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Micronization of curcumin with biodegradable polymer by supercritical anti-solvent using micro swirl

Kimthet Chhouk, Wahyudiono, Hideki Kanda, Shin-Ichro Kawasaki, Motonobu Goto

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 184-193 doi: 10.1007/s11705-017-1678-3

摘要： Curcumin is a hydrophobic polyphenol compound exhibiting a wide range of biological activities such as anti-inflammatory, anti-bacterial, anti-fungal, anti-carcinogenic, anti-human immunodeficiency virus, and anti-microbial activity. In this work, a swirl mixer was employed to produce the micronized curcumin with polyvinylpyrrolidone (PVP) by the supercritical anti-solvent process to improve the bioavailability of curcumin. The effects of operating parameters such as curcumin/PVP ratio, feed concentration, temperature, pressure, and CO flow rate were investigated. The characterization and solubility of particles were determined by using scanning electron microscopy, Fourier Transform Infrared spectroscopy, and ultra-violet-visible spectroscopy. The result shows that the optimal condition for the production of curcumin/PVP particles is at curcumin/PVP ratio of 1:30, feed concentration of 5 mg·mL , temperature of 40 °C, pressure of 15 MPa, and CO flow rate of 15 mL·min . Moreover, the dissolution of curcumin/PVP particles is faster than that of raw curcumin.

关键词： micronization curcumin polyvinylpyrrolidone supercritical anti-solvent swirl mixer

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Influence of mass air flow ratio on gas-particle flow characteristics of a swirl burner in a 29 MW pulverized

Rong YAN, Zhichao CHEN, Shuo GUAN, Zhengqi LI

《能源前沿（英文）》 2021年第15卷第1期页码 68-77 doi: 10.1007/s11708-020-0697-9

摘要： In a gas/particle two-phase test facility, a three-component particle-dynamics anemometer was used to measure the characteristics of gas/particle two-phase flows in a 29 megawatt (MW) pulverized coal industrial boiler equipped with a new type of swirling pulverized coal burner. The distributions of three-dimensional gas/particle velocity, particle volume flux, and particle size distribution were measured under different working conditions. The mean axial velocity and the particle volume flux in the central region of the burner outlet were found to be negative. This indicated that a central recirculation zone was formed in the center of the burner. In the central recirculation zone, the absolute value of the mean axial velocity and the particle volume flux increased when the external secondary air volume increased. The size of the central reflux zone remained stable when the air volume ratio changed. Along the direction of the jet, the peak value formed by the tertiary air gradually moved toward the center of the burner. This tertiary air was mixed with the peak value formed by the air in the adiabatic combustion chamber after the cross-section of / = 0.7. Large particles were concentrated near the wall area, and the particle size in the recirculation zone was small.

关键词： industrial pulverized coal boiler swirl burner air/particle flow particle dynamic analyzer (PDA)

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Control of peak pressures of an HCCI engine under varying swirl and operating parameters

T. KARTHIKEYA SHARMA,G. AMBA PRASAD RAO,K. MADHU MURTHY

《能源前沿（英文）》 2016年第10卷第3期页码 337-346 doi: 10.1007/s11708-016-0401-2

摘要： The major advantages of homogeneous charge compression ignition (HCCI) are high efficiency in combination with low NO -emissions. However, one of the major challenges with HCCI is the control of higher peak pressures which may damage the engine, limiting the HCCI engine life period. In this paper, an attempt is made to analyze computationally the effect of induction swirl in controlling the peak pressures of an HCCI engine under various operating parameters. A single cylinder 1.6 L reentrant piston bowl diesel engine is chosen. For computational analysis, the ECFM-3Z model of STAR –CD is considered because it is suitable for analyzing the combustion processes in SI and CI engines. As an HCCI engine is a hybrid version of SI and CI engines, the ECFM-3Z model with necessary modifications is used to analyze the peak pressures inside the combustion chamber. The ECFM-3Z model for HCCI mode of combustion is validated with the existing literature to make sure that the results obtained are accurate. Numerical experiments are performed to study the effect of varying properties like speed of the engine, piston bowl geometry, exhaust gas recirculation (EGR) and equivalence ratio under different swirl ratios in controlling the peak pressures inside the combustion chamber. The results show that the swirl ratio has a considerable impact on controlling the peak pressures of HCCI engine. A reduction in peak pressures are observed with a swirl ratio of 4 because of reduced in cylinder temperatures. The combined effect of four operating parameters, i.e., the speed of the engine, piston bowl geometry, EGR, and equivalence ratio with swirl ratios suggest that lower intake temperatures, reentrant piston bowl, higher engine speeds and higher swirl ratios are favorable in controlling the peak pressures.

关键词： HCCI engine ECFM-3Z Swirl ratio peak pressures engine speed piston bowl geometry

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柴油机进气涡流自动试验系统设计与评价方法

于吉超,刘德新,冯洪庆

《中国工程科学》 2007年第9卷第5期页码 85-90

摘要：

涡流是影响柴油机经济性与排放特性的关键参数，在柴油机设计与改进过程一般通过气道稳态试验台进行测量与评价。介绍了一种自动化程度较高的气道稳态试验台的设计方案，可以自动控制气门升程和试验压力，适用于生产线。论述和比较了当前常用的测量与分析方法，并在试验台上进行了相应试验研究。结果表明，即使在相同试验条件下，不同测量方法或分析方法也会有不同的结果，在对不同试验台测量结果进行比较时，需要注意由于方法不同所引起的差异。

关键词：涡流柴油机叶片风速仪涡流动量计稳态试验台

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Spray characteristics of high-pressure swirl injector fueled with alcohol

WANG Xibin, CHEN Wansheng, GAO Jian, JIANG Deming, HUANG Zuohua

《能源前沿（英文）》 2007年第1卷第1期页码 105-112 doi: 10.1007/s11708-007-0012-z

摘要： The spray characteristics of methanol and ethanol with high-pressure swirl injector were explored experimentally and numerically. Experimental results show that the spray characteristics of methanol and ethanol had displayed the same trends as that of gasoline. Under the low back-pressure ambient conditions, the spray behavior exhibited a hollow cone with wide spray angle and initial spray slug at the tip, while the spray presented a solid cone in the case of high back-pressure. Vortexes in the opposite direction existed in the rear part of the spray under low back-pressure ambient conditions while the vortexes formed in the middle part under high back-pressure ambient conditions. Experiments also showed that methanol had the largest cone angle, while ethanol and gasoline presented almost the same cone angle. Simulation results indicated that methanol and ethanol had a slightly larger Sauter mean diameter (SMD) than that of gasoline with swirl injector. The SMD profile of methanol coincided well with that of ethanol under low back-pressure ambient conditions, but displayed a slightly larger value under high back-pressure due to fuel evaporation. Numerical simulation could successfully demonstrate the spray characteristics of high-pressure swirl injector for methanol and ethanol fuels.

关键词： low back-pressure diameter initial spray hollow middle

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Entropy production analysis of swirling diffusion combustion processes

Deodat MAKHANLALL, Linhua LIU,

《能源前沿（英文）》 2010年第4卷第3期页码 326-332 doi: 10.1007/s11708-009-0058-1

摘要： A critical factor in the design of combustion systems for optimum fuel economy and emission performance lies in adequately predicting thermodynamic irreversibilities associated with transport and chemical processes. The objective of this study is to map these irreversibilities in terms of entropy production for methane combustion. The numerical solution of the combustion process is conducted with the help of a Fluent 6.1.22 computer code, and the volumetric entropy production rate due to chemical reaction, viscous dissipation, and mass and heat transfer are calculated as post-processed quantities with the computed data of the reaction rates, fluid velocity, temperature and radiative intensity. This paper shows that radiative heat transfer, which is an important source of entropy production, cannot be omitted for combustion systems. The study is extended by conducting a parametric investigation to include the effects of wall emissivity, optical thickness, swirl number, and Boltzmann number on entropy production. Global entropy production rates decrease with the increase in swirl velocity, wall emissivity and optical thickness. Introducing swirling air into the combustion system and operations with the appropriate Boltzmann number reduces the irreversibility affected regions and improves energy utilization efficiency.

关键词： entropy-based design radiation transfer swirl magnussen combustion-model