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Strategic Study of CAE >> 2003, Volume 5, Issue 1

Mechanism and Modeling for Polymerization of Acrylamide in Inverse Microemulsions

1. College of Chemistry and Chemical Engineering of Fuzhou University, Fuzhou 350002, China

2. Department of Chemical Engineering of Zhejiang University, Hangzhou 310027, China

Funding project:化学工程国家重点联合实验室浙江大学聚合反应工程实验室开放基金(KF9904);福建省自然科学基金(D0010004) Received: 2002-04-08 Revised: 2002-10-08 Available online: 2003-01-20

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Abstract

After discussion on the mechanism of polymer particle nucleation and growth in inverse microemulsion polymerization, a schematic physical model for polymerization of acrylamide in inverse microemulsions was presented. Furthermore, several key problems in mathematically modeling of inverse microemulsion polymerization were pointed out.

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References

[ 1 ] 赵国玺编著.表面活性剂物理化学[M].北京:北京大学出版社, 1984 link1

[ 2 ] 崔正刚, 殷福珊编.微乳化技术及应用[M ].北京:中国轻工业出版社, 1999 link1

[ 3 ] ThomasWM , WangDW .Acrylamidepolymers.in:MarkMF , BikalesNM , OverbergerCG , etal, eds.EncyclopediaofPolymerScienceandEngineering[M ].Vol1.NewYork:JohnWiley&SonsInc, 1985.169

[ 4 ] CandauF , LeongYS , PouyetG , etal.Inversemicroemulsion polymerizationofacrylamide:Characterizationofthewater in oilmicroemulsionsandthefinalmicro latexes[J].JColloidInterfaceSci, 1984, 101:167

[ 5 ] Barto灳J.Partitioned polymerization, 6.Inversemicroemulsionpolymerizationofacrylamideinitiatedbyammoniumperoxodisulfate, 2, 2 azoisobutyronitrileanddibenzoylperoxideinthe presenceand/orabsenceoffremy’ssalt[J].MakromolChemRapidCommun.1991, (2) :675

[ 6 ] 哈润华, 侯斯健. (2-甲基丙烯酰氧乙基) 三甲基氯化铵-丙烯酰胺反相微乳液共聚合研究[J].高分子学报, 1993, (5) :570 link1

[ 7 ] Janigov偄I, Csomorov偄K, Stillhammerov偄M, etal.Differentialscanningcalorimetryandthermogravimetrystudiesof polyacrylamide preparedbyfree radicalpolymerizationininversemicroemulsionandinsolution[J].MacromolChemPhys, 1994, 195:3609

[ 8 ] 李 晓, 刘 戈, 袁惠根.煤油/Span80-Tween60/水/丙烯酰胺反相微乳液聚合动力学[J].化学反应工程与工艺, 1999, 15 (1) :13 link1

[ 9 ] 严 锋, 郑昌仁, 韦亚兵.阳离子型微乳液聚合丙烯酰胺的表征[J].高等学校化学学报, 2000, 21 (4) :655 link1

[10] LeongYS , CandauF .Inversemicroemulsionpolymerization[J].JPhysChem, 1982, 86 (12) :2269

[11] 李 晓, 张卫英, 袁惠根.丙烯酰胺反相微乳液聚合[J].精细石油化工进展, 2002, 3 (3) :13 link1

[12] CandauF , LeongYS , FitchRM .Kineticstudyofthepolymeriztionofacrylamideininversemicroemulsion[J].JPolymSciPolymChemEd, 1985, 23:193

[13] 张志成, 徐相凌, 张曼维.过硫酸钾引发丙烯酰胺微乳液聚合[J].高分子学报, 1995, (1) :23 link1

[14] CarverMT , HirschE , WittmannJC , etal.Percolationand particlenucleationininversemicroemulsionpolymerization[J].JPhysChem, 1989, 93:4867~4873

[15] GuoJS , SudolED , VanderhoffJW , etal.Particlenucleationand partitioninginstyreneO/Wmicroemulsionpolymerization[J].JPolymSciPolymChemEd, 1992, 30:691~702

[16] BlegerF , MurthyAK , PlaF , etal.Particlenucleationduringmicroemulsion polymerzationofmethylmethacrylate[J].Macromolecules.1994, 27:2559~2565

[17] 徐相凌, 张志成, 张曼维.辐射引发丙烯酰胺微乳液聚合[J].高分子学报, 1995, (3) :377 link1

[18] Barto灳J.Free radicalpolymerizationininversemicroemulsions[J].ProgPolymSci, 1996, 21:399

[19] VaˇskovˇsV , JuranicovˇsV , Barto灳J.Polymerizationininversemicroemulions, 2.Copolymerizationofwater andoil solublemonomersinitiatedby2, 2’ azoisobutyronitrile[J].MakromolChem, 1991, 192:989

[20] Barto灳J.Reactantpartitioninginfree radicalhetero phasepolymerization:Thecaseofinversemicroemulsionpolymerizationofacrylamide[J ].PolymerInternational, 1993, 30:151

[21] CandauF , ZekhniniZ , HeatleyF .13CNMRstudyofthesequencedistributionofpoly (acrylamide co sodiumacrylates) preparedininversemicroemulsions[J].Macromolecules, 1986, 19 (7) :1895

[22] 李 晓, 袁惠根.辛烷/Span80-Tween60/丙烯酰胺/水反相微乳液聚合动力学[J].合成橡胶工业, 1999, 22 (4) :220 link1

[23] GuoJS , SudolED , VanderhoffJW , etal.Modelingofthestyrenemicroemulsion polymerization[J].JPolymSciPolymChemEd, 1992, 30:703

[24] MorganJD , LusvardiM , KalerEW .Kineticsandmechanismofmicroemulsionpolymerizationofhexylmethacrylate[J].Macromolecules, 1997, 30 (7) :1897

[25] 李 晓, 刘 戈, 袁惠根.煤油/Span80-Tween60/水/丙烯酰胺反相微乳液聚合III.聚合动力学BP人工神经网络模型[A].见:中国化学会.’99全国高分子学术论文报告会论文集[C], 上海, 1999.a-335

[26] UgelstadJ, MorkPC , KaggerudKH , etal.Swellingofoligomer polymerparticles, newmethodsofpreparationofemulsionand polymerdispersions[J].AdvColloidInterfaceSci, 1980, 13:101

[27] CorpartJM , CandauF .Formulationandpolymerizationofmicroemulsionscontainingmixtureofcationicandanionicmonomers[J].ColloidPolymSci, 1993, 271 (11) :1055~1067 link1

[28] Barto灳J, TinoJ, Hlonˇskov偄Z, etal.Effectofpercolationonfree radicalpolymerizationofacrylamideininversemicroemulsion[J].PolymerInternational.1994, 34:89

[29] 赵 勇, 何炳林, 哈润华.乳化剂对丙烯酰胺反相微乳液共聚合的影响[J].应用化学, 2000, 17 (2) :168 link1

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