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Frontiers of Chemical Science and Engineering >> 2015, Volume 9, Issue 4 doi: 10.1007/s11705-015-1549-8

Orderly decorated nanostructural photoelectrodes with uniform spherical TiO

Department of Research and Development, SUN Nanotechnologists Company, Tehran 13488-96394, Iran

Accepted: 2015-11-20 Available online: 2015-11-26

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Abstract

This study presents a novel nanostructural electrode made of 20-nm-diameter nanoparticles, which orderly decorated with 2-µm TiO particles, deposited by a new gel process. The decorated electrode (DE) is better than the non-decorated electrode (NE) in both light scattering and light harvesting, as confirmed by diffuse reflectance spectroscopy. X-ray diffraction reveals that both electrodes have a mixture of anatase and rutile phases. The dye-sensitized solar cell based on the decorated electrode shows the highest power conversion efficiency of 7.80% as a result of less recombination demonstrated by electrochemical impedance spectroscopy. From internal power conversion efficiency measurement, the external quantum efficiency of DE cell at 530 nm is 89%, which is higher than that of NE cell (77%).

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