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Strategic Study of CAE >> 2014, Volume 16, Issue 7

Preparation and antibacterial property of Polyethersulfone Hybrid Ultrafiltration Membrane Containing GO immobilized by Lysozyme

School of Chemical Engineering and Energy,Zhengzhou University,Zhengzhou 450001,China

Funding project:国家自然科学基金项目(21106137,21376225);中国博士后基金项目(2013M531684);大学生创新实验训练计划项目(2013xjxm075,2013xjxm072) Received: 2014-05-08 Available online: 2014-08-12 14:32:53.000

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Abstract

Graphene oxide provides an ideal substrate for lysozyme immobilization due to a large specific surface area and abundant functional groups. The lysozyme immobilization on the GO sheets could take place readily by electrostatic interaction of GO-lysozyme (denoted as GO-Ly). The immobilized lysozyme of GO used as the addictive was blended with PES to prepare hybrid ultrafiltration membrane via phase inversion.The effect of GO-Ly content on the morphology, hydrophilic, separation, mechanical and antibacterial properties of hybrid membranes was investigated. The results showed that the surface hydrophilicity and water flux was significantly improved with the increase of GO-Ly content. Meanwhile, the mechanical strength of hybrid membrane was also increased. Especially for 1.5 wt.% of GO-Ly, the water flux reached up to 318 L/(m2?h). The rejection of PVA30000-70000 was 99% and the antibacterial rate of the hybrid membrane against E. coli could achieve 68%.

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References

[ 1 ] Susanto Heru,Ulbricht Mathias. Characteristics,performance and stability of polyethersulfone ultrafiltration membranes prepared by phase separation method using different macromolecular additives [J]. Journal of Membrane Science,2009,327 (1/ 2):125-135. link1

[ 2 ] Puro L,Kallioinen M,Mänttäri M,et al. Performance of RC and PES ultrafiltration membranes in filtration of pulp mill process waters [J]. Desalination,2010,264(3):249-255. link1

[ 3 ] Su Yanlei,Li Chao,Zhao Wei,et al. Modification of polyethersulfone ultrafiltration membranes with phosphorylcholine copolymer can remarkably improve the antifouling and permeation properties [J]. Journal of Membrane Science,2008,322(1): 171-177. link1

[ 4 ] Shi Qing,Su Yanlei,Zhu Shiping,et al. A facile method for synthesis of pegylated polyethersulfone and its application in fabrication of antifouling ultrafiltration membrane [J]. Journal of Membrane Science,2007,303(1/2):204-212. link1

[ 5 ] Yu Haoxia,Zhang Yatao,Zhang Jingyi,et al. Preparation and antibacterial property of SiO2-Ag/PES hybrid ultrafiltration membranes [J]. Desalination and Water Treatment,2013,51(16- 18):3584-3590. link1

[ 6 ] Chen Yifeng,Zhang Yatao,Liu Jindun,et al. Preparation and antibacterial property of polyethersulfone ultrafiltration hybrid membrane containing halloysite nanotubes loaded with copper ions [J]. Chemical Engineering Journal,2012,210:298-308. link1

[ 7 ] Ciston Shannon,Lueptow Richard M,Gray Kimberly A. Bacterial attachment on reactive ceramic ultrafiltration membranes [J]. Journal of Membrane Science,2008,320(1/2):101-107. link1

[ 8 ] Zhu Xiaoying,Bai Renbi,Wee Kin-Ho,et al. Membrane surfaces immobilized with ionic or reduced silver and their anti- biofouling performances [J]. Journal of Membrane Science,2010, 363(1/2):278-286. link1

[ 9 ] Chen Yifeng,Zhang Yatao,Zhang Haoqin,et al. Biofouling control of halloysite nanotubes-decorated polyethersulfone ultrafiltration membrane modified with chitosan- silver nanoparticles [J]. Chemical Engineering Journal,2013,228:12-20. link1

[10] Yu Haoxia,Zhang Xiaofei,Zhang Yatao,et al. Development of a hydrophilic PES ultrafiltration membrane containing SiO2@N- Halamine nanoparticles with both organic antifouling and antibacterial properties [J]. Desalination,2013,326:69- 76. link1

[11] Zhang Jingyi,Zhang Yatao,Chen Yifeng,et al. Preparation and characterization of novel polyethersulfone hybrid ultrafiltration membranes bending with modified halloysite nanotubes loaded with silver nanoparticles [J]. Industrial & Engineering Chemistry Research,2012,51:3081-3090. link1

[12] Yu Liang,Zhang Yatao,Zhang Bing,et al. Preparation and characterization of HPEI-GO/PES ultrafiltration membrane with antifouling and antibacterial properties [J]. Journal of Membrane Science,2013,447:452-462. link1

[13] Li W,Li X,Wang Q,et al. Antibacterial activity of nanofibrous mats coated with lysozyme- layered silicate composites via electrospraying [J]. Carbohydrate Polymers,2014,99: 218-225. link1

[14] Eby D Matthew,Schaeublin Nicole M,Farrington Karen E,et al. Lysozyme catalyzes the formation of antimicrobial silver nanoparticles [J]. ACS Nano,2009,3(4):984-994. link1

[15] Wang Qiang,Fan Xuerong,Hu Yingjun,et al. Antibacterial functionalization of wool fabric via immobilizing lysozymes [J]. Bioprocess and Biosystems Engineering,2009,32(5): 633-639. link1

[16] Edwards J Vincent,Prevost Nicolette T,Condon Brian,et al. Covalent attachment of lysozyme to cotton/cellulose materials: Protein verses solid support activation [J]. Cellulose,2011,18 (5):1239-1249. link1

[17] Paredes J I,Villar- Rodil S,Martinez- Alonso A,et al. Graphene oxide dispersions in organic solvents [J]. Langmuir, 2008,24(19):10560-10564. link1

[18] Wang Shiren,Zhang Yue,Abidi Noureddine,et al. Wettability and surface free energy of graphene films[J]. Langmuir,2009, 25(18):11078-11081. link1

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