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可拓分类树 1

建材 1

建筑卫生陶瓷用黏土矿原料（高岭土） 1

强国战略 1

氟化石墨 1

水泥灰岩 1

物元模型 1

玻璃用硅质原料 1

球墨铸铁 1

石墨 1

石墨形态 1

石墨；石墨深加工；石墨精矿；石墨烯；氟化石墨 1

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Permeability and thermal conductivity of host compressed natural graphite for consolidated activated

Bo TIAN, Liwei WANG, Zhequan JIN, Ruzhu WANG

《能源前沿（英文）》 2011年 第5卷 第2期   页码 159-165 doi: 10.1007/s11708-011-0145-y

摘要： Permeability and thermal conductivity test units were set up to study the heat and mass transfer performance of the host material, i.e. expanded natural graphite (ENG), for consolidated activated carbon (AC) adsorbent. The permeability was tested with nitrogen as the gas source, and the thermal conductivity was studied using steady-state heat source method. The results showed that the values of permeability and thermal conductivity were 10 to 10 m and 1.7 to 3.2 W/(m·K), respectively, while the density compressed expanded natural graphite (CENG) varied from 100 to 500 kg/m . The permeability decreased with the increasing density of CENG, whereas the thermal conductivity increased with the increasing density of CENG. Then the thermal conductivity and permeability of granular AC were researched. It was discovered that the thermal conductivity of samples with different grain size almost kept constant at 0.36 W/(m·K) while the density was approximately 600 kg/m . This means that the thermal conductivity was not related to the grain size of AC. The thermal conductivity of CENG was improved by 5 to 10 times compared with that of granular AC. Such a result showed that CENG was a promising host material for AC to improve the heat transfer performance, while the mass transfer performance should be considered in different conditions for utilization of adsorbent.

关键词： permeability     thermal conductivity     expanded nature graphite     activated carbon    

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Preparing graphene from anode graphite of spent lithium-ion batteries

Wenxuan Zhang, Zhanpeng Liu, Jing Xia, Feng Li, Wenzhi He, Guangming Li, Juwen Huang

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0993-8

摘要： With extensive use of lithium ion batteries (LIBs), amounts of LIBs were discarded, giving rise to growth of resources demand and environmental risk. In view of wide usage of natural graphite and the high content (12%–21%) of anode graphite in spent LIBs, recycling anode graphite from spent LIBs cannot only alleviate the shortage of natural graphite, but also promote the sustainable development of related industries. After calcined at 600°Cfor 1 h to remove organic substances, anode graphite was used to prepare graphene by oxidation-reduction method. Effect of pH and N2H4·H2O amount on reduction of graphite oxide were probed. Structure of graphite, graphite oxide and graphene were characterized by XRD, Raman and FTIR. Graphite oxide could be completely reduced to graphene at pH 11 and 0.25 mL N2H4·H2O. Due to the presence of some oxygen-containing groups and structure defects in anode graphite, concentrated H2SO4 and KMnO4 consumptions were 40% and around 28.6% less than graphene preparation from natural graphite, respectively.

关键词： Spent LIBs     Graphite     Graphite oxide     Grapheme    

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Electro-catalytic activity of CeO modified graphite felt for carbamazepine degradation via E-peroxone

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1410-x

摘要：

•CeOx/GF-EP process had the better degradation efficiency than GF-EP process.

关键词： E-peroxone     CeOx     Graphite felt     Carbamazepine     Mineralization    

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Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1278-1

摘要： Abstract • Graphite bipolar electrodes act as an appropriate bed for the CDI process. • Activated carbon Coating improves the application of the electrodes. • CDI is an environmentally friendly method to apply for brackish water. • Initial concentration is the most important parameter in the CDI method. • CDI process in a batch-mode setup needs more development. This research investigates a capacitive deionization method for salinity reduction in a batch reactor as a new approach for desalination. Reductions of cost and energy compared with conventional desalination methods are the significant advantages of this approach. In this research, experiments were performed with a pair of graphite bipolar electrodes that were coated with a one-gram activated carbon solution. After completing preliminary tests, the impacts of four parameters on electrical conductivity reduction, including (1) the initial concentration of feed solution, (2) the duration of the tests, (3) the applied voltage, and (4) the pH of the solution, were examined. The results show that the maximum efficiency of electrical conductivity reduction in this laboratory-scale reactor is about 55%. Furthermore, the effects of the initial concentration of feed solution are more significant than the other parameters. Thus, using the capacitive deionization method for water desalination with low and moderate salt concentrations (i.e., brackish water) is proposed as an affordable method. Compared with conventional desalination methods, capacitive deionization is not only more efficient but also potentially more environmentally friendly.

关键词： Capacitive deionization (CDI)     Desalination     Electrical conductivity (EC)     Graphite bipolar electrode     Activated carbon coated (ACC)    

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石墨资源及材料产业高质量发展战略研究

孙传尧 ,申士富 ,王文利 ,袁国辉 ,黄正宏 ,张以河

《中国工程科学》 2022年 第24卷 第3期   页码 29-39 doi: 10.15302/J-SSCAE-2022.03.004

摘要：

天然石墨是一种由新制备及应用技术引领发展的新技术矿产，是支撑我国战略性新兴产业发展的重要原材料。本文分析了石墨资源及材料产业高质量发展的需求，总结了我国石墨资源及材料产业的发展现状，分析了我国石墨产业高质量发展的潜力和面临的主要问题，提出了我国石墨资源及材料产业下一步发展的目标。在此基础上，本文提出了石墨资源及材料产业高质量发展的举措，包括以石墨精深加工为中心布局技术创新体系；优化资源配置，加快发展绿色石墨企业及绿色石墨矿山；加强平台能力建设，夯实产业链供应链技术创新基础；重点突破石墨烯独特物性的专属应用，避免过度宣传。研究建议，健全我国石墨全产业链及供应链数据库，建立长期支持我国石墨产业高质量发展的政策机制，加快资源整合及“国际石墨谷”建设，规划布局创新能力平台和加强人才培养。

关键词： 石墨；石墨深加工；石墨精矿；石墨烯；氟化石墨    

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Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery

Tong Zhang, Elie Paillard

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 577-591 doi: 10.1007/s11705-018-1758-z

摘要：

Lithium-ion batteries are a key technology in today’s world and improving their performances requires, in many cases, the use of cathodes operating above the anodic stability of state-of-the-art electrolytes based on ethylene carbonate (EC) mixtures. EC, however, is a crucial component of electrolytes, due to its excellent ability to allow graphite anode operation–also required for high energy density batteries–by stabilizing the electrode/electrolyte interface. In the last years, many alternative electrolytes, aiming at allowing high voltage battery operation, have been proposed. However, often, graphite electrode operation is not well demonstrated in these electrolytes. Thus, we review here the high voltage, EC-free alternative electrolytes, focusing on those allowing the steady operation of graphite anodes. This review covers electrolyte compositions, with the widespread use of additives, the change in main lithium salt, the effect of anion (or Li salt) concentration, but also reports on graphite protection strategies, by coatings or artificial solid electrolyte interphase (SEI) or by use of water-soluble binder for electrode processing as these can also enable the use of graphite in electrolytes with suboptimal intrinsic SEI formation ability.

关键词： lithium-ion     electrolyte     solid electrolyte interphase     additives     high voltage     graphite    

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Oxidation performance of graphite material in reactors

LUO Xiaowei, YU Xinli, YU Suyuan

《能源前沿（英文）》 2008年 第2卷 第4期   页码 471-474 doi: 10.1007/s11708-008-0074-6

摘要： Graphite is used as a structural material and moderator for high temperature gas-cooled reactors (HTGR). When a reactor is in operation, graphite oxidation influences the safety and operation of the reactor because of the impurities in the coolant and/or the accident conditions, such as water ingress and air ingress. In this paper, the graphite oxidation process is introduced, factors influencing graphite oxidation are analyzed and discussed, and some new directions for further study are pointed out.

关键词： ingress     accident     oxidation     coolant     moderator    

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Promoting Si-graphite composite anodes with SWCNT additives for half and NCM811 full lithium ion batteries

Jingning SHAN, Xiaofang YANG, Chao YAN, Yiguang JU, Lin CHEN, Fang ZHAO

《能源前沿（英文）》 2019年 第13卷 第4期   页码 626-635 doi: 10.1007/s11708-019-0650-y

摘要： Single wall carbon nanotube (SWCNT) additives were formulated into µm-Si-graphite composite electrodes and tested in both half cells and full cells with high nickel cathodes. The critical role of small amount of SWCNT addition (0.2 wt%) was found for significantly improving delithiation capacity, first cycle coulombic efficiency (FCE), and capacity retention. Particularly, Si (10 wt%)-graphite electrode exhibits 560 mAh/g delithiation capacity and 92% FCE at 0.2 C during the first charge-discharge cycle, and 91% capacity retention after 50 cycles (0.5 C) in a half cell. Scanning electron microscope (SEM) was used to illustrate the electrode morphology, compositions and promoting function of the SWCNT additives. In addition, full cells assembled with high nickel-NCM811 cathodes and µm-Si-graphite composite anodes were evaluated for the consistence between half and full cell performance, and the consideration for potential commercial application. Finally, criteria to assess Si-containing anodes are proposed and discussed from an industrial perspective.

关键词： lithium-ion battery     Si anode     Si-graphite composite     single wall carbon nanotube (SWCNT)     NCM811    

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基于可拓学的球墨铸铁石墨形态识别

陈智斌,余永权,杨少敏

《中国工程科学》 2005年 第7卷 第3期   页码 84-89

摘要：

根据石墨的形态特征，运用物元分析方法建立起关于石墨形态识别的物元模型，提出了可拓分类树方法，讨论了可拓分类树的构造和实现途径，并将其应用于石墨形态的类型判别；给出了典型的实验结果，并对该方法与现有识别方法作出比较。

关键词： 物元模型     可拓分类树     石墨形态     球墨铸铁    

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exoelectrogen-methanogen evolution from low-strength wastewater in an up-flow biofilm reactor with conductive granular graphite

Zechong Guo, Lei Gao, Ling Wang, Wenzong Liu, Aijie Wang

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1074-3

摘要：

Methane yield increased 22 times from low-strength wastewater by applying conductive fillers.

Conductive fillers accelerated the start-up stage of anaerobic biofilm reactor.

Conductive fillers altered methanogens structure.

关键词： Low-strength wastewater     Methane production     Conductive filler     Microbial community structure    

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Fluoride removal from secondary effluent of the graphite industry using electrodialysis: Optimization

Xiaomeng Wang, Ning Li, Jianye Li, Junjun Feng, Zhun Ma, Yuting Xu, Yongchao Sun, Dongmei Xu, Jian Wang, Xueli Gao, Jun Gao

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1132-5

摘要：

RSM was utilized to optimize and model influential parameters on fluoride removal.

Regression models involving independent variables and main response were developed.

Interactive effects and optimum of process factors were illuminated and determined.

Fluoride removal efficiency of 99.69% was observed in optimal process conditions.

关键词： Response surface methodology     Fluoride removal     Electrodialysis     Box-Behnken design    

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氟化石墨嵌锂和嵌钠行为的第一性原理研究 Article

饶凤雅,王志强,徐波,陈立泉,欧阳楚英

《工程（英文）》 2015年 第1卷 第2期   页码 243-246 doi: 10.15302/J-ENG-2015039

摘要：

通过第一性原理计算研究了嵌入锂/钠后氟化石墨结构的演化过程。计算考虑了单层氟化石墨上和体相氟化石墨中的锂/钠嵌入。与锂的嵌入相比，将钠嵌入氟化石墨 (CF) 正极中所表现的循环性能更好，这是因为锂–氟间相互作用和钠–氟间相互作用的强度和特点不同。锂和氟之间的相互作用与钠和氟之间的相互作用相比更强且更集中。这种锂–氟之间强烈的库仑吸引作用破坏了F—C，并将氟原子拔出，从而导致在锂嵌入过程中形成单层石墨烯。

关键词： 第一性原理     锂/钠可充电电池     氟化石墨    

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Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems

《环境科学与工程前沿（英文）》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1476-5

摘要：

• MES was constructed for simultaneous ammonia removal and acetate production.

关键词： Biocathode     Carbon dioxide     Electrochemical oxidation     Graphite anode     Boron-doped diamond    

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On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

《能源前沿（英文）》 2010年 第4卷 第2期   页码 181-184 doi: 10.1007/s11708-009-0065-2

摘要： A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differently on stainless steel. The mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶1, which is demonstrated to be the optimum ratio. The experimental research in this paper reveals that, of the three solutions, which are pure calcium chloride, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest oxidation creation and pitting corrosion happened in the solution of calcium chloride with expanded graphite, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon, and pitting corrosion was stronger than oxidation creation in the solution of pure calcium chloride. This paper gives the reasons for these phenomena. Furthermore, based on theory analysis, multiple means and approaches are provided to prevent stainless steel from further corroding.

关键词： stainless steel     corrosion     calcium chloride     expanded graphite     activated carbon     oxidation creation     pitting corrosion    

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建材非金属矿产资源强国战略研究

顾真安,同继锋,崔源声,彭寿,苏桂军,周洪锦,冯惠敏,赵飞,田桂萍,孟庆洁,洪伟

《中国工程科学》 2019年 第21卷 第1期   页码 104-112 doi: 10.15302/J-SSCAE-2019.01.015

摘要：

本文研究我国主要建材产品生产所用的水泥灰岩、玻璃用硅质原料、建筑卫生陶瓷用黏土矿原料（高岭土）、高纯石英和石墨五种非金属矿产资源的强国建设战略，确定建材非金属矿产资源发展的战略思路与目标，指出加强矿区规划与保护、建设供应示范基地和标准原料基地、加快推进战略性资源储备制度等重点任务，提出设立矿产资源强国建设领导小组、完善矿产资源原料产品标准体系建设、加强人才培养体系建设、加强矿产资源法律法规制定与实施等保障措施。

关键词： 建材     强国战略     水泥灰岩     玻璃用硅质原料     建筑卫生陶瓷用黏土矿原料（高岭土）     高纯石英     石墨    

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标题 作者 时间 类型 操作

Permeability and thermal conductivity of host compressed natural graphite for consolidated activated

Bo TIAN, Liwei WANG, Zhequan JIN, Ruzhu WANG

期刊论文

Preparing graphene from anode graphite of spent lithium-ion batteries

Wenxuan Zhang, Zhanpeng Liu, Jing Xia, Feng Li, Wenzhi He, Guangming Li, Juwen Huang

期刊论文

Electro-catalytic activity of CeO modified graphite felt for carbamazepine degradation via E-peroxone

期刊论文

Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

期刊论文

石墨资源及材料产业高质量发展战略研究

孙传尧 ,申士富 ,王文利 ,袁国辉 ,黄正宏 ,张以河

期刊论文

Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery

Tong Zhang, Elie Paillard

期刊论文

Oxidation performance of graphite material in reactors

LUO Xiaowei, YU Xinli, YU Suyuan

期刊论文

Promoting Si-graphite composite anodes with SWCNT additives for half and NCM811 full lithium ion batteries

Jingning SHAN, Xiaofang YANG, Chao YAN, Yiguang JU, Lin CHEN, Fang ZHAO

期刊论文

基于可拓学的球墨铸铁石墨形态识别

陈智斌,余永权,杨少敏

期刊论文

exoelectrogen-methanogen evolution from low-strength wastewater in an up-flow biofilm reactor with conductive granular graphite

Zechong Guo, Lei Gao, Ling Wang, Wenzong Liu, Aijie Wang

期刊论文

Fluoride removal from secondary effluent of the graphite industry using electrodialysis: Optimization

Xiaomeng Wang, Ning Li, Jianye Li, Junjun Feng, Zhun Ma, Yuting Xu, Yongchao Sun, Dongmei Xu, Jian Wang, Xueli Gao, Jun Gao

期刊论文

氟化石墨嵌锂和嵌钠行为的第一性原理研究

饶凤雅,王志强,徐波,陈立泉,欧阳楚英

期刊论文

Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems

期刊论文

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

期刊论文

建材非金属矿产资源强国战略研究

顾真安,同继锋,崔源声,彭寿,苏桂军,周洪锦,冯惠敏,赵飞,田桂萍,孟庆洁,洪伟

期刊论文