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Frontiers of Chemical Science and Engineering >> 2018, Volume 12, Issue 1 doi: 10.1007/s11705-017-1686-3

Tuning of the active phase structure and hydrofining performance of alumina-supported tri-metallic WMoNi catalysts via phosphorus incorporation

. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China.. State Key Laboratory of Energy & Environmental Photocatalysis, Fuzhou University, Fuzhou 350116, China

Accepted: 2018-01-05 Available online: 2018-02-26

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Abstract

The effects of phosphorus on the structure and hydrofining performance of tri-metallic WMoNi/Al O catalysts prepared with W/Mo-based hybrid precursor nanocrystals were investigated. The incorporation of phosphorus weakened the metal-support interactions (MSIs) and facilitated the formation of more synergetic NiWMoS phases with higher stacks. Catalytic tests using a fluid catalytic cracking diesel fuel showed that the changes in the MSIs and the morphology of the active phases had a more positive effect on the hydrodenitrogenation activity than on the hydrodesulfurization activity. In contrast, when phosphorus was incorporated into a tri-metallic WMoNiP/Al O catalyst prepared by a conventional incipient impregnation method, the MSIs decreased causing aggregation of the metal species which resulted in poorer hydrofining performance of the catalyst. These results show that incorporating phosphorus into a WMoNi/Al O catalyst can finely tune the structure of the active phase to enhance the hydrogenation and hydrodenitrogenation activity of the resulting tri-metallic catalyst.

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