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δN-stable isotope analysis of NH: An overview on analytical measurements, source sampling and its source apportionment

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1414-6

摘要：

• Challenges in sampling of NH₃ sources for d¹⁵N analysis are highlighted.

关键词： Aerosol ammonium Atmospheric gaseous ammonia Isotope fingerprinting Isotope-based source apportionment Ammonia gas-to-particle conversion

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Development and application of a random walk model of atmospheric diffusion in the emergency response

CHI Bing, LI Hong, FANG Dong

《能源前沿（英文）》 2007年第1卷第2期页码 195-201 doi: 10.1007/s11708-007-0025-7

摘要： Plume concentration prediction is one of the main contents of radioactive consequence assessment for early emergency response to nuclear accidents. Random characteristics of atmospheric diffusion itself was described, a random walk model of atmospheric diffusion (Random Walk) was introduced and compared with the Lagrangian puff model (RIMPUFF) in the nuclear emergency decision support system (RODOS) developed by the European Community for verification. The results show the concentrations calculated by the two models are quite close except that the plume area calculated by Random Walk is a little smaller than that by RIMPUFF. The random walk model for atmospheric diffusion can simulate the atmospheric diffusion in case of nuclear accidents, and provide more actual information for early emergency and consequence assessment as one of the atmospheric diffusion module of the nuclear emergency decision support system.

关键词： RODOS concentration prediction information nuclear RIMPUFF

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Abundance and distribution of ammonia-oxidizing archaea in Tibetan and Yunnan plateau agricultural soils

Kun DING,Xianghua WEN,Liang CHEN,Daishi HUANG,Fan FEI,Yuyang LI

《环境科学与工程前沿（英文）》 2014年第8卷第5期页码 693-702 doi: 10.1007/s11783-014-0635-3

摘要： As low oxygen and high ultraviolet (UV) exposure might significantly affect the microbial existence in plateau, it could lead to a specialized microbial community. To determine the abundance and distribution of ammonia-oxidizing archaea (AOA) in agricultural soil of plateau, seven soil samples were collected respectively from farmlands in Tibet and Yunnan cultivating the wheat, highland-barley, and colza, which are located at altitudes of 3200–3800 m above sea level. Quantitative PCR (q-PCR) and clone library targeting on gene were used to quantify the abundances of AOA and ammonia-oxidizing bacteria (AOB), and characterize the community structures of AOA in the samples. The number of AOA cells (9.34 × 10 –2.32 × 10 g soil) was 3.86–21.84 times greater than that of AOB cells (6.91 × 10 –1.24 × 10 g soil) in most of the samples, except a soil sample cultivating highland-barley with an AOA/AOB ratio of 0.90. Based Kendall’s correlation coefficient, no remarkable correlation between AOA abundance and the environmental factor was observed. Additionally, the diversities of AOA community were affected by total nitrogen and organic matter concentration in soils, suggesting that AOA was probably sensitive to several environmental factors, and could adjust its community structure to adapt to the environmental variation while maintaining its abundance.

关键词： ammonia-oxidizing archaea ammonia-oxidizing bacteria quantitative PCR clone library plateau

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Effects of exogenous acylated homoserine lactones on biofilms in biofilters for gaseous toluene treatment

《环境科学与工程前沿（英文）》 2023年第17卷第2期 doi: 10.1007/s11783-023-1617-0

摘要：

● Biofilm formation was enhanced by exogenous AHLs.

关键词： Quorum sensing AHLs Biofilter Biofilm formation

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Heat and mass transfer of ammonia-water in falling film evaporator

Xianbiao BU, Weibin MA, Huashan LI

《能源前沿（英文）》 2011年第5卷第4期页码 358-366 doi: 10.1007/s11708-011-0161-y

摘要： To investigate the performance of heat and mass transfer of ammonia-water during the process of falling film evaporation in vertical tube evaporator, a mathematical model of evaporation process was presented, the solution of which that needed a coordinate transformation was based on stream function. The computational results from the mathematical model were validated with experimental data. Subsequently, a series of parameters, such as velocity, film thickness and concentration, etc., were obtained from the mathematical model. Calculated results show that the average velocity and the film thickness change dramatically at the entrance region when <100 mm, while they vary slightly with the tube length in the fully developed region when >100 mm. The average concentration of the solution reduces along the tube length because of evaporation, but the reducing tendency becomes slow. It can be concluded that there is an optimalβrelationship between the tube length and the electricity generated. The reason for the bigger concentration gradient in the direction is that the smooth tube is chosen in the calculation. It is suggested that the roll-worked enhanced tube or other enhanced tube can reduce the concentration gradient in the film thickness direction and enhance the heat and mass transfer rate.

关键词： falling film evaporation ammonia-water heat and mass transfer

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Heterogeneous reaction mechanism of gaseous HNO

Nan ZHAO,Qingzhu ZHANG,Wenxing WANG

《环境科学与工程前沿（英文）》 2016年第10卷第5期 doi: 10.1007/s11783-016-0836-z

摘要： We studied the heterogeneous reaction mechanism of gaseous HNO with solid NaCl. HCl is released from heterogeneous reactions between gaseous HNO and solid NaCl. Water molecules induce surface reconstruction of NaCl to facilitate the reaction. Sea salt particles containing NaCl are among the most abundant particulate masses in coastal atmosphere. Reactions involving sea salt particles potentially generate Cl radicals, which are released into coastal atmosphere. Cl radicals play an important role in the nitrogen and O cycles, sulfur chemistry and particle formation in the troposphere of the polluted coastal regions. This paper aimed at the heterogeneous reaction between gaseous HNO and solid NaCl. The mechanism was investigated by density functional theory (DFT). The results imply that water molecules induce the surface reconstruction, which is essential for the heterogeneous reaction. The surface reconstruction on the defective (710) surface has a barrier of 10.24 kcal·mol and is endothermic by 9.69 kcal·mol , whereas the reconstruction on the clean (100) surface has a barrier of 18.46 kcal·mol and is endothermic by 12.96 kcal·mol . The surface reconstruction involved in water-adsorbed (710) surface is more energetically favorable. In comparison, water molecules adsorbed on NaCl (100) surface likely undergo water diffusion or desorption. Further, it reveals that the coordination number of the Cl is reduced after the surface reconstruction, which assists Cl to accept the proton from HNO . HCl is released from heterogeneous reactions between gaseous HNO and solid NaCl and can react with OH free radicals to produce atomic Cl radicals. The results will offer further insights into the impact of gaseous HNO on the air quality of the coastal areas.

关键词： Seasalt particles NaCl HNO₃ Heterogeneous reaction Reaction mechanism Density functional theory

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Simulation on thermodynamic state of ammonia carbonation at low temperature and low pressure

Jingcai ZHAO, Xingfu SONG, Ze SUN, Jianguo YU

《化学科学与工程前沿（英文）》 2013年第7卷第4期页码 447-455 doi: 10.1007/s11705-013-1370-1

摘要： This study on thermodynamic property of NH -CO -H O system provided the basic data for ammonia carbonation. Simulations on vapor-liquid equilibrium (VLE) of ammonia carbonation with different physical properties were discussed in NH -H O and NH -CO -H O systems, respectively. The results indicated that at low temperature (303.15 K–363.15 K) and pressure (0.1–0.4 MPa), the PR (Peng-Robinson) equation was suitable for the description of the thermodynamic state in NH -H O system. NRTL (Non-Random-Two-Liquid) series models were selected for NH -CO -H O mixed electrolyte solution system. VLE data regression results showed that NRTL series models were suitable for describing thermodynamic properties of NH -CO -H O system, because average relative error fitting with each model was about 1%. As an asymmetric electrolytes model in NRTL model, E–NRTLRK (Electrolyte NRTL Redlich Kwong) could most accurately fit VLE data of NH -CO -H O system, with fitting error less than 1%. In the extent temperature range of 273.15 K–363.15 K, the prediction of product component using E-NRTLRK model for ammonia carbonation agreed well with the data reported in literature.

关键词： vapor-liquid equilibrium activity coefficient carbon dioxide ammonia NRTL

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Microwave-assisted catalytic oxidation of gaseous toluene with a Cu-Mn-Ce/cordierite honeycomb catalyst

Longli Bo, Shaoyuan Sun

《化学科学与工程前沿（英文）》 2019年第13卷第2期页码 385-392 doi: 10.1007/s11705-018-1738-3

摘要： A novel Cu-Mn-Ce/cordierite honeycomb catalyst was prepared by an incipient wetness method and the catalyst was characterized. The active ingredients were present as various spinel species of Cu, Mn and Ce oxides with different valences and they were unevenly dispersed over the surface of the catalyst. The catalytic oxidation of gaseous toluene was primarily investigated using a fixed bed reactor under microwave heating in the continuous flow mode. Under the optimal conditions of 6.7 wt-% loading of the active component, a bed temperature of 200°C, a flow rate of 0.12 m ·h and an initial concentration of toluene of 1000 mg·m , the removal and mineralization efficiencies of toluene were 98% and 70%, respectively. Thus the use of the microwave effectively improved the oxidation of toluene and this is attributed to dipole polarization and hotspot effects. After four consecutive cycles (a total of 1980 min), the Cu-Mn-Ce/cordierite catalyst still exhibited excellent catalytic activity and structural stability, and the toluene removal was higher than 90%. This work demonstrates the possibility of treating volatile organic compounds in exhaust gases by microwave-assisted catalytic oxidation.

关键词： microwave catalytic oxidation toluene Cu-Mn-Ce/cordierite mineralization

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Design guidelines for urea hydrolysers for ammonia demand of the SCR DENOX project in coal-fired power

Peng ZHENG, Xuan YAO, Wei ZHENG

《能源前沿（英文）》 2013年第7卷第1期页码 127-132 doi: 10.1007/s11708-012-0225-7

摘要： Ammonia is highly volatile and will present substantial environmental and operation hazards when leaking into the air. However, ammonia is the most common reactant in the DENOX project to eliminate NO in the flue gas. The storage and transportation of liquid ammonia has always been a dilemma of the power plant. Urea is a perfect substitute source for ammonia in the plant. Urea hydrolysis technology can easily convert urea into ammonia with low expense. Presently, there is still no self-depended mature urea hydrolysis technology for the DENOX project in China; therefore, this paper proposes several guidelines to design the urea hydrolyser by theoretical analysis. Based on theoretical analysis, a simulation model is built to simulate the chemical reaction in the urea hydrolyser and is validated by the operational data of the commercial hydrolyser revealed in the literature. This paper endeavors to propose suggestions and guidelines to develop domestically urea hydrolysers in China.

关键词： urea hydrolyser ammonia selective catalytic reduction (SCR)

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Emission factors of gaseous carbonaceous species from residential combustion of coal and crop residue

Qin WANG, Chunmei GENG, Sihua LU, Wentai CHEN, Min SHAO

《环境科学与工程前沿（英文）》 2013年第7卷第1期页码 66-76 doi: 10.1007/s11783-012-0428-5

摘要： Experiments were performed to measure the emission factors ( s) of gaseous carbonaceous species, such as CO , CO, CH , and non-methane volatile organic compounds (NMVOCs), from the combustion of five types of coal of varying organic maturity and two types of biomass briquettes under residential burning conditions. Samples were collected in stainless steel canisters and 2,4-dinitrophenylhydrazine (DNPH) cartridges and were analyzed by GC–FID/MS and HPLC, respectively. The s from crop residue briquette burning were generally higher than those from coals, with the exception of CO . The dominant NMVOC species identified in coal smoke were carbonyls (41.7%), followed by C2 unsaturated hydrocarbons (29.1%) and aromatics (12.1%), while C2 unsaturated hydrocarbons were the dominant species (68.9%) emitted from the combustion of crop residue briquettes, followed by aromatics (14.4%). A comparison of burning normal crop residues in stoves and the open field indicated that briquettes emitted a larger proportion of ethene and acetylene. Both combustion efficiency and coal organic maturity had a significant impact on NMVOC s from burning coal: NMVOC emissions increased with increasing coal organic maturity but decreased as the combustion efficiency improved. Emissions from the combustion of crop residue briquettes from stoves occurred mainly during the smoldering process, with low combustion efficiency. Therefore, an improved stove design to allow higher combustion efficiency would be beneficial for reducing emissions of carbonaceous air pollutants.

关键词： residential combustion coal crop residue briquette emission factors gaseous carbonaceous species

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Enhancement on the ammonia oxidation capacity of ammonia-oxidizing archaeon originated from wastewater

《环境科学与工程前沿（英文）》 2021年第15卷第5期 doi: 10.1007/s11783-020-1375-1

摘要：

• AOA’s ammonia oxidizing capacity was enhanced under moderate magnetic field.

关键词： Ammonia-oxidizing archaeon Ammonia oxidation Magnetic field Magnetotaxis Heredity

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Is atmospheric oxidation capacity better in indicating tropospheric O formation?

《环境科学与工程前沿（英文）》 2022年第16卷第5期 doi: 10.1007/s11783-022-1544-5

摘要：

● This study summarizes and evaluates different approaches that indicate O₃ formation.

关键词： O₃ AOC O₃ formation regime

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Spatial and Temporal Variations in the Atmospheric Age Distribution of Primary and Secondary Inorganic

Xiaodong Xie,Qi Ying,Hongliang Zhang,Jianlin Hu,

《工程（英文）》 doi: 10.1016/j.eng.2022.03.013

摘要： The aging timescale of particles is a key parameter in determining their impacts on air quality, human health, and climate. In this study, a one-year simulation of the age distributions of the primary and secondary inorganic fine particulate matter (PM2.5) components was conducted over China using an age-resolved Community Multiscale Air Quality (CMAQ) model. The results indicate that primary PM2.5 (PPM) and ammonium mainly originate from fresh local emissions, with approximately 60%–80% concentrated in 0–24 h age bins in most of China throughout the year. The average age is ∼15–25 h in most regions in summer, but increases to 40–50 h in southern region of China and the Sichuan Basin (SCB) in winter. Sulfate is more aged than PPM, indicating an enhanced contribution from regional transport. Aged sulfate with atmospheric age > 48 h account for 30%–50% of total sulfate in most regions and seasons, and the concentrations in the > 96 h age bin can reach up to 15 µg·m−3 in SCB during winter. Dramatic seasonal variations occur in the Yangtze River Delta, Pearl River Delta, and SCB, with highest average age of 60–70 h in winter and lowest of 40–45 h in summer. The average age of nitrate is 20–30 h in summer and increases to 40–50 h in winter. The enhanced deposition rate of nitric acid vapor combined with the faster chemical reaction rate of nitrogen oxides leads to a lower atmospheric age in summer. Additionally, on pollution days, the contributions of old age bins (> 24 h) increase notably for both PPM and secondary inorganic aerosols in most cities and seasons, suggesting that regional transport plays a vital role during haze events. The age information of PM2.5, provided by the age-resolved CMAQ model, can help policymakers design effective emergent emission control measures to eliminate severe haze episodes.

关键词： Atmospheric age PM 2.5 CMAQ model Control strategy

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Experimental study on capturing CO 2 greenhouse gas by mixture of ammonia and soil

Ying WU, Yifei WANG, Qinghua ZENG, Xin GONG, Zunhong YU,

《化学科学与工程前沿（英文）》 2009年第3卷第4期页码 468-473 doi: 10.1007/s11705-009-0257-7

摘要： This paper presents our study on removal of carbon dioxide (CO) greenhouse gas emissions by using the mixture of ammonia and soil. CO capture capacity using this method is 15% higher than the sum of ammonia chemical absorption capacity and soil physical adsorption capacity. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) are utilized to study this synergism. The removal effect is not only reflected in ammonia chemical reaction with CO. CO can also be absorbed by ammonium bicarbonate (NHHCO) crystal, which is the main component of the product, or wrapped in the pore of the crystal or packed in the gap between the crystal and the soil. CO can be permanently deposited as carbonated minerals in the subsoil earth layers.

关键词： electron microscopy product physical adsorption capacity spectroscopy

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Effect of fine solid particles on absorption rate of gaseous CO

LU Sumin, MA Youguang, SHEN Shuhua, ZHU Chunying

《化学科学与工程前沿（英文）》 2008年第2卷第4期页码 368-372 doi: 10.1007/s11705-008-0067-3

摘要： The influence of the properties of solid particles in slurry on the absorption of CO in the slurry was investigated in a stirred thermostatic reactor. The absorption experiments were carried out in three different slurries consisting of water, cyclohexane and soybean oil, respectively, and three kinds of solid particles (active carbon, active alumina and silica gel) were incorporated into each of the above mentioned slurries separately. The experimental results show that the active carbon particles could enhance the absorption rate of gaseous CO in the aqueous slurry, while in the cyclohexane slurry, active carbon particles indicated no the absorption enhancement effect. However, it was observed that the active alumina and silica gel particles could enhance the absorption rate of CO in the cyclohexane slurry. These phenomena indicate that the solid particles, which could enhance the gaseous CO absorption rate, should possess two properties simultaneously, i.e. they rejected the solvent and had higher adsorption capacity for the solute. The experimental results also show that, as for those solid particles which could enhance the gas absorption rate, the enhancement increased quickly with the increase of solid concentration in slurry at first, and then reached a constant value gradually. It was also found that the enhancement factor was related to the coverage fraction of solid particles on the gas-liquid interface, and due to the reduction of surface fraction with increasing stirred speed, the enhancement factor decreased.

关键词： constant influence soybean solvent concentration

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标题作者时间类型操作

δN-stable isotope analysis of NH: An overview on analytical measurements, source sampling and its source apportionment

期刊论文

Development and application of a random walk model of atmospheric diffusion in the emergency response

CHI Bing, LI Hong, FANG Dong

期刊论文

Abundance and distribution of ammonia-oxidizing archaea in Tibetan and Yunnan plateau agricultural soils

Kun DING,Xianghua WEN,Liang CHEN,Daishi HUANG,Fan FEI,Yuyang LI

期刊论文

Effects of exogenous acylated homoserine lactones on biofilms in biofilters for gaseous toluene treatment

期刊论文

Heat and mass transfer of ammonia-water in falling film evaporator

Xianbiao BU, Weibin MA, Huashan LI

期刊论文

Heterogeneous reaction mechanism of gaseous HNO

Nan ZHAO,Qingzhu ZHANG,Wenxing WANG

期刊论文

Simulation on thermodynamic state of ammonia carbonation at low temperature and low pressure

Jingcai ZHAO, Xingfu SONG, Ze SUN, Jianguo YU

期刊论文

Microwave-assisted catalytic oxidation of gaseous toluene with a Cu-Mn-Ce/cordierite honeycomb catalyst

Longli Bo, Shaoyuan Sun

期刊论文

Design guidelines for urea hydrolysers for ammonia demand of the SCR DENOX project in coal-fired power

Peng ZHENG, Xuan YAO, Wei ZHENG

期刊论文

Emission factors of gaseous carbonaceous species from residential combustion of coal and crop residue

Qin WANG, Chunmei GENG, Sihua LU, Wentai CHEN, Min SHAO

期刊论文

Enhancement on the ammonia oxidation capacity of ammonia-oxidizing archaeon originated from wastewater

期刊论文

Is atmospheric oxidation capacity better in indicating tropospheric O formation?

期刊论文

Spatial and Temporal Variations in the Atmospheric Age Distribution of Primary and Secondary Inorganic

Xiaodong Xie,Qi Ying,Hongliang Zhang,Jianlin Hu,

期刊论文

Experimental study on capturing CO 2 greenhouse gas by mixture of ammonia and soil

Ying WU, Yifei WANG, Qinghua ZENG, Xin GONG, Zunhong YU,

期刊论文

Effect of fine solid particles on absorption rate of gaseous CO

LU Sumin, MA Youguang, SHEN Shuhua, ZHU Chunying

期刊论文

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