Journal Home Online First Current Issue Archive For Authors Journal Information 中文版

Frontiers of Chemical Science and Engineering >> 2018, Volume 12, Issue 3 doi: 10.1007/s11705-018-1753-4

Synthesis of iron(II) complexes with asymmetric N

Department of Chemistry, University of Bayreuth, 95440 Bayreuth, Germany

Accepted: 2018-09-06 Available online: 2018-09-18

Next Previous

Abstract

The synthesis of new Schiff base-like ligands with asymmetric substituents pattern and their iron complexes with pyridine as axial ligand is described. Two of the ligands and one of the iron(II) complexes were characterized by single crystal X-ray structure analysis. One of the the iron(II) complexes shows spin crossover behavior while the others remain in the high spin state. The influence of the reduced symmetry of the ligand on the properties of the complexes is discussed.

Related Research