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Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

《环境科学与工程前沿(英文)》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1697-x

摘要:

● Titanium-based flow-through electrode achieved high Cr(VI) reduction efficiency.

关键词: Flow-through electrode     Hexavalent chromium     Heavy metals     Neural network     Artificial intelligence    

Intensifying electrified flow-through water treatment technologies via local environment modification

《环境科学与工程前沿(英文)》 2024年 第18卷 第6期 doi: 10.1007/s11783-024-1829-Y

摘要:

● Modifying local environment can intensify the performance of flow-through electrodes.

关键词: Point-of-use water treatment     Electrified membrane     Advection-enhanced mass transport     Water decontamination and disinfection     Emerging contaminants    

biofilm reactor for effective and energy-efficient azo dye degradation: the synergistic effect of MnO/Ti flow-through

《环境科学与工程前沿(英文)》 2023年 第17卷 第4期 doi: 10.1007/s11783-023-1649-5

摘要:

● MnO x /Ti flow-through anode was coupled with the biofilm-attached cathode in ECBR.

关键词: Azo dye removal     Electrocatalytic biofilm reactor     Anodic oxidation     Electricity-stimulated biodegradation     Energy consumption    

Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

《化学科学与工程前沿(英文)》 2011年 第5卷 第2期   页码 252-257 doi: 10.1007/s11705-010-1010-y

摘要: Xylan of corn stover was pretreated with 1%, 2% and 3% (w/w) sulfuric acid at relatively low temperatures (90°C, 95°C and 100°C) in a dilute acid cycle spray flow-through reactor (DCF). The hydrolysis of xylan to its monomeric xylose was modeled by a series of first-order reactions. Both biphasic and Saeman hydrolysis models were applied to fit the experimental data. The results confirmed that the kinetic data of xylan hydrolysis fitted a first-order irreversible reaction model and the experimental data. The reaction rates of xylose monomer formation and degradation were sensitive to catalyst concentration and temperature. Higher catalyst concentration and lower reaction temperature result in high xylose yield. The activation energy for xylose formation and degradation were determined to be 112.9 and 101.0 kJ·mol , respectively. Over 90% theoretical xylose obtained from corn stover can be used to produce ethanol, xylitol and fumaric acid by fermentation.

关键词: corn stover     xylan hydrolysis     biphasic model     Saeman model     cycle spray     kinetics    

Electrocatalytic reduction of nitrate using Pd-Cu modified carbon nanotube membranes

《环境科学与工程前沿(英文)》 2023年 第17卷 第4期 doi: 10.1007/s11783-023-1640-1

摘要:

● Pd-Cu modified CNT membranes were prepared successfully by electrodeposition method.

关键词: Pd-Cu modified CNT membrane     Nitrate reduction     Flow-through     Electrodeposition     Electrocatalytic reduction    

三维孔道助催化剂体系下Fe2+/Fe3+循环的可持续高级氧化过程 Article

Weiyang Lv, Hao Li, Jinhui Wang, Lixin Wang, Zenglong Wu, Yuge Wang, Wenkai Song, Wenkai Cheng, Yuyuan Yao

《工程(英文)》 2024年 第36卷 第5期   页码 262-273 doi: 10.1016/j.eng.2023.06.010

摘要:

Realizing fast and continuous generation of reactive oxygen species (ROSs) via iron-based advanced oxidation processes (AOPs) is significant in the environmental and biological fields. However, current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect, giving rise to the sluggish Fe2+/Fe3+ cycle and low dynamic concentration of Fe2+ for ROS production. Herein, we present a three-dimensional (3D) macroscale co-catalyst functionalized with MoS2 to achieve ultra-efficient Fe2+ regeneration (equilibrium Fe2+ ratio of 82.4%) and remarkable stability (more than 20 cycles) via a circulating flow-through process. Unlike the conventional batch-type reactor, experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode, initiated by the convection-enhanced mass/charge transfer for Fe2+ reduction and then strengthened by MoS2-induced flow rotation for sufficient reactant mixing, is crucial for oxidant activation and subsequent ROS generation. Strikingly, the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation efficiency. Our findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology, especially in large-scale complex wastewater treatment.

关键词: Advanced oxidation processes     3D co-catalyst     Flow-through mode     Enhanced mass transfer     Complex wastewater treatment    

Self-supported copper-based gas diffusion electrodes improve the local CO concentration for efficient electrochemical CO reduction

《化学科学与工程前沿(英文)》 2024年 第18卷 第3期 doi: 10.1007/s11705-024-2392-6

摘要: Electrochemical CO2 reduction is a sustainable approach in green chemistry that enables the production of valuable chemicals and fuels while mitigating the environmental impact associated with CO2 emissions. Despite its several advantages, this technology suffers from an intrinsically low CO2 solubility in aqueous solutions, resulting in a lower local CO2 concentration near the electrode, which yields lower current densities and restricts product selectivity. Gas diffusion electrodes (GDEs), particularly those with tubular architectures, can solve these issues by increasing the local CO2 concentration and triple-phase interface, providing abundant electroactive sites to achieve superior reaction rates. In this study, robust and self-supported Cu flow-through gas diffusion electrodes (FTGDEs) were synthesized for efficient formate production via electrochemical CO2 reduction. They were further compared with traditional Cu electrodes, and it was found that higher local CO2 concentration due to improved mass transfer, the abundant surface area available for the generation of the triple-phase interface, and the porous structure of Cu FTGDEs enabled high formate Faradaic efficiency (76%) and current density (265 mA·cm–2) at –0.9 V vs. reversible hydrogen electrode (RHE) in 0.5 mol·L–1 KHCO3. The combined phase inversion and calcination process of the Cu FTGDEs helped maintain a stable operation for several hours. The catalytic performance of the Cu FTGDEs was further investigated in a non-gas diffusion configuration to demonstrate the impact of local gas concentration on the activity and performance of electrochemical CO2 reduction. This study demonstrates the potential of flow-through gas-diffusion electrodes to enhance reaction kinetics for the highly efficient and selective reduction of CO2, offering promising applications in sustainable electrochemical processes.

关键词: CO2 electroreduction     flow-through delivery     hollow fiber structure     local concentration     formate    

A hybrid fuel cell for water purification and simultaneously electricity generation

《环境科学与工程前沿(英文)》 2023年 第17卷 第1期 doi: 10.1007/s11783-023-1611-6

摘要:

● A novel hybrid fuel cell (F-HFC) was fabricated.

关键词: Flow-through field     Hybrid fuel cell     Polyoxometalates     Water purification     Electricity generation    

Numerical study of internal flow field and flow passage improvement of an inlet particle separator

Florian PAOLI, Tong WANG

《能源前沿(英文)》 2011年 第5卷 第4期   页码 386-397 doi: 10.1007/s11708-011-0156-8

摘要: By performing gas flow field numerical simulations for several inlet Reynolds numbers (from 2 × 10 to 9 × 10 ) and byflow ratios (from 10% to 20%), the present study has proposed to improve the flow passage of an inlet particle separator. An adjacent objective of the study is to lower pressure losses of the inlet particle separator (IPS). No particle has been included in the gas flow for a -epsilon turbulence model. The velocity distribution in different sections and the pressure coefficient along the duct have been analyzed, which indicates that there exist important low-velocity regions and vortices in the separation area. Therefore, the profile of streamlines along the original passage has been considered. This profile illustrated a vacuum region in the same area. All investigations suggest that the separation area is the most critical one for fulfilling the objective on pressure losses limitation. Then the flow passage improvement method has focused on the separation area. An improved shape has been designed in order to suit smoothly to the streamlines in this region. Similar numerical studies as those for the original shape have been conducted on this improved shape, confirming some considerable enhancements compared with the original shape. The significant vortices which appear in the original shape reduce in amount and size. Besides, pressure losses are greatly decreased in both outlets (up to 30% for high Reynolds number) and the flow is uniform at the main outlet. Subsequent engineering surveys could rely on expressions obtained for in both outlets which extend the pressure losses for a wide range of inlet Reynolds numbers. As a result, the numerical calculations demonstrate that the flow passage improvement method applied in this study has succeeded in designing a shape which enhances the flow behavior.

关键词: streamlines     pressure losses     flow passage improvement     inlet particle separator (IPS)    

LARGE-SCALE FARMING BENEFITS SOIL ACIDIFICATION ALLEVIATION THROUGH IMPROVED FIELD MANAGEMENT IN BANANA

《农业科学与工程前沿(英文)》 2023年 第10卷 第1期   页码 48-60 doi: 10.15302/J-FASE-2022475

摘要:

● Large farms had the highest average yield and the least yield variation.

关键词: plantations     land transfer     large-scale farming     nutrient management     soil acidification    

The computational fluid dynamic modeling of downwash flow field for a six-rotor UAV

Yongjun ZHENG, Shenghui YANG, Xingxing LIU, Jie WANG, Tomas NORTON, Jian CHEN, Yu TAN

《农业科学与工程前沿(英文)》 2018年 第5卷 第2期   页码 159-167 doi: 10.15302/J-FASE-2018216

摘要: The downwash flow field of the multi-rotor unmanned aerial vehicle (UAV), formed by propellers during operation, has a significant influence on the deposition, drift and distribution of droplets as well as the spray width of the UAV for plant protection. To study the general characteristics of the distribution of the downwash airflow and simulate the static wind field of multi-rotor UAVs in hovering state, a 3D full-size physical model of JF01-10 six-rotor plant protection UAV was constructed using SolidWorks. The entire flow field surrounding the UAV and the rotation flow fields around the six rotors were established in UG software. The physical model and flow fields were meshed using unstructured tetrahedral elements in ANSYS software. Finally, the downwash flow field of UAV was simulated. With an increased hovering height, the ground effect was reduced and the minimum current velocity increased initially and then decreased. In addition, the spatial proportion of the turbulence occupied decreased. Furthermore, the appropriate operational hovering height for the JF01-10 is considered to be 3 m. These results can be applied to six-rotor plant protection UAVs employed in pesticide spraying and spray width detection.

关键词: CFD simulation     downwash flow field     numerical analysis     plant protection     six-rotor UAV    

Investigation into the influence of diffuser stagger angles on the flow field and performance of a centrifugal

XI Guang, DING Haiping, YUAN Minjian, ZHANG Chunmei, ZHOU Li

《能源前沿(英文)》 2007年 第1卷 第3期   页码 290-294 doi: 10.1007/s11708-007-0041-7

摘要: The performance graphs of a centrifugal compressor under different diffuser stagger angles were measured, and the influence of different stagger angles of vanes on the stage performance as well as flow field was investigated numerically. The results show that the performance graph shifts when the diffuser stagger angle is altered; the influence of different stagger angles of vanes on the flow field inside the centrifugal compressor is great. Large scale vortices appear on the diffuser vane under larger incidence. An optimal diffuser stagger angle should exist at a specified flow rate to make the characteristic of the flow optimized. The incidence corresponding to the highest efficiency is not 0º at the design condition.

关键词: diffuser stagger     incidence     different stagger     flow     centrifugal compressor    

Numerical simulation of air flow field in high-pressure fan with splitter blades

LI Jianfeng, LU Junfu, ZHANG Hai, LIU Qing, YUE Guangxi

《能源前沿(英文)》 2008年 第2卷 第4期   页码 438-442 doi: 10.1007/s11708-008-0085-3

摘要: For a deeper understanding of the flow characteristics in the high-pressure centrifugal blower of a fan of Model 9-26 with splitter blades, a three dimensional (3-D) numerical simulation of air flows in the fan was conducted with FLUENT software. The standard - turbulent model and unstructured grids were used. The computational fluid dynamics (CFD) results showed that the performance of a fan could be improved by adding the splitter blades in the channel among the leaf blades. Under operational conditions, with the presence of splitter blades, the air flow rate of the fan increased about 5% and the total pressure at the outlet of the fan increased about 10% on average. It was also found that the length of the splitter blades affected the air flow and pressure drop. There is an optimal value for the length. The simulation results provide helpful information for improving the fan performance.

关键词: splitter     numerical simulation     presence     unstructured     operational    

Analytical solutions of three-dimensional contaminant transport in uniform flow field in porous media

Hongtao WANG, Huayong WU

《环境科学与工程前沿(英文)》 2009年 第3卷 第1期   页码 112-128 doi: 10.1007/s11783-008-0067-z

摘要: The purpose of this study is to present a library of analytical solutions for the three-dimensional contaminant transport in uniform flow field in porous media with the first-order decay, linear sorption, and zero-order production. The library is constructed using Green's function method (GFM) in combination with available solutions. The library covers a wide range of solutions for various conditions. The aquifer can be vertically finite, semi-infinitive or infinitive, and laterally semi-infinitive or infinitive. The geometry of the sources can be of point, line, plane or volumetric body; and the source release can be continuous, instantaneous, or by following a given function over time. Dimensionless forms of the solutions are also proposed. A computer code FlowCAS is developed to calculate the solutions. Calculated results demonstrate the correctness of the presented solutions. The library is widely applicable to solve contaminant transport problems of one- or multiple- dimensions in uniform flow fields.

关键词: solution library     contaminant transport     analytical solution     dispersion and advection     porous media     type curve     Green's function method (GFM)    

广域电磁法和拟流场法精细探测技术——以井工一矿水害探测为例 Article

何继善

《工程(英文)》 2018年 第4卷 第5期   页码 667-675 doi: 10.1016/j.eng.2018.09.006

摘要:

井工一矿存在严重的老空区和水害。以往的单一勘探方法,如地震法、直流电法、音频大地电磁法、可控源音频大地电磁法、瞬变电磁法等,均未能探明老采空区范围和水害赋存情况。为了解决这个难题,联合采用广域电磁法和井- 地拟流场法的三位一体立体式探测技术,并利用三维反演电阻率资料精准获取富水区域和采空区的位置,确定了不同层位水的连通性,为井工一矿的安全生产提供了可靠的技术保障。结果合理、成效显著,释放了近4 km2 的可采面积。

关键词: 广域电磁法     拟流场法     采空区     富水性     精细探测    

标题 作者 时间 类型 操作

Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

期刊论文

Intensifying electrified flow-through water treatment technologies via local environment modification

期刊论文

biofilm reactor for effective and energy-efficient azo dye degradation: the synergistic effect of MnO/Ti flow-through

期刊论文

Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

期刊论文

Electrocatalytic reduction of nitrate using Pd-Cu modified carbon nanotube membranes

期刊论文

三维孔道助催化剂体系下Fe2+/Fe3+循环的可持续高级氧化过程

Weiyang Lv, Hao Li, Jinhui Wang, Lixin Wang, Zenglong Wu, Yuge Wang, Wenkai Song, Wenkai Cheng, Yuyuan Yao

期刊论文

Self-supported copper-based gas diffusion electrodes improve the local CO concentration for efficient electrochemical CO reduction

期刊论文

A hybrid fuel cell for water purification and simultaneously electricity generation

期刊论文

Numerical study of internal flow field and flow passage improvement of an inlet particle separator

Florian PAOLI, Tong WANG

期刊论文

LARGE-SCALE FARMING BENEFITS SOIL ACIDIFICATION ALLEVIATION THROUGH IMPROVED FIELD MANAGEMENT IN BANANA

期刊论文

The computational fluid dynamic modeling of downwash flow field for a six-rotor UAV

Yongjun ZHENG, Shenghui YANG, Xingxing LIU, Jie WANG, Tomas NORTON, Jian CHEN, Yu TAN

期刊论文

Investigation into the influence of diffuser stagger angles on the flow field and performance of a centrifugal

XI Guang, DING Haiping, YUAN Minjian, ZHANG Chunmei, ZHOU Li

期刊论文

Numerical simulation of air flow field in high-pressure fan with splitter blades

LI Jianfeng, LU Junfu, ZHANG Hai, LIU Qing, YUE Guangxi

期刊论文

Analytical solutions of three-dimensional contaminant transport in uniform flow field in porous media

Hongtao WANG, Huayong WU

期刊论文

广域电磁法和拟流场法精细探测技术——以井工一矿水害探测为例

何继善

期刊论文