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ITZ microstructure, thickness, porosity and its relation with compressive and flexural strength of cementmortar; influence of cement fineness and water/cement ratio

《结构与土木工程前沿（英文）》 2022年 第16卷 第2期   页码 191-201 doi: 10.1007/s11709-021-0792-y

摘要： A new insight into the interfacial transition zone (ITZ) in cement mortar specimens (CMSs) that is influenced by cement fineness is reported. The importance of cement fineness in ITZ characterizations such as morphology and thickness is elucidated by backscattered electron images and by consequences to the compressive (Fc) and flexural strength (Ff), and porosity at various water/cement ratios. The findings indicate that by increasing the cement fineness the calcium silicate hydrate formation in the ITZ is favored and that this can refine the pore structures and create a denser and more homogeneous microstructure. By increasing cement fineness by about 25% of, the ITZ thickness of CMSs was reduced by about 30% and Fc was increased by 7%–52% and Ff by 19%–40%. These findings illustrate that the influence of ITZ features on the mechanical strength of CMSs is mostly related to the cement fineness and ITZ microstructure.

关键词： cement fineness     interfacial transition zone     compressive and flexural strength    

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Effect of fineness of ash on pozzolanic properties and acid resistance of sugarcane bagasse ash replacedcement mortars

Shan E ALI; Rizwan AZAM; Muhammad Rizwan RIAZ; Mohamed ZAWAM

《结构与土木工程前沿（英文）》 2022年 第16卷 第10期   页码 1287-1300 doi: 10.1007/s11709-022-0872-7

摘要： This paper addresses the potential use of Sugar Cane Bagasse Ash (SCBA) as a pozzolanic material for partial cement replacement in concrete mixtures. Cement mortars containing SCBA having five different particle size distributions at a replacement rate of 20% by weight were used to study the chemical and physical pozzolanic properties of SCBA. The durability of SCBA replaced mortars was also evaluated. SCBA with 0% retained on sieve No. 325 was used to replace 20% by weight of cement and create mortar specimens that were subjected to sulfuric acid attack of varying concentrations (1%−3% by weight of water). The tested samples were observed to check visual distortion, mass loss, and compressive strength loss at 1, 7, 14, 28, and 56 d of acidic exposure, and the results were compared to those for the control sample, that was lime water cured, at the same ages. The SCBA sets were found to meet the requirements for pozzolan class N specified by ASTM C 618. Mortars containing SCBA with 0% or 15% retention produced better compressive strength than the control mortars after 28 d. Additionally, X-ray fluorescence and X-ray diffraction analysis showed that the SCBA had favorable chemical properties for a pozzolanic material. Furthermore, SCBA replaced samples at all ages showed improved resistance against acidic attack relative to that of the control mortars. Maximum deterioration was seen for 3% concentrated solution. This study’s findings demonstrated that SCBA with an appropriate fineness could be used as a pozzolanic material, consistently with ASTM C 618.

关键词： durability     cement replacement     sugarcane bagasse ash     fineness of ash     pozzolanic properties     mortar acid resistance    

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Extending blending proportions of ordinary Portland cement and calcium sulfoaluminate cement blends:

《结构与土木工程前沿（英文）》 2021年 第15卷 第5期   页码 1249-1260 doi: 10.1007/s11709-021-0770-4

摘要： This study extended blending proportion range of ordinary Portland cement (OPC) and calcium sulfoaluminate (CSA) cement blends, and investigated effects of proportions on setting time, workability, and strength development of OPC-CSA blend-based mixtures. Thermogravimetric analysis (TGA) and X-ray diffraction (XRD) were conducted to help understand the performance of OPC-CSA blend-based mixtures. The setting time of the OPC-CSA blends was extended, and the workability was improved with increase of OPC content. Although the early-age strength decreased with increase of OPC content, the strength development was still very fast when the OPC content was lower than 60% due to the rapid formation and accumulation of ettringite. At 2 h, the OPC-CSA blend-based mortars with OPC contents of 0%, 20%, 40%, and 60% achieved the unconfined compressive strength (UCS) of 17.5, 13.9, 9.6, and 5.0 MPa, respectively. The OPC content had a negligible influence on long-term strength. At 90 d, the average UCS of the OPC-CSA blend-based mortars was 39.2 ± 1.7 MPa.

关键词： calcium sulfoaluminate cement     cement blends     hydration reaction     setting     workability     compressive strength    

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Study of bond strength between various grade of Ordinary Portland Cement (OPC) and Portland PozzolaneCement (PPC) mixes and different diameter of TMT bars by using pullout test

A D POFALE, S P WANJARI

《结构与土木工程前沿（英文）》 2013年 第7卷 第1期   页码 39-45 doi: 10.1007/s11709-013-0193-y

摘要： Since last two decades, the Portland Pozzolane Cement (PPC) is extensively used in structural concrete. But, till to date, a few literature is available on bond strength of concrete using PPC mixes. There are many literatures available on bond strength of concrete mixes using Ordinary Portland Cement (OPC). Hence, a comparative study was conducted on bond strength between OPC and PPC mixes. In the present investigation, total 24 samples consisting of M20, M35 and M50 grades of concrete and 16 and 25 mm diameter of TMT bar were tested for 7 and 28 days. The pullout bond test was conducted on each specimen as per IS: 2770-1967/1997 [1] and the results were observed at 0.25 mm slip at loaded end called as critical bond stress and at maximum bond load called as maximum bond stress. It was observed that the critical bond strength of PPC mixes is 10% higher than OPC mixes. Whereas, marginal improvement was noticed in maximum bond strength of PPC mixes. Hence, based on these findings, it could be concluded that development length for PPC mixes could be reduced by 10% as compared with same grade of OPC mixes.

关键词： bond strength     Portland Pozzolane Cement (PPC) concrete     Ordinary Portland Cement (OPC) concrete     bond between concrete and steel     pullout test     development length    

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An extended numerical model of the first exothermic peak for three dimensional printed cement-based materials

《结构与土木工程前沿（英文）》 2024年 第18卷 第1期   页码 80-88 doi: 10.1007/s11709-024-1036-8

摘要： The first exothermic peak of cement-based material occurs a few minutes after mixing, and the properties of three dimensional (3D) printed concrete, such as setting time, are very sensitive to this. Against this background, based on the classical Park cement exothermic model of hydration, we propose and construct a numerical model of the first exothermic peak, taking into account the proportions of C3S, C3A and quicklime in particular. The calculated parameters are calibrated by means of relevant published exothermic test data. It is found that this developed model offers a good simulation of the first exothermic peak of hydration for C3S and C3A proportions from 0 to 100% of cement clinker and reflects the effect of quicklime content at 8%–10%. The unique value of this research is provision of an important computational tool for applications that are sensitive to the first exothermic peak of hydration, such as 3D printing.

关键词： 3D printed cement-based materials     cement hydration     the first exothermic peak     liquid quick-setting agent     numerical model    

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Autogenous healing mechanism of cement-based materials

《结构与土木工程前沿（英文）》 2023年 第17卷 第6期   页码 948-963 doi: 10.1007/s11709-023-0960-3

摘要： Autogenous self-healing is the innate and fundamental repair capability of cement-based materials for healing cracks. Many researchers have investigated factors that influence autogenous healing. However, systematic research on the autogenous healing mechanism of cement-based materials is lacking. The healing process mainly involves a chemical process, including further hydration of unhydrated cement and carbonation of calcium oxide and calcium hydroxide. Hence, the autogenous healing process is influenced by the material constituents of the cement composite and the ambient environment. In this study, different factors influencing the healing process of cement-based materials were investigated. Scanning electron microscopy and optical microscopy were used to examine the autogenous healing mechanism, and the maximum healing capacity was assessed. Furthermore, detailed theoretical analysis and quantitative detection of autogenous healing were conducted. This study provides a valuable reference for developing an improved healing technique for cement-based composites.

关键词： autogenous healing     cement-based materials     healing mechanism     aggregation effect    

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Research review of the cement sand and gravel (CSG) dam

Xin CAI, Yingli WU, Xingwen GUO, Yu MING

《结构与土木工程前沿（英文）》 2012年 第6卷 第1期   页码 19-24 doi: 10.1007/s11709-012-0145-y

摘要： The cement sand and gravel (CSG) dam is a new style of dam that owes the advantages both of the concrete faced rock-fill dam (CRFD) and roller compacted concrete (RCC) gravity dam, because of which it has attracted much attention of experts home and abroad. At present, some researches on physic-mechanical property of CSG material and work behavior of CSG dam have been done. This paper introduces the development and characteristics of CSG dam systematically, and summarizes the progress of the study on basic tests, constitutive relation of CSG material and numerical analysis of CSG dam, in addition, indicates research and application aspect of the dam.

关键词： cement sand and gravel (CSG) dam     cement sand and gravel (CSG) material     research review    

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Experimental study and field application of calcium sulfoaluminate cement for rapid repair of concrete

Yanhua GUAN, Ying GAO, Renjuan SUN, Moon C. WON, Zhi GE

《结构与土木工程前沿（英文）》 2017年 第11卷 第3期   页码 338-345 doi: 10.1007/s11709-017-0411-0

摘要： The fast-track repair of deteriorated concrete pavement requires materials that can be placed, cured, and opened to the traffic in a short period. Type III cement and Calcium Sulfoaluminate (CSA) cement are the most commonly used fast-setting hydraulic cement (FSHC). In this study, the properties of Type III and CSA cement concrete, including compressive strength, coefficient of thermal expansion (CTE) and shrinkage were evaluated. The test results indicate that compressive strength of FSHC concrete increased rapidly at the early age. CSA cement concrete had higher early-age and long term strength. The shrinkage of CSA cement concrete was lower than that of Type III cement concrete. Both CSA and Type III cement concrete had similar CTE values. Based on the laboratory results, the CSA cement was selected as the partial-depth rapid repair material for a distressed continuously reinforced concrete pavement. The data collected during and after the repair show that the CSA cement concrete had good short-term and long-term performances and, therefore, was suitable for the rapid repair of concrete pavement.

关键词： Calcium Sulfoaluminate (CSA) cement     Type III cement     coefficient of thermal expansion (CTE)     shrinkage     rapid repair    

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Mechanical properties and microstructure of multilayer graphene oxide cement mortar

《结构与土木工程前沿（英文）》 2021年 第15卷 第4期   页码 1058-1070 doi: 10.1007/s11709-021-0747-3

摘要： This study reports on the effects of multilayer graphene oxide (MGO) on compressive strength, flexural strength, and microstructure of cement mortar. The cement mortar was prepared with type P. II. 52.5 Portland cement, standard sand, and MGO. Four mixes were prepared with inclusion of MGO (0%, 0.02%, 0.04%, and 0.06% by weight of cement). The testing result shows that the compressive of GO-cement mortar increased by 4.84%–13.42%, and the flexural strength increased by 4.37%–8.28% at 3 d. GO-cement mortar’s compressive strength and flexural strength at 7 d increased by 3.84%–12.08% and 2.54%–13.43%, respectively. MGO made little contribution to the increases of compressive strength and flexural strength of cement mortar at 28 d. The results of X-ray diffraction (XRD), scanning electron microscope (SEM), and nitrogen (N2) adsorption/desorption tests show that the types of hydration products and crystal grain size did not change after adding MGO. Still, it can help to improve the microstructure of the cement mortar via regulating hydration products and can provide more condensed cores to accelerate hydration. Furthermore, the regulating action of MGO for the microstructure of cement mortar at an early age was better than that at 28 d.

关键词： graphene oxide     cement     mortar     mechanical properties     microstructure    

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Multiscale mechanical modeling of hydrated cement paste under tensile load using the combined DEM-MD

Yue HOU, Linbing WANG

《结构与土木工程前沿（英文）》 2017年 第11卷 第3期   页码 270-278 doi: 10.1007/s11709-017-0408-8

摘要： In this paper, a combined DEM-MD method is proposed to simulate the crack failure process of Hydrated Cement Paste (HCP) under a tensile force. A three-dimensional (3D) multiscale mechanical model is established using the combined Discrete Element Method (DEM)-Molecular Dynamics (MD) method in LAMMPS (Large-scale Atomic/Molecular Massively Parallel Simulator). In the 3D model, HCP consists of discrete particles and atoms. Simulation results show that the combined DEM-MD model is computationally efficient with good accuracy in predicting tensile failures of HCP.

关键词： hydrated cement paste     multiscale     MD simulation     DEM    

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Silicon carbide waste as a source of mixture materials for cement mortar

Zhengwu Jiang, Qiang Ren, Haoxin Li, Qing Chen

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0974-y

摘要： This paper presents an investigation of the feasibility of recycling silicon carbide waste (SCW) as a source of mixture materials in the production of cement mortar. Mortars with SCW were prepared by replacing different amounts of cement with SCW, and the properties of the resulting mortars, such as the fluidity, strength and shrinkage, were studied in this work. Thermogravimetry-differential scanning calorimetry and scanning electron microscopy were employed to understand the reasons for the property changes of the mortars. The results indicate that SCW decreases the initial and 1-h fluidity of fresh mortar but improves the loss of fluidity. The mortar with SCW exhibits a lower strength at 3 d and 7 d but a higher strength at 28 d and 56 d compared to the control. The shrinkage rate of cement mortar with SCW shows an obvious decrease as the replacement ratio increases. In addition, the content of calcium hydroxide in hardened paste also shows that SCW has some impact on the hydration of the cement-SCW system. The microstructures of the hardened paste also show evidence for a later strength change of mortar containing SCW. This work provides a strategic reference for possibly applying SCW as a mixture material in the production of cement mortar.

关键词： Silicon carbide waste     Cement mortar     Fluidity     Strength     Shrinkage    

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The stress relaxation of cement clinkers under high temperature

Xiufang WANG,Yiwang BAO,Xiaogen LIU,Yan QIU

《机械工程前沿（英文）》 2015年 第10卷 第4期   页码 413-417 doi: 10.1007/s11465-015-0357-7

摘要：

The energy consumption of crushing is directly affected by the mechanical properties of cement materials. This research provides a theoretical proof for the mechanism of the stress relaxation of cement clinkers under high temperature. Compression stress relaxation under various high temperatures is discussed using a specially developed load cell, which can measure stress and displacement under high temperatures inside an autoclave. The cell shows that stress relaxation dramatically increases and that the remaining stress rapidly decreases with an increase in temperature. Mechanical experiments are conducted under various temperatures during the cooling process to study the changes in the grinding resistance of the cement clinker with temperature. The effects of high temperature on the load-displacement curve, compressive strength, and elastic modulus of cement clinkers are systematically studied. Results show that the hardening phenomenon of the clinker becomes apparent with a decrease in temperature and that post-peak behaviors manifest characteristics of the transformation from plasticity to brittleness. The elastic modulus and compressive strength of cement clinkers increase with a decrease in temperature. The elastic modulus increases greatly when the temperature is lower than 1000 °C. The compressive strength of clinkers increases by 73.4% when the temperature drops from 1100 to 800 °C.

关键词： stress relaxation     high temperature     cement clinker     compression     elastic modulus    

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利用GPS数据资料调查昭阳湖洪滩区沉积物的细度和含水量 Article

Mutiara Syifa, Prima Riza Kadavi, Sung Jae Park, Chang-Wook Lee

《工程（英文）》 2021年 第7卷 第2期   页码 252-259 doi: 10.1016/j.eng.2020.12.011

摘要：

昭阳湖是韩国最大的湖泊，与江原道的春川市、杨口郡和麟蹄郡接壤。作为环境资源，昭阳湖被广泛用于水电、防洪和供水。为此，本文调查了昭阳湖洪滩区，并对该地区的沉积物进行了分析。文中利用GPS数据和航空摄影技术监测了昭阳湖洪滩区的沉积物。为了确保采样位置测量的准确性，我们比较了来自三个GPS单元的数据。在三个地点采集了沉积物样本：两个地点在洪滩区的东部平原地区；一个地点在西部地区。总共收集了8个样本：其中在东部采样点采集了三个样本，采集深度以每10 cm的间隔采集到30 cm的深度。在西部采样点采集了两个样本，采集深度分别为10 cm和30 cm。收集样品后分析了颗粒大小和含水量的垂直趋势和水平趋势。沉积物样品的大小从粗粒到极粗粒，呈负斜率趋势分布，这表明溃口有东移的趋势。洪滩区东侧的含水量高，有发生溃口的可能性，且东侧发生溃口的概率比西侧高。这项研究结果表明，通过对颗粒细度、含水量、泥沙沉积量和泥沙去除率的分析，可以了解和预测昭阳湖的溃口运动方向和泥沙分布情况。

关键词： 昭阳湖     砂粒细度指数     含水量     GPS数据     数字表面模型    

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Properties of cement grout modified with ultra-fine slag

Sowmini GOPINATHAN, K B ANAND

《结构与土木工程前沿（英文）》 2018年 第12卷 第1期   页码 58-66 doi: 10.1007/s11709-017-0383-0

摘要： The purpose of the study is to obtain a cement grout with improved performance. The grout mixes of the present study contain cement, ultra-fine slag (UFS), super plasticizer and water. Properties like flowability, bleeding, compressive strength and shrinkage of cement grouts have been studied. Rheological parameters were also studied in order to explain the grout workability. The results show that, cement replacement with slag in grouts could reduce bleeding substantially without affecting the workability of the mixes. Introduction of slag enhanced the compressive strength and reduced shrinkage reasonably. Ultra-fine slag can be used as a supplementary cementitious material in cementitious grouts in order to improve the grout behavior.

关键词： cement grout     ultra-fine slag     flowability     bleeding     viscosity    

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Recovery of waste heat in cement plants for the capture of CO

Ruifeng DONG, Zaoxiao ZHANG, Hongfang LU, Yunsong YU

《化学科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 104-111 doi: 10.1007/s11705-011-1166-0

摘要： Large amounts of energy are consumed during the manufacturing of cement especially during the calcination process which also emits large amounts of CO . A large part of the energy used in the making of cement is released as waste heat. A process to capture CO by integrating the recovery and utilization of waste heat has been designed. Aspen Plus software was used to calculate the amount of waste heat and the efficiency of energy utilization. The data used in this study was based on a dry process cement plant with a 5-stage preheater and a precalciner with a cement output of 1 Mt/y. According to the calculations: 1) the generating capacity of the waste heat recovery system is 4.9 MW. 2) The overall CO removal rate was as high as 78.5%. 3) The efficiency of energy utilization increased after the cement producing process was retrofitted with this integrated design.

关键词： cement industry     waste heat     recovery     utilization     CO2 removal    

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标题 作者 时间 类型 操作

ITZ microstructure, thickness, porosity and its relation with compressive and flexural strength of cementmortar; influence of cement fineness and water/cement ratio

期刊论文

Effect of fineness of ash on pozzolanic properties and acid resistance of sugarcane bagasse ash replacedcement mortars

Shan E ALI; Rizwan AZAM; Muhammad Rizwan RIAZ; Mohamed ZAWAM

期刊论文

Extending blending proportions of ordinary Portland cement and calcium sulfoaluminate cement blends:

期刊论文

Study of bond strength between various grade of Ordinary Portland Cement (OPC) and Portland PozzolaneCement (PPC) mixes and different diameter of TMT bars by using pullout test

A D POFALE, S P WANJARI

期刊论文

An extended numerical model of the first exothermic peak for three dimensional printed cement-based materials

期刊论文

Autogenous healing mechanism of cement-based materials

期刊论文

Research review of the cement sand and gravel (CSG) dam

Xin CAI, Yingli WU, Xingwen GUO, Yu MING

期刊论文

Experimental study and field application of calcium sulfoaluminate cement for rapid repair of concrete

Yanhua GUAN, Ying GAO, Renjuan SUN, Moon C. WON, Zhi GE

期刊论文

Mechanical properties and microstructure of multilayer graphene oxide cement mortar

期刊论文

Multiscale mechanical modeling of hydrated cement paste under tensile load using the combined DEM-MD

Yue HOU, Linbing WANG

期刊论文

Silicon carbide waste as a source of mixture materials for cement mortar

Zhengwu Jiang, Qiang Ren, Haoxin Li, Qing Chen

期刊论文

The stress relaxation of cement clinkers under high temperature

Xiufang WANG,Yiwang BAO,Xiaogen LIU,Yan QIU

期刊论文

利用GPS数据资料调查昭阳湖洪滩区沉积物的细度和含水量

Mutiara Syifa, Prima Riza Kadavi, Sung Jae Park, Chang-Wook Lee

期刊论文

Properties of cement grout modified with ultra-fine slag

Sowmini GOPINATHAN, K B ANAND

期刊论文

Recovery of waste heat in cement plants for the capture of CO

Ruifeng DONG, Zaoxiao ZHANG, Hongfang LU, Yunsong YU

期刊论文