊论文

Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

期刊论文

硫酸盐岩与碳酸盐岩复合岩溶发育机理与工程效应研究

卢耀如,张凤娥

期刊论文

Valorization of agro-industrial fruit peel waste to fluorescent nanocarbon sensor: Ultrasensitive detection of potentially hazardous tropane alkaloid

期刊论文

A red water occurrence in drinking water distribution systems caused by changes in water source in Beijing, China: mechanism analysis and control measures

ZHANG Xiaojian,MI Zilong,WANG Yang,LIU Shuming,NIU Zhangbin,LU Pinpin,WANG Jun,GU Junnong,CHEN Chao

期刊论文