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Frontiers of Environmental Science & Engineering >> 2017, Volume 11, Issue 4 doi: 10.1007/s11783-017-0936-4

Effects of seed particles Al

. School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China.. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China.. State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China

Available online: 2017-04-26

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Abstract

Seed particles Al O , Al (SO ) and H SO were selected to investigate their effects on secondary aerosol (SA) formation in toluene/NO photooxidation under sulfur dioxide (SO ) and ammonia (NH ). Effect of seed particles on SA formation was related to their acid-base properties and the presence of acid or alkaline gases. Under NH -poor condition, SA formation increased with increasing SO concentration due to the acid-catalyzing effect of the oxidation products of SO (i.e. H SO ). The enhancing effect of SO became unobvious under NH -rich condition, because NH would eliminate the acid-catalyzing effect by neutralizing the acid products. Acidic seeds H SO accelerated SA formation under either SO or NH condition. Weak acidic Al (SO ) seeds didn’t affect obviously on SA formation. The inhibiting effect of amphoteric seeds Al O on SA formation was related to the presence of SO / NH due to their acid-base property. Under NH -poor condition, the inhibiting effect of Al O on SA formation decreased with increasing concentration of SO , while under NH -rich condition, the inhibiting effect wasn’t remarkable.

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