Frontiers of Chemical Science and Engineering
>> 2017,
Volume 11,
Issue 3
doi:
10.1007/s11705-016-1587-x
RESEARCH ARTICLE
Electrochemistry during efficient copper recovery from complex electronic waste using ammonia based solutions
. Department of Materials Science and Engineering, TU Delft, 2628 CD Delft, the Netherlands.. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China.. Ironmaking Department, R&D, Tata Steel, 1970 CA IJmuiden, the Netherlands
Accepted: 2016-09-12
Available online: 2017-08-23
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Abstract
Leaching selectivity during metal recovery from complex electronic waste using a hydrochemical process is always one of the generic issues. It was recently improved by using ammonia-based leaching process, specifically for electronic waste enriched with copper. This research proposes electrodeposition as the subsequent approach to effectively recover copper from the solutions after selective leaching of the electronic waste and focuses on recognising the electrochemical features of copper recovery. The electrochemical reactions were investigated by considering the effects of copper concentration, scan rate and ammonium salts. The diffusion coefficient, charge transfer coefficient and heterogeneous reaction constant of the electrodeposition process were evaluated in accordance with different solution conditions. The results have shown that electrochemical recovery of copper from ammonia-based solution under the conditions of selective electronic waste treatment is charge transfer controlled and provide bases to correlate the kinetic parameters with further optimisation of the selective recovery of metals from electronic waste.
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