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Frontiers of Chemical Science and Engineering >> 2012, Volume 6, Issue 3 doi: 10.1007/s11705-012-0903-3

Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane

Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing 100124, China

Available online: 2012-09-05

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Abstract

The latest progress and developments in catalysts for the oxidation of cyclohexane are reviewed. Catalytic systems for the oxidation of cyclohexane including metal supported, metal oxides, molecular sieves, metal substituted polyoxometalates, photocatalysts, organocatalysts, Gif systems, metal-organic catalysts and metalloporphyrins are discussed with a particular emphasis on metalloporphyrin catalytic systems. The advantages and disadvantages of these methods are summarized and analyzed. Finally, the development trends in the oxidation technology of cyclohexane are examined.

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